Benzophenone hydrazone derivatives as insecticides

ABSTRACT

Novel benzophenonehydrazone derivatives represented by the formula (I): ##STR1## wherein, R 1  is halogen; R 2  is hydrogen or C 1-4  alkyl; R 3  is cyano, optically substituted C 1-4  alkyl, C 2-4  alkenyl, C 3-4  alkynyl, C 1-4  alkyl-carbonyl or C 1-4  alkoxy-thiocarbonyl; R 4  is hydrogen, phenyl, optionally substituted C 1-6  alkyl, optionally substituted C 2-8  alkenyl, --CO--R 8 , --CO--O--R 9  or ##STR2## R 5  is hydrogen, formyl, phenyl, optionally substituted C 1-8  alkyl, optionally substituted C 2-8  alkenyl, optionally substituted C 3-8  alkynyl, optionally substituted C 1-8  alkyl-arbonyl, optionally substituted C 1-6  alkyl-oxalyl, optionally substituted C 1-8  alkoxy-carbonyl, optionally substituted C 1-8  alkoxy-oxalyl, optionally substituted C 3-8  cycloalkyl-carbonyl, optionally substituted C 2-8  alkenyl-carbonyl or optionally substituted benzoyl; R 6  is hydrogen or halogen; R 7  is hydrogen, halogen or C 1-2  alkyl, C 1-4  alkyl-carbonyl or C 1-4  alkoxy-thiocarbonyl; n is 0, 1 or 2, provided that n is 0 when R 3  is cyano, C 1-4  alkyl-carbonyl or C 1-4  alkoxy-thiocarbonyl,  is a single bond of Anti form or of Syn form. 
     The benzophenonehydrazone derivatives of the formula (I) have excellent insecticidal activities.

The present invention relates to novel benzophenone hydrazone derivatives, to processes for the preparation thereof and to their use as insecticides, as well as to novel intermediates for their preparation and to processes for their preparation.

It has been already known that certain 4-substituted-4'-alkysufonyloxybenzophenone hydrazone derivatives have insecticidal activities (see British Crop Protection Conference Pests and Diseases 1984, Vol.2, 405-412, Japanese Patent Kokai Publications Sho 54-122261 (=EP-3913-A, U.S. Pat. No. 4,394,387), Sho 56-45452 (=EP-26040-A, U.S. Pat. Nos. 4,331,680, 4,432,994), Hei 2-138246 (=EP-355832-A, U.S. Pat. No. 4,980,373), Hei 3-74356 (DERWENT AN-91-136915), Hei 4-1173 (DERWENT AN-92-053936), Hei 6-25134(=CA2094010), Hei 6-184079 (=U.S. Pat. Nos. 5,340,837, 5,405,871), Hei 7-149708(=EP-647622), Hei 7-242618(=CA2139465) and Hei 7-247261 (=DERWENT AN=95-363559)).

However, the level and/or duration of activity of these known compounds are not entirely satisfactory in all fields of application, in particular against certain organisms or when low concentrations are applied.

There have now been found novel benzophenone hydrazone derivatives of the formula (I). ##STR3## wherein R¹ is halogen,

R² is hydrogen or C₁₋₄ alkyl,

R³ is cyano, optionally substituted C₁₋₄ alkyl, C₂₋₄ alkenyl or C₃₋₄ alkynyl, C₁₋₄ alkyl-carbonyl or C₁₋₄ alkoxy-thiocarbonyl,

R⁴ is hydrogen, phenyl, benzyl, optionally substituted C₁₋₈ alkyl, optionally substituted C₂₋₈ alkenyl, --CO--R⁸, --CO--O--R⁹ or ##STR4## R⁵ is hydrogen, formyl, phenyl, optionally substituted C₁₋₈ alkyl, optionally substituted C₂₋₈ alkenyl, optionally substituted C₃₋₈ alkynyl, optionally substituted C₁₋₈ alkyl-carbonyl, optionally substituted C₁₋₆ alkyl-oxalyl, optionally substituted C₁₋₈ alkoxy-carbonyl, optionally substituted C₁₋₈ alkoxy-oxalyl, optionally substituted C₃₋₈ cycloalkyl-carbonyl, optionally substituted C₂₋₈ alkenyl-carbonyl or optionally substituted benzoyl,

R⁶ is hydrogen or halogen,

R⁷ is hydrogen, halogen or C₁₋₂ alkyl,

n is 0, 1 or 2, provided that n is 0 when R³ is cyano, C₁₋₄ alkyl-carbonyl or C₁₋₄ alkoxy-thiocarbonyl,

is a single bond of Anti form or of Syn form,

R⁸ is optionally substituted C₁₋₈ alkyl, optionally substituted C₂₋₈ alkenyl, optionally substituted phenyl, optionally substituted C₃₋₈ cycloalkyl, optionally substituted C₁₋₈ alkyl-carbonyl or optionally substituted C₁₋₈ alkoxy-carbonyl, or hydrogen,

R⁹ is optionally substituted C₁₋₈ alkyl, optionally substituted C₃₋₈ cycloalkyl, optionally substituted C₂₋₈ alkenyl or optionally substituted C₃₋₈ alkynyl,

R¹⁰ is hydrogen or C₁₋₄ alkyl,

R¹¹ is hydrogen, optionally substituted C₁₋₄ alkyl or optionally substituted phenyl and,

Z is oxygen or sulfur.

The compounds of the formula (I), according to the invention, are obtained when

(a) in the case where R⁵ is hydrogen:

compounds of the formula (II) ##STR5## wherein R¹, R², R³, R⁶, R⁷ and n are defined as above,

are reacted with compounds of the formula (III) ##STR6## wherein R⁴ is defined as above; in the presence of an inert solvent, and, if appropriate, in the presence of an acid catalyst, or

(b) in the case where R⁵ is hydrogen and R⁴ is ##STR7## and R¹¹ is not hydrogen, then R¹¹ is replaced by R¹², then R¹² is optionally substituted C₁₋₄ alkyl or optionally substituted phenyl:

compounds of the formula (IV) ##STR8## wherein R¹, R², R³, R⁶, R⁷ and n are defined as above,

are reacted with compound of the formula (V)

    OCN--R.sup.12                                              (V)

wherein R¹² is optionally substituted C₁₋₄ alkyl or optionally substituted phenyl,

in the presence of an inert solvent, or

(c) in the case where R⁴ is --CO--R⁸ or --CO--O--R⁹, provided that R⁸ is not hydrogen, then R⁸ or --O--R⁹ is replaced by R¹³, the aforementioned compounds of the formula (IV) are reacted with compounds of the formula (VI) ##STR9## wherein hal is chlorine or bromine and R¹³ is R⁸ or --O--R⁹,

in the presence of an inert solvent, and if appropriate in the presence of an acid binder, or

(d) in the case where R⁵ is not hydrogen, then R⁵ is replaced by R¹⁴ :

compounds of the formula (VII) ##STR10## wherein R¹, R², R³, R⁴, R⁶, R⁷ and n have the same meaning as mentioned above,

are reacted with compounds of the formula (VIII)

    hal--R.sup.14                                              (VIII)

wherein hal and R¹⁴ have the same meaning as mentioned above,

in the presence of an inert solvent, and if appropriate in the presence of an acid binder, or

(e) in the case where n is 1:

compounds the formula (IX) ##STR11## wherein R¹, R², R³, R⁴, R⁵, R⁶ and R⁷ have the same meaning as mentioned above,

are oxidized in the presence of an inert solvent, or

(f): in the case where n is 2:

compounds of the formula (X) ##STR12## wherein R¹, R², R³, R⁴, R⁵, R⁶ and R⁷ have the same meanings as mentioned above and q is 0 or 1,

are oxidized in the presence of an inert solvent.

The benzophenone hydrazone derivatives of the formula (I) according to the invention exhibit powerful insecticidal action, especially against lepidoptera, coleoptera and soil insects.

According to the invention, unexpectedly, the benzophenone hydrazone derivatives of the formula (I) exhibit substantially, superior insecticidal action as compared with those of the compounds described in the above references which are similar to the compounds of the invention.

In the compounds of the formula (I) according to the invention, and the respective formulae representing their intermediates employed for the preparation of the compounds of formula (I), each of the halogen as well as the halogen parts of the haloalkyl, haloalkenyl and haloalkoxy represent fluorine, chlorine, bromine and iodine, preferably fluorine, chlorine or bromine.

Alkyl represents, for example, methyl, ethyl, propyl, isopropyl, n-(iso-, sec- or tert-)butyl, n-(iso-, sec-, tert- or neo-)pentyl and n-(iso-, sec-, tert- or neo-)hexyl, preferably, methyl, ethyl, propyl, isopropyl and n-(iso-, sec- or tert-)butyl.

Alkenyl represents, for example, vinyl, allyl, isopropenyl, 1-methyl-2-propenyl, 2-methyl-2-propenyl, 2- (or 3-)butenyl, 2-(3- or 4-)pentenyl,

Alkynyl represents, for example, propargyl.

Phenyl and the phenoxy may optionally be substituted by one or more than one substituent. The substituent(s) of those are selected from the group consisting of halogen(fluorine, chlorine, bromine), cyano, nitro, alkyl (methyl, ethyl, propyl or isopropyl), haloalkyl(trifluoromethyl), alkoxy(methoxy, ethoxy), haloalkoxy (trifluoromethoxy) and alkylthio(methylthio).

Cycloalkyl represents, for example, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, cycloheptyl and cyclooctyl. The cycloalkyl may optionally be substituted by C₁₋₄ alkyl(methyl, ethyl, propyl, isopropyl and butyl).

Alkoxy represents, for example, methoxy, ethoxy, propoxy, isopropoxy, n-(iso-, sec- or tert-)butoxy, n-(iso-, sec-, tert- or neo-)pentoxy, n-(iso-, sec-, tert- or neo-)hexoxy.

Haloalkoxy represents the above mentioned alkoxy groups which are substituted with the same or different halogen atom(s) and is, for example, trifluoromethoxy.

Alkylthio represents, for example, methylthio, ethylthio, propylthio, isopropylthio, n-(iso-, sec- or tert-)butylthio, n-(iso-, sec-, tert- or neo-)pentylthio, n-(iso-, sec-, tert- or neo-)hexylthio.

Among the benzophenone hydrazone derivatives according to the invention, of the formula (I), preferred compounds are those in which

R¹ is halogen,

R² is hydrogen or C₁₋₃ alkyl,

R³ is cyano, C₁₋₄ alkyl which may be substituted by one or more than one substituent selected from the group consisting of halogen, cyano, methoxy, ethoxy and trimethylsilyl or is C₂₋₃ alkenyl, propargyl, methyl-carbonyl, methoxy-thiocarbonyl or ethoxy-thiocarbonyl,

R⁴ is hydrogen, C₁₋₄ alkyl, C₂₋₄ alkenyl, phenyl, or is benzyl, --CO--R⁸, --CO--O--R⁹ or ##STR13## R⁵ is hydrogen, formyl, phenyl, C₁₋₆ alkyl which may be substituted by one or more than one substituent selected from the group consisting of halogen, cyano, C₁₋₄ alkoxy, C₁₋₄ alkylthio, hydroxycarbonyl, C₁₋₄ alkoxy-carbonyl, phenyl, phenyl which is substituted by halogen and methoxyphenyl or is C₂₋₆ alkenyl, C₃₋₆ alkynyl, C₁₋₆ alkyl-carbonyl, C₁₋₆ halogenalkyl-carbonyl, C₁₋₄ alkoxy-C₁₋₆ alkyl-carbonyl, C₁₋₆ alkyl-oxalyl, C₁₋₆ alkoxy-carbonyl which may be substituted by one or more than one substituent selected from the group consisting of C₃₋₆ cycloalkyl and C₁₋₄ alkoxy or is C₁₋₆ alkoxy-oxalyl, C₃₋₆ cycloalkyl-carbonyl which may be substituted by C₁₋₄ alkyl, C₂₋₆ alkenyl-carbonyl which may be substituted by phenyl or is benzoyl which may be substituted by one or more than one substituent selected from the group consisting of halogen, nitro, cyano, C₁₋₄ alkoxy and C₁₋₄ alkylthio,

R⁶ is hydrogen or halogen,

R⁷ is hydrogen or halogen or C₁₋₂ alkyl,

n is 0, 1 or 2, provided that n is 0 when R³ is cyano, methyl-carbonyl, methoxy-thiocarbonyl or ethoxy-thiocarbonyl,

is a single bond of Anti form or of Syn form,

R⁸ is C₁₋₆ alkyl which may be substituted by one or more than one substituent selected from the group consisting of halogen, cyano, C₁₋₄ alkoxy, C₁₄ alkoxy-carbonyl and phenoxy or is C₂₋₆ alkenyl which may be substituted by one or more than one substituent selected from the group consisting of halogen and phenyl, or is phenyl which may be substituted by one or more than one substituent selected from the group consisting of halogen, nitro, cyano, C₁₋₄ alkyl, C₁₋₄ alkoxy and C₁₋₄ alkythio, or is C₃₋₆ cycloalkyl which may be substituted by C₁₋₄ alkyl, or is C₁₋₆ alkyl-carbonyl or C₁₋₆ alkoxy-carbonyl, or hydrogen,

R⁹ is C₁₋₆ alkyl which may be substituted by one or more than one substituent selected from the group consisting of halogen, phenyl, 4-nitrophenyl, trimethylsilyl and C₃₋₆ cycloalkyl, or is C₃₋₆ cycloalkyl, or C₂₋₆ alkenyl which may be substituted by phenyl or is C₃₋₆ alkynyl,

R¹⁰ is hydrogen or C₁₋₄ alkyl,

R¹¹ is hydrogen, C₁₋₄ alkyl which may be substituted by halogen or is phenyl which may be substituted by one or more than one substituent selected from the group consisting of halogen, C₁₋₄ alkoxy or C₁₋₄ haloalkoxy and

Z is oxygen or sulfur.

Particularly preferred benzophenone hydrazone derivatives of the formula (I) are those in which

R¹ is fluorine, chlorine, bromine or iodine,

R² is hydrogen, methyl, ethyl or n-propyl,

R³ is cyano, methyl, ethyl, propyl, isopropyl, n-butyl, sec-butyl, cyanomethyl, fluoromethyl, chloromethyl, difluoromethyl, trifluoromethyl, 2-fluroroethyl, 2-chloroethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, 3-fluoropropyl, 3-chloropropyl, 2,2,3,3-tetrafluoropropyl, methoxymethyl, ethoxymethyl, trimethylsilylmethyl, vinyl, allyl, propargyl, methyl-carbonyl or ethoxythiocarbonyl,

R⁴ is hydrogen, methyl, ethyl, propyl, isopropyl, n-butyl, tert-butyl, allyl, phenyl, benzyl, --CO--R⁸, --CO--O--R⁹ or ##STR14## R⁵ is hydrogen, methyl, ethyl, propyl, isopropyl, n-butyl, tert-butyl, n-pentyl, n-hexyl, methoxymethyl, ethoxymethyl, methylthiomethyl, methylthioethyl, methoxycarbonylmethyl, ethoxycarbonylmethyl, 2-ethoxycarbonylethyl, difluoromethyl, 2-chloroethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, cyanomethyl, cyanoethyl, vinyl, allyl, propargyl, phenyl, benzoyl, cinnamoyl, benzyl, 4-chlorobenzoyl, 4-methoxybenzoyl, formyl,methylcarbonyl, ethylcarbonyl, propylcarbonyl, isopropylcarbonyl, n-butylcarbonyl, 2,2,2-trifluoroethylcarbonyl, 5-bromopentylcarbonyl, methoxymethylcarbonyl, methyloxalyl, ethyloxalyl, propyloxalyl, isopropyloxalyl, n-butyl-oxalyl, methoxycarbonyl, ethoxycarbonyl, propoxycarbonyl, butoxycarbonyl, methoxyoxalyl, ethoxyoxalyl, propoxyoxalyl, butoxyoxalyl, cyclopropylcarbonyl, 1-methylcyclopropylcarbonyl, cyclopropylmethoxycarbonyl or 2-methoxyethoxycarbonyl, hydroxycarbonylethyl,

R⁶ is hydrogen, fluorine or chlorine,

R⁷ is hydrogen, bromine or methyl,

n is 0, 1 or 2, provided that n is 0 when R³ is methyl-carbonyl or ethoxythiocarbonyl,

is a single bond of Anti form or of Syn form,

R⁸ is methyl, ethyl, propyl, isopropyl, n-butyl, isobutyl, sec-butyl, tert-butyl, n-pentyl, n-hexyl, cyanomethyl, 2-chloroethyl, 3-chloropropyl, 4-chlorobutyl, methoxymethyl, 2-methoxyethyl, phenoxymethyl, ethoxycarbonylmethyl, vinyl, isopropenyl, 1-propenyl, 2,3,3-trifluoro-2-propenyl, phenyl, 4-chlorophenyl, 4-bromophenyl, 4-methylphenyl, 4-methoxyphenyl, styryl, cyclopropyl, cyclopentyl, cyclohexyl, 1-methylcyclopropyl, methylcarbonyl, ethylcarbonyl, propylcarbonyl, methoxycarbonyl, ethoxycarbonyl or propyoxcarbonyl, or hydrogen,

R⁹ is methyl, ethyl, propyl, isopropyl, n-butyl, isobutyl, tert-butyl, sec-butyl, n-pentyl, neo-pentyl, 2-methylbutyl, n-hexyl, trimethylsilylmethyl, allyl, cyclopentyl, cyclohexyl, 2-methyl-2-propenyl, propargyl, 2-chloroethyl, 2,2,2-trifluoroethyl, 2,2,3,3-tetrafluoropropyl, cyclopropylmethyl, cyclohexylmethyl, benzyl or 4-nitrobenzyl

R¹⁰ is hydrogen or methyl,

R¹¹ is hydrogen, methyl, ethyl, 2-chloroethyl, phenyl, 2-chlorophenyl, 2-methoxyphenyl or 4-trifluoromethoxyphenyl, and

Z is oxygen or sulfur.

Specifically mentioned are the following compounds in Table 1 to Table 4.

                                      TABLE 1                                      __________________________________________________________________________      ##STR15##                                                                     R.sup.1                                                                           R.sup.2                                                                           R.sup.3 n R.sup.5        R.sup.6                                                                           R.sup.7                                                                           R.sup.9                                   __________________________________________________________________________     F  H  CH.sub.3                                                                               0 H              H  H  CH.sub.3                                  F  H  CH.sub.3                                                                               0 H              H  H  C.sub.2 H.sub.5                           F  H  CH.sub.3                                                                               0 H              3-F                                                                               H  CH.sub.3                                  F  H  CH.sub.3                                                                               0 H              3-F                                                                               H  C.sub.2 H.sub.5                           F  H  CH.sub.3                                                                               1 H              H  H  CH.sub.3                                  F  H  CH.sub.3                                                                               1 H              H  H  C.sub.2 H.sub.5                           F  H  CH.sub.3                                                                               1 H              H  H  n-C.sub.3 H.sub.7                         F  H  CH.sub.3                                                                               1 H              H  H  iso-C.sub.3 H.sub.7                       F  H  CH.sub.3                                                                               1 H              H  H  iso-C.sub.4 H.sub.9                       F  H  CH.sub.3                                                                               1 H              H  H  CH.sub.2 CF.sub.3                         F  H  CH.sub.3                                                                               2 H              H  H  C.sub.2 H.sub.5                           F  H  CH.sub.3                                                                               2 H              H  H  n-C.sub.3 H.sub.7                         F  H  CH.sub.3                                                                               2 H              H  H  iso-C.sub.3 H.sub.7                       F  H  CH.sub.3                                                                               2 H              H  H  iso-C.sub.4 H.sub.9                       F  H  CH.sub.3                                                                               2 H              H  H  CH.sub.2 CF.sub.3                         F  H  C.sub.2 H.sub.5                                                                        0 H              H  H  C.sub.2 H.sub.5                           F  H  C.sub.2 H.sub.5                                                                        0 H              3-F                                                                               H  C.sub.2 H.sub.5                           F  H  C.sub.2 H.sub.5                                                                        1 H              H  H  CH.sub.3                                  F  H  C.sub.2 H.sub.5                                                                        1 H              H  H  C.sub.2 H.sub.5                           F  H  C.sub.2 H.sub.5                                                                        1 H              H  H  CH.sub.2 CF.sub.3                         F  H  C.sub.2 H.sub.5                                                                        1 H              H  H  iso-C.sub.3 H.sub.7                       F  H  C.sub.2 H.sub.5                                                                        2 H              H  H  CH.sub.3                                  F  H  C.sub.2 H.sub.5                                                                        2 H              H  H  C.sub.2 H.sub.5                           F  H  C.sub.2 H.sub.5                                                                        2 H              H  H  n-C.sub.3 H.sub.7                         F  H  C.sub.2 H.sub.5                                                                        2 H              H  H  iso-C.sub.4 H.sub.9                       F  H  C.sub.2 H.sub.5                                                                        2 H              H  H  CH.sub.2 CF.sub.3                         F  H  C.sub.2 H.sub.5                                                                        2 H              3-F                                                                               H  C.sub.2 H.sub.5                           F  H  CH.sub.2 CH.sub.2 F                                                                    0 H              H  H  CH.sub.3                                  F  H  CH.sub.2 CF.sub.3                                                                      0 H              H  H  CH.sub.3                                  F  H  CH.sub.2 CF.sub.3                                                                      0 H              3-F                                                                               H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0 H              H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 H              H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               0 H              H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               0 H              H  H  sec-C.sub.4 H.sub.9                       Cl H  CH.sub.3                                                                               0 H              H  H  tert-C.sub.4 H.sub.9                      Cl H  CH.sub.3                                                                               0 H              H  H  n-C.sub.4 H.sub.9                         Cl H  CH.sub.3                                                                               0 H              H  H  iso-C.sub.4 H.sub.9 --                    Cl H  CH.sub.3                                                                               0 H              H  H  n-C.sub.5 H.sub.11                        Cl H  CH.sub.3                                                                               0 H              H  H  neo-C.sub.5 H.sub.11                      Cl H  CH.sub.3                                                                               0 H              H  H  CH.sub.2 CH(CH.sub.3)C.sub.2                                                   H.sub.5                                   Cl H  CH.sub.3                                                                               0 H              H  H  n-C.sub.6 H.sub.13                        Cl H  CH.sub.3                                                                               0 H              H  H  n-C.sub.7 H.sub.15                        Cl H  CH.sub.3                                                                               0 H              H  H  n-C.sub.8 H.sub.17                        Cl H  CH.sub.3                                                                               0 H              H  H  CH.sub.2 CH═CH.sub.2                  Cl H  CH.sub.3                                                                               0 H              H  H  CH.sub.2 C(CH.sub.3)═CH.sub.2         Cl H  CH.sub.3                                                                               0 H              H  H  CH.sub.2 C.tbd.CH                         Cl H  CH.sub.3                                                                               0 H              H  H  CH.sub.2 C.sub.6 H.sub.5                  Cl H  CH.sub.3                                                                               0 H              H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               0 H              H  H  CH.sub.2 CH.sub.2 Cl                      Cl H  CH.sub.3                                                                               0 H              H  H  CH.sub.2 CH.sub.2 OCH.sub.3               Cl H  CH.sub.3                                                                               0 H              H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  CH.sub.3                                                                               0 H              H  H                                                                                  ##STR16##                                Cl H  CH.sub.3                                                                               0 H              H  H                                                                                  ##STR17##                                Cl H  CH.sub.3                                                                               0 H              H  H                                                                                  ##STR18##                                Cl H  CH.sub.3                                                                               0 H              H  2-F                                                                               C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 H              H  3-F                                                                               C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 H              H  3-Cl                                                                              C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 H              H  3-Br                                                                              C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 H              H  3-CH.sub.3                                                                        C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 H              2-F                                                                               H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0 H              2-F                                                                               H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 H              2-Cl                                                                              H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0 H              2-Cl                                                                              H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 H              3-F                                                                               H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0 H              3-F                                                                               H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 H              3-Cl                                                                              H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0 H              3-Cl                                                                              H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 CH.sub.3       H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0 CH.sub.3       H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 CH.sub.3       H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               0 CH.sub.3       H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               0 CH.sub.3       H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               0 C.sub.2 H.sub.5                                                                               H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0 C.sub.2 H.sub.5                                                                               H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 C.sub.2 H.sub.5                                                                               H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               0 C.sub.2 H.sub.5                                                                               H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               0 C.sub.2 H.sub.5                                                                               H  H  n-C.sub.4 H.sub.9                         Cl H  CH.sub.3                                                                               0 C.sub.2 H.sub.5                                                                               H  H  iso-C.sub.4 H.sub.9                       Cl H  CH.sub.3                                                                               0 C.sub.2 H.sub.5                                                                               H  H  sec-C.sub.4 H.sub.9                       Cl H  CH.sub.3                                                                               0 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               0 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0 n-C.sub.3 H.sub.7                                                                             H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 n-C.sub.3 H.sub.7                                                                             H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               0 n-C.sub.3 H.sub.7                                                                             H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               0 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               0 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0 iso-C.sub.3 H.sub.7                                                                           H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 iso-C.sub.3 H.sub.7                                                                           H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               0 iso-C.sub.3 H.sub.7                                                                           H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               0 iso-C.sub.3 H.sub.7                                                                           H  H  n-C.sub.4 H.sub.9                         Cl H  CH.sub.3                                                                               0 iso-C.sub.3 H.sub.7                                                                           H  H  iso-C.sub.4 H.sub.9                       Cl H  CH.sub.3                                                                               0 iso-C.sub.3 H.sub.7                                                                           H  H  sec-C.sub.4 H.sub.9                       Cl H  CH.sub.3                                                                               0 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               0 n-C.sub.4 H.sub.9                                                                             H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0 n-C.sub.4 H.sub.9                                                                             H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 n-C.sub.4 H.sub.9                                                                             H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               0 n-C.sub.4 H.sub.9                                                                             H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               0 CHF.sub.2      H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 CH.sub.2 OCH.sub.3                                                                            H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0 CH.sub.2 OCH.sub.3                                                                            H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 CH.sub.2 OCH.sub.3                                                                            H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               0 CH.sub.2 OCH.sub.3                                                                            H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               0 CH.sub.2 OCH.sub.3                                                                            H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               0 CH.sub.2 OC.sub.2 H.sub.5                                                                     H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0 CH.sub.2 OC.sub.2 H.sub.5                                                                     H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 CH.sub.2 OC.sub.2 H.sub.5                                                                     H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               0 CH.sub.2 OC.sub.2 H.sub.5                                                                     H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               0 CH.sub.2 OC.sub.2 H.sub.5                                                                     H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               0 CH.sub.2 SCH.sub.3                                                                            H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0 CH.sub.2 SCH.sub.3                                                                            H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 CH.sub.2 SCH.sub.3                                                                            H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               0 CH.sub.2 SCH.sub.3                                                                            H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               0 CH.sub.2 SCH.sub.3                                                                            H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               0 CH.sub.2 C.sub.6 H.sub.5                                                                      H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                             H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 CH.sub.2 CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                                                    H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 CHO            H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0 CHO            H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 COCH.sub.3     H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0 COCH.sub.3     H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 COCH.sub.3     H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               0 COCH.sub.3     H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               0 COC.sub.2 H.sub.5                                                                             H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0 COC.sub.2 H.sub.5                                                                             H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 COC.sub.2 H.sub.5                                                                             H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               0 COC.sub.2 H.sub.5                                                                             H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               0 COC.sub.2 H.sub.5                                                                             H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               0 COC.sub.3 H.sub.7 -n                                                                          H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0 COC.sub.3 H.sub.7 -n                                                                          H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 COC.sub.3 H.sub.7 -n                                                                          H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               0 COC.sub.3 H.sub.7 -n                                                                          H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               0 COC.sub.3 H.sub.7 -n                                                                          H  H  n-C.sub.4 H.sub.9                         Cl H  CH.sub.3                                                                               0 COC.sub.3 H.sub.7 -n                                                                          H  H  sec-C.sub.4 H.sub.9                       Cl H  CH.sub.3                                                                               0 COC.sub.3 H.sub.7 -n                                                                          H  H  iso-C.sub.4 H.sub.9                       Cl H  CH.sub.3                                                                               0 COC.sub.3 H.sub.7 -n                                                                          H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               0 COC.sub.3 H.sub.7 -iso                                                                        H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0 COC.sub.3 H.sub.7 -iso                                                                        H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 COC.sub.3 H.sub.7 -iso                                                                        H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               0 COC.sub.4 H.sub.9 -n                                                                          H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0 COC.sub.4 H.sub.9 -n                                                                          H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 COC.sub.4 H.sub.9 -n                                                                          H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               0 COC.sub.4 H.sub.9 -n                                                                          H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               0                                                                                 ##STR19##     H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0                                                                                 ##STR20##     H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0                                                                                 ##STR21##     H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               0                                                                                 ##STR22##     H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 COC.sub.6 H.sub.5                                                                             H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0 COC.sub.6 H.sub.5                                                                             H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 COC.sub.6 H.sub.5                                                                             H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               0 COC.sub.6 H.sub.5                                                                             H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               0 COC.sub.6 H.sub.5                                                                             H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               0                                                                                 ##STR23##     H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0                                                                                 ##STR24##     H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 COCH═CHC.sub.6 H.sub.5                                                                    H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 COCH.sub.2 OCH.sub.3                                                                          H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0 COCH.sub.2 OCH.sub.3                                                                          H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 COCH.sub.2 OCH.sub.3                                                                          H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               1 H              H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               1 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               1 H              H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               1 H              H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               1 H              H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               1 H              H  H  iso-C.sub.4 H.sub.9                       Cl H  CH.sub.3                                                                               1 H              H  H  tert-C.sub.4 H.sub.9                      Cl H  CH.sub.3                                                                               1 H              2-Cl                                                                              H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               1 H              2-F                                                                               H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               1 H              3-F                                                                               H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               1 H              3-Cl                                                                              H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               1 CH.sub.3       H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               1 C.sub.2 H.sub.5                                                                               H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               1 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               1 C.sub.2 H.sub.5                                                                               H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               1 C.sub.2 H.sub.5                                                                               H  H  n-C.sub.4 H.sub.9                         Cl H  CH.sub.3                                                                               1 C.sub.2 H.sub.5                                                                               H  H  sec-C.sub.4 H.sub.9                       Cl H  CH.sub.3                                                                               1 C.sub.2 H.sub.5                                                                               H  H  iso-C.sub.4 H.sub.9                       Cl H  CH.sub.3                                                                               1 C.sub.2 H.sub.5                                                                               H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               1 C.sub.2 H.sub.5                                                                               H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               1 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               1 iso-C.sub.3 H.sub.7                                                                           H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               1 iso-C.sub.3 H.sub.7                                                                           H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               1 iso-C.sub.3 H.sub.7                                                                           H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               1 CH.sub.2 OCH.sub.3                                                                            H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               1 CH.sub.2 OCH.sub.3                                                                            H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               1 CH.sub.2 OC.sub.2 H.sub.5                                                                     H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               1 CH.sub.2 OC.sub.2 H.sub.5                                                                     H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               1 CH.sub.2 SCH.sub.3                                                                            H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               1 CH.sub.2 SCH.sub.3                                                                            H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               1 COCH.sub.3     H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               1 COC.sub.2 H.sub.5                                                                             H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               1 COC.sub.2 H.sub.5                                                                             H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               1 COC.sub.2 H.sub.5                                                                             H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               1 COC.sub.2 H.sub.5                                                                             H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               1 COC.sub.3 H.sub.7 -n                                                                          H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               1 COC.sub.3 H.sub.7 -n                                                                          H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               1 COC.sub.3 H.sub.7 -n                                                                          H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               1 COC.sub.3 H.sub.7 -n                                                                          H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               1 COC.sub.3 H.sub.7 -iso                                                                        H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               1 COC.sub.3 H.sub.7 -iso                                                                        H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               1 COC.sub.3 H.sub.7 -iso                                                                        H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               1 COC.sub.3 H.sub.7 -iso                                                                        H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               1                                                                                 ##STR25##     H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               1                                                                                 ##STR26##     H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               1                                                                                 ##STR27##     H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               1                                                                                 ##STR28##     H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               1 COC.sub.6 H.sub.5                                                                             H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               1 COC.sub.6 H.sub.5                                                                             H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               1 COC.sub.6 H.sub.5                                                                             H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               1 COC.sub.6 H.sub.5                                                                             H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               1 COCH.sub.2 OCH.sub.3                                                                          H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               1 COCH.sub.2 OCH.sub.3                                                                          H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               1 COCH.sub.2 OCH.sub.3                                                                          H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               2 H              H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               2 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               2 H              H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               2 H              H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               2 H              H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               2 H              H  H  iso-C.sub.4 H.sub.9                       Cl H  CH.sub.3                                                                               2 H              H  H  sec-C.sub.4 H.sub.9                       Cl H  CH.sub.3                                                                               2 H              H  H  tert-C.sub.4 H.sub.9                      Cl H  CH.sub.3                                                                               2 CH.sub.3       H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               2 C.sub.2 H.sub.5                                                                               H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               2 C.sub.2 H.sub.5                                                                               H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               2 C.sub.2 H.sub.5                                                                               H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               2 C.sub.2 H.sub.5                                                                               H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               2 C.sub.2 H.sub.5                                                                               H  H  n-C.sub.4 H.sub.9                         Cl H  CH.sub.3                                                                               2 C.sub.2 H.sub.5                                                                               H  H  iso-C.sub.4 H.sub.9                       Cl H  CH.sub.3                                                                               2 C.sub.2 H.sub.5                                                                               H  H  sec-C.sub.4 H.sub.9                       Cl H  CH.sub.3                                                                               2 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               2 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               2 iso-C.sub.3 H.sub.7                                                                           H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               2 iso-C.sub.3 H.sub.7                                                                           H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               2 iso-C.sub.3 H.sub.7                                                                           H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               2 CH.sub.2 OCH.sub.3                                                                            H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               2 CH.sub.2 OCH.sub.3                                                                            H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               2 CH.sub.2 OC.sub.2 H.sub.5                                                                     H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               2 CH.sub.2 OC.sub.2 H.sub.5                                                                     H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               2 CH.sub.2 SCH.sub.3                                                                            H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               2 CH.sub.2 SCH.sub.3                                                                            H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               2 COCH.sub.3     H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               2 COC.sub.2 H.sub.5                                                                             H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               2 COC.sub.2 H.sub.5                                                                             H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               2 COC.sub.2 H.sub.5                                                                             H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               2 COC.sub.2 H.sub.5                                                                             H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               2 COC.sub.3 H.sub.7 -n                                                                          H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               2 COC.sub.3 H.sub.7 -n                                                                          H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               2 COC.sub.3 H.sub.7 -n                                                                          H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               2 COC.sub.3 H.sub.7 -n                                                                          H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               2 COC.sub.3 H.sub.7 -iso                                                                        H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               2 COC.sub.3 H.sub.7 -iso                                                                        H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               2 COC.sub.3 H.sub.7 -iso                                                                        H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               2 COC.sub.3 H.sub.7 -iso                                                                        H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               2                                                                                 ##STR29##     H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               2                                                                                 ##STR30##     H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               2                                                                                 ##STR31##     H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               2                                                                                 ##STR32##     H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               2 COC.sub.6 H.sub.5                                                                             H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               2 COC.sub.6 H.sub.5                                                                             H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               2 COC.sub.6 H.sub.5                                                                             H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               2 COC.sub.6 H.sub.5                                                                             H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               2 COCH.sub.2 OCH.sub.3                                                                          H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               2 COCH.sub.2 OCH.sub.3                                                                          H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               2 COCH.sub.2 OCH.sub.3                                                                          H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        0 H              H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        0 H              H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        0 H              H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        0 H              H  H  iso-C.sub.4 H.sub.9                       Cl H  C.sub.2 H.sub.5                                                                        0 H              H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        0 H              H  H  n-C.sub.4 H.sub.9                         Cl H  C.sub.2 H.sub.5                                                                        0 H              H  H  sec-C.sub.4 H.sub.9                       Cl H  C.sub.2 H.sub.5                                                                        0 H              H  H  n-C.sub.5 H.sub.11                        Cl H  C.sub.2 H.sub.5                                                                        0 H              H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        0 H              H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  C.sub.2 H.sub.5                                                                        0 H              2-F                                                                               H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        0 H              3-F                                                                               H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        0 H              2-Cl                                                                              H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        0 H              3-Cl                                                                              H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        0 CH.sub.3       H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        0 CH.sub.3       H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        0 CH.sub.3       H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        0 CH.sub.3       H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        0 C.sub.2 H.sub.5                                                                               H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        0 C.sub.2 H.sub.5                                                                               H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        0 C.sub.2 H.sub.5                                                                               H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        0 C.sub.2 H.sub.5                                                                               H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        0 C.sub.2 H.sub.5                                                                               H  H  n-C.sub.4 H.sub.9                         Cl H  C.sub.2 H.sub.5                                                                        0 C.sub.2 H.sub.5                                                                               H  H  iso-C.sub.4 H.sub.9                       Cl H  C.sub.2 H.sub.5                                                                        0 C.sub.2 H.sub.5                                                                               H  H  sec-C.sub.4 H.sub.9                       Cl H  C.sub.2 H.sub.5                                                                        0 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        0 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        0 n-C.sub.3 H.sub.7                                                                             H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        0 n-C.sub.3 H.sub.7                                                                             H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        0 n-C.sub.3 H.sub.7                                                                             H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        0 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        0 iso-C.sub.3 H.sub.7                                                                           H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        0 iso-C.sub.3 H.sub.7                                                                           H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        0 iso-C.sub.3 H.sub.7                                                                           H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        0 iso-C.sub.3 H.sub.7                                                                           H  H  n-C.sub.4 H.sub.9                         Cl H  C.sub.2 H.sub.5                                                                        0 iso-C.sub.3 H.sub.7                                                                           H  H  iso-C.sub.4 H.sub.9                       Cl H  C.sub.2 H.sub.5                                                                        0 iso-C.sub.3 H.sub.7                                                                           H  H  sec-C.sub.4 H.sub.9                       Cl H  C.sub.2 H.sub.5                                                                        0 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        0 n-C.sub.4 H.sub.9                                                                             H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        0 n-C.sub.4 H.sub.9                                                                             H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        0 n-C.sub.4 H.sub.9                                                                             H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        0 n-C.sub.4 H.sub.9                                                                             H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        0 CH.sub.2 OCH.sub.3                                                                            H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        0 CH.sub.2 OCH.sub.3                                                                            H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        0 CH.sub.2 OCH.sub.3                                                                            H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        0 CH.sub.2 OCH.sub.3                                                                            H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        0 CH.sub.2 OCH.sub.3                                                                            H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        0 CH.sub.2 OC.sub.2 H.sub.5                                                                     H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        0 CH.sub.2 OC.sub.2 H.sub.5                                                                     H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        0 CH.sub.2 OC.sub.2 H.sub.5                                                                     H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        0 CH.sub.2 OC.sub.2 H.sub.5                                                                     H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        0 CH.sub.2 OC.sub.2 H.sub.5                                                                     H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        0 CH.sub.2 SCH.sub.3                                                                            H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        0 CH.sub.2 SCH.sub.3                                                                            H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        0 CH.sub.2 SCH.sub.3                                                                            H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        0 CH.sub.2 SCH.sub.3                                                                            H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        0 CH.sub.2 SCH.sub.3                                                                            H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        0 CHO            H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        0 COCH.sub.3     H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        0 COCH.sub.3     H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        0 COCH.sub.3     H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.2 H.sub.5                                                                             H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.2 H.sub.5                                                                             H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.2 H.sub.5                                                                             H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.2 H.sub.5                                                                             H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.2 H.sub.5                                                                             H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.3 H.sub.7 -n                                                                          H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.3 H.sub.7 -n                                                                          H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.3 H.sub.7 -n                                                                          H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.3 H.sub.7 -n                                                                          H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.3 H.sub.7 -n                                                                          H  H  n-C.sub.4 H.sub.9                         Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.3 H.sub.7 -n                                                                          H  H  iso-C.sub.4 H.sub.9                       Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.3 H.sub.7 -n                                                                          H  H  sec-C.sub.4 H.sub.9                       Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.3 H.sub.7 -n                                                                          H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.3 H.sub.7 -iso                                                                        H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.3 H.sub.7 -iso                                                                        H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.3 H.sub.7 -iso                                                                        H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.4 H.sub.9 -n                                                                          H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.4 H.sub.9 -n                                                                          H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.4 H.sub.9 -n                                                                          H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.4 H.sub.9 -n                                                                          H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        0 COCH.sub.2 OCH.sub.3                                                                          H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        0 COCH.sub.2 OCH.sub.3                                                                          H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        0 COCH.sub.2 OCH.sub.3                                                                          H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        0                                                                                 ##STR33##     H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        0                                                                                 ##STR34##     H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        0                                                                                 ##STR35##     H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.6 H.sub.5                                                                             H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.6 H.sub.5                                                                             H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.6 H.sub.5                                                                             H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.6 H.sub.5                                                                             H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.6 H.sub.5                                                                             H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        0                                                                                 ##STR36##     H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        1 H              H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        1 H              H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        1 H              H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        1 H              H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        1 H              H  H  iso-C.sub.4 H.sub.9                       Cl H  C.sub.2 H.sub.5                                                                        1 H              H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        1 C.sub.2 H.sub.5                                                                               H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        1 C.sub.2 H.sub.5                                                                               H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        1 C.sub.2 H.sub.5                                                                               H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        1 C.sub.2 H.sub.5                                                                               H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        1 C.sub.2 H.sub.5                                                                               H  H  n-C.sub.4 H.sub.9                         Cl H  C.sub.2 H.sub.5                                                                        1 C.sub.2 H.sub.5                                                                               H  H  iso-C.sub.4 H.sub.9                       Cl H  C.sub.2 H.sub.5                                                                        1 C.sub.2 H.sub.5                                                                               H  H  sec-C.sub.4 H.sub.9                       Cl H  C.sub.2 H.sub.5                                                                        1 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        1 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        1 iso-C.sub.3 H.sub.7                                                                           H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        1 iso-C.sub.3 H.sub.7                                                                           H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        1 iso-C.sub.3 H.sub.7                                                                           H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        1 CH.sub.2 OCH.sub.3                                                                            H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        1 CH.sub.2 OC.sub.2 H.sub.5                                                                     H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        1 CH.sub.2 OC.sub.2 H.sub.5                                                                     H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        1 CH.sub.2 SCH.sub.3                                                                            H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        1 CH.sub.2 SCH.sub.3                                                                            H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        1 COC.sub.2 H.sub.5                                                                             H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        1 COC.sub.2 H.sub.5                                                                             H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        1 COC.sub.2 H.sub.5                                                                             H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        1 COC.sub.2 H.sub.5                                                                             H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        1 COC.sub.3 H.sub.7 -n                                                                          H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        1 COC.sub.3 H.sub.7 -n                                                                          H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        1 COC.sub.3 H.sub.7 -n                                                                          H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        1 COC.sub.3 H.sub.7 -n                                                                          H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        1 COC.sub.3 H.sub.7 -iso                                                                        H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        1 COC.sub.3 H.sub.7 -iso                                                                        H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        1 COC.sub.3 H.sub.7 -iso                                                                        H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        1 COC.sub.3 H.sub.7 -iso                                                                        H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        1                                                                                 ##STR37##     H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        1                                                                                 ##STR38##     H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        1                                                                                 ##STR39##     H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        1                                                                                 ##STR40##     H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        1 COCH.sub.2 OCH.sub.3                                                                          H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        1 COCH.sub.2 OCH.sub.3                                                                          H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        1 COCH.sub.2 OCH.sub.3                                                                          H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        1 COC.sub.6 H.sub.5                                                                             H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        1 COC.sub.6 H.sub.5                                                                             H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        1 COC.sub.6 H.sub.5                                                                             H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        1 COC.sub.6 H.sub.5                                                                             H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        2 H              H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        2 H              H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        2 H              H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        2 H              H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        2 H              H  H  iso-C.sub.4 H.sub.9                       Cl H  C.sub.2 H.sub.5                                                                        2 H              H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        2 H              2-F                                                                               H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        2 H              3-F                                                                               H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        2 H              2-Cl                                                                              H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        2 H              3-Cl                                                                              H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        2 C.sub.2 H.sub.5                                                                               H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        2 C.sub.2 H.sub.5                                                                               H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        2 C.sub.2 H.sub.5                                                                               H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        2 C.sub.2 H.sub.5                                                                               H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        2 C.sub.2 H.sub.5                                                                               H  H  n-C.sub.4 H.sub.9                         Cl H  C.sub.2 H.sub.5                                                                        2 C.sub.2 H.sub.5                                                                               H  H  sec-C.sub.4 H.sub.9                       Cl H  C.sub.2 H.sub.5                                                                        2 C.sub.2 H.sub.5                                                                               H  H  iso-C.sub.4 H.sub.9                       Cl H  C.sub.2 H.sub.5                                                                        2 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        2 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        2 iso-C.sub.3 H.sub.7                                                                           H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        2 iso-C.sub.3 H.sub.7                                                                           H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        2 iso-C.sub.3 H.sub.7                                                                           H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        2 CH.sub.2 OCH.sub.3                                                                            H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        2 CH.sub.2 OCH.sub.3                                                                            H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        2 CH.sub.2 OC.sub.2 H.sub.5                                                                     H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        2 CH.sub.2 OC.sub.2 H.sub.5                                                                     H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        2 CH.sub.2 SCH.sub.3                                                                            H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        2 CH.sub.2 SCH.sub.3                                                                            H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        2 CHO            H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        2 COC.sub.2 H.sub.5                                                                             H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        2 COC.sub.2 H.sub.5                                                                             H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        2 COC.sub.2 H.sub.5                                                                             H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        2 COC.sub.2 H.sub.5                                                                             H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        2 COC.sub.3 H.sub.7 -n                                                                          H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        2 COC.sub.3 H.sub.7 -n                                                                          H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        2 COC.sub.3 H.sub.7 -n                                                                          H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        2 COC.sub.3 H.sub.7 -n                                                                          H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        2 COC.sub.3 H.sub.7 -iso                                                                        H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        2 COC.sub.3 H.sub.7 -iso                                                                        H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        2 COC.sub.3 H.sub.7 -iso                                                                        H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        2 COC.sub.3 H.sub.7 -iso                                                                        H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        2                                                                                 ##STR41##     H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        2                                                                                 ##STR42##     H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        2                                                                                 ##STR43##     H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        2                                                                                 ##STR44##     H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        2 COC.sub.6 H.sub.5                                                                             H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        2 COC.sub.6 H.sub.5                                                                             H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        2 COC.sub.6 H.sub.5                                                                             H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        2 COCH.sub.2 OCH.sub.3                                                                          H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        2 COCH.sub.2 OCH.sub.3                                                                          H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        2 COCH.sub.2 OCH.sub.3                                                                          H  H  n-C.sub.3 H.sub.7                         Cl H  n-C.sub.3 H.sub.7                                                                      0 H              H  H  CH.sub.3                                  Cl H  n-C.sub.3 H.sub.7                                                                      0 H              H  H  C.sub.2 H.sub.5                           Cl H  n-C.sub.3 H.sub.7                                                                      0 H              H  H  n-C.sub.3 H.sub.7                         Cl H  n-C.sub.3 H.sub.7                                                                      0 H              H  H  iso-C.sub.4 H.sub.9                       Cl H  n-C.sub.3 H.sub.7                                                                      0 C.sub.2 H.sub.5                                                                               H  H  CH.sub.3                                  Cl H  n-C.sub.3 H.sub.7                                                                      0 C.sub.2 H.sub.5                                                                               H  H  C.sub.2 H.sub.5                           Cl H  n-C.sub.3 H.sub.7                                                                      0 iso-C.sub.3 H.sub.7                                                                           H  H  C.sub.2 H.sub.5                           Cl H  n-C.sub.3 H.sub.7                                                                      0 COC.sub.3 H.sub.7 -n                                                                          H  H  C.sub.2 H.sub.5                           Cl H  n-C.sub.3 H.sub.7                                                                      1 H              H  H  CH.sub.3                                  Cl H  n-C.sub.3 H.sub.7                                                                      1 H              H  H  C.sub.2 H.sub.5                           Cl H  n-C.sub.3 H.sub.7                                                                      1 H              H  H  n-C.sub.3 H.sub.7                         Cl H  n-C.sub.3 H.sub.7                                                                      1 H              H  H  iso-C.sub.3 H.sub.7                       Cl H  n-C.sub.3 H.sub.7                                                                      1 H              H  H  iso-C.sub.4 H.sub.9                       Cl H  n-C.sub.3 H.sub.7                                                                      1 H              H  H  CH.sub.2 CF.sub.3                         Cl H  n-C.sub.3 H.sub.7                                                                      2 H              H  H  CH.sub.3                                  Cl H  n-C.sub.3 H.sub.7                                                                      2 H              H  H  C.sub.2 H.sub.5                           Cl H  n-C.sub.3 H.sub.7                                                                      2 H              H  H  CH.sub.2 CF.sub.3                         Cl H  n-C.sub.3 H.sub.7                                                                      2 H              H  H  n-C.sub.3 H.sub.7                         Cl H  n-C.sub.3 H.sub.7                                                                      2 H              H  H  iso-C.sub.3 H.sub.7                       Cl H  n-C.sub.3 H.sub.7                                                                      2 H              H  H  iso-C.sub.4 H.sub.9                       Cl H  iso-C.sub.3 H.sub.7                                                                    0 H              H  H  CH.sub.3                                  Cl H  iso-C.sub.3 H.sub.7                                                                    0 H              H  H  C.sub.2 H.sub.5                           Cl H  iso-C.sub.3 H.sub.7                                                                    1 H              H  H  CH.sub.3                                  Cl H  iso-C.sub.3 H.sub.7                                                                    1 H              H  H  C.sub.2 H.sub.5                           Cl H  iso-C.sub.3 H.sub.7                                                                    2 H              H  H  CH.sub.3                                  Cl H  iso-C.sub.3 H.sub.7                                                                    2 H              H  H  C.sub.2 H.sub.5                           Cl H  n-C.sub.4 H.sub.9                                                                      0 H              H  H  C.sub.2 H.sub.5                           Cl H  sec-C.sub.4 H.sub.9                                                                    0 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 OCH.sub.3                                                                     0 H              H  H  CH.sub.3                                  Cl H  CH.sub.2 OCH.sub.3                                                                     0 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 OC.sub.2 H.sub.5                                                              0 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 Si(CH.sub.3).sub.3                                                            0 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 F                                                                             0 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 F                                                                             1 H              H  H  CH.sub.3                                  Cl H  CH.sub.2 F                                                                             1 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 F                                                                             1 H              H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.2 F                                                                             1 H              H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.2 F                                                                             1 H              H  H  iso-C.sub.4 H.sub.9                       Cl H  CH.sub.2 F                                                                             1 H              H  H  CH.sub.2 CF.sub.3                         Cl H  CHF.sub.2                                                                              0 H              H  H  CH.sub.3                                  Cl H  CHF.sub.2                                                                              0 H              H  H  C.sub.2 H.sub.5                           Cl H  CHF.sub.2                                                                              0 H              H  H  iso-C.sub.3 H.sub.7                       Cl H  CHF.sub.2                                                                              0 H              H  H  iso-C.sub.4 H.sub.9                       Cl H  CHF.sub.2                                                                              0 H              H  H  n-C.sub.4 H.sub.9                         Cl H  CHF.sub.2                                                                              0 H              H  H  n-C.sub.5 H.sub.11                        Cl H  CHF.sub.2                                                                              0 H              H  H  n-C.sub.6 H.sub.13                        Cl H  CHF.sub.2                                                                              0 H              H  H  CH.sub.2 CF.sub.3                         Cl H  CHF.sub.2                                                                              0 C.sub.2 H.sub.5                                                                               H  H  CH.sub.3                                  Cl H  CHF.sub.2                                                                              0 C.sub.2 H.sub.5                                                                               H  H  C.sub.2 H.sub.5                           Cl H  CHF.sub.2                                                                              0 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.3                                  Cl H  CHF.sub.2                                                                              0 iso-C.sub.3 H.sub.7                                                                           H  H  C.sub.2 H.sub.5                           Cl H  CHF.sub.2                                                                              0 COC.sub.3 H.sub.7 -n                                                                          H  H  C.sub.2 H.sub.5                           Cl H  CHF.sub.2                                                                              1 H              H  H  CH.sub.3                                  Cl H  CHF.sub.2                                                                              1 H              H  H  C.sub.2 H.sub.5                           Cl H  CHF.sub.2                                                                              1 H              H  H  CH.sub.2 CF.sub.3                         Cl H  CHF.sub.2                                                                              1 H              H  H  n-C.sub.3 H.sub.7                         Cl H  CHF.sub.2                                                                              1 H              H  H  iso-C.sub.3 H.sub.7                       Cl H  CHF.sub.2                                                                              1 H              H  H  iso-C.sub.4 H.sub.9                       Cl H  CF.sub.3                                                                               0 H              H  H  CH.sub.3                                  Cl H  CF.sub.3                                                                               0 H              H  H  C.sub.2 H.sub.5                           Cl H  CF.sub.3                                                                               0 H              H  H  CH.sub.2 CF.sub.3                         Cl H  CF.sub.3                                                                               0 H              H  H  iso-C.sub.4 H.sub.9                       Cl H  CF.sub.3                                                                               0 H              H  H  n-C.sub.4 H.sub.9                         Cl H  CF.sub.3                                                                               0 H              H  H  n-C.sub.5 H.sub.11                        Cl H  CF.sub.3                                                                               0 H              H  H  n-C.sub.6 H.sub.13                        Cl H  CH.sub.2 Cl                                                                            0 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 CH.sub.2 F                                                                    0 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 CH.sub.2 F                                                                    0 H              H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.2 CH.sub.2 F                                                                    0 H              H  H  CH.sub.3                                  Cl H  CH.sub.2 CH.sub.2 F                                                                    0 H              H  H  iso-C.sub.4 H.sub.9                       Cl H  CH.sub.2 CH.sub.2 F                                                                    0 H              H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.2 CH.sub.2 F                                                                    1 H              H  H  CH.sub.3                                  Cl H  CH.sub.2 CH.sub.2 F                                                                    1 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 CH.sub.2 F                                                                    1 H              H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.2 CH.sub.2 F                                                                    1 H              H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.2 CH.sub.2 F                                                                    1 H              H  H  iso-C.sub.4 H.sub.9                       Cl H  CH.sub.2 CH.sub.2 F                                                                    1 H              H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.2 CH.sub.2 F                                                                    2 H              H  H  CH.sub.3                                  Cl H  CH.sub.2 CH.sub.2 F                                                                    2 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 CH.sub.2 F                                                                    2 H              H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.2 CH.sub.2 F                                                                    2 H              H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.2 CH.sub.2 F                                                                    2 H              H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.2 CH.sub.2 F                                                                    2 H              H  H  iso-C.sub.4 H.sub.9                       Cl H  CH.sub.2 CHF.sub.2                                                                     0 H              H  H  CH.sub.3                                  Cl H  CH.sub.2 CHF.sub.2                                                                     0 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 CHF.sub.2                                                                     0 H              H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.2 CHF.sub.2                                                                     0 H              H  H  iso-C.sub.4 H.sub.9                       Cl H  CH.sub.2 CHF.sub.2                                                                     0 H              H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.2 CHF.sub.2                                                                     1 H              H  H  CH.sub.3                                  Cl H  CH.sub.2 CHF.sub.2                                                                     1 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 CHF.sub.2                                                                     1 H              H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.2 CHF.sub.2                                                                     1 H              H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.2 CHF.sub.2                                                                     1 H              H  H  iso-C.sub.4 H.sub.9                       Cl H  CH.sub.2 CHF.sub.2                                                                     1 H              H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.2 CHF.sub.2                                                                     2 H              H  H  CH.sub.3                                  Cl H  CH.sub.2 CHF.sub.2                                                                     2 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 CHF.sub.2                                                                     2 H              H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.2 CHF.sub.2                                                                     2 H              H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.2 CHF.sub.2                                                                     2 H              H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.2 CHF.sub.2                                                                     2 H              H  H  iso-C.sub.4 H.sub.9                       Cl H  CH.sub.2 CF.sub.3                                                                      0 C.sub.2 H.sub.5                                                                               H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 CF.sub.3                                                                      0 COC.sub.3 H.sub.7 -n                                                                          H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 CF.sub.3                                                                      0 iso-C.sub.3 H.sub.7                                                                           H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 CF.sub.3                                                                      0 H              H  H  CH.sub.3                                  Cl H  CH.sub.2 CF.sub.3                                                                      0 C.sub.2 H.sub.5                                                                               H  H  CH.sub.3                                  Cl H  CH.sub.2 CF.sub.3                                                                      0 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 CF.sub.3                                                                      0 H              H  H  n-C.sub.4 H.sub.9                         Cl H  CH.sub.2 CF.sub.3                                                                      0 H              H  H  iso-C.sub.4 H.sub.9                       Cl H  CH.sub.2 CF.sub.3                                                                      0 H              H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.2 CF.sub.3                                                                      1 H              H  H  CH.sub.3                                  Cl H  CH.sub.2 CF.sub.3                                                                      1 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 CF.sub.3                                                                      1 H              H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.2 CF.sub.3                                                                      1 H              H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.2 CF.sub.3                                                                      1 H              H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.2 CF.sub.3                                                                      1 H              H  H  iso-C.sub.4 H.sub.9                       Cl H  CH.sub.2 CF.sub.3                                                                      2 H              H  H  CH.sub.3                                  Cl H  CH.sub.2 CF.sub.3                                                                      2 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 CF.sub.3                                                                      2 H              H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.2 CF.sub.3                                                                      2 H              H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.2 CF.sub.3                                                                      2 H              H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.2 CF.sub.3                                                                      2 H              H  H  iso-C.sub.4 H.sub.9                       Cl H  CH.sub.2 CH.sub.2 Cl                                                                   0 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 CH.sub.2 Cl                                                                   2 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 CH.sub.2 CH.sub.3 F                                                           0 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 CH.sub.2 CH.sub.3 F                                                           2 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 CF.sub.2 CF.sub.2 H                                                           0 H              H  H  C.sub.2 H.sub.5                           Cl H  CF.sub.2 CF.sub.2 CF.sub.3                                                             0 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 CH.sub.2 CH.sub.2 Cl                                                          0 H              H  H  C.sub.2 H.sub.5                           Cl H  CH═CH.sub.2                                                                        0 H              H  H  CH.sub.3                                  Cl H  CH═CH.sub.2                                                                        0 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 CH═CH.sub.2                                                               0 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 CH═CH.sub.2                                                               1 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 CH═CH.sub.2                                                               2 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 C.tbd.CH                                                                      0 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 C.tbd.CH                                                                      0 H              H  H  CH.sub.3                                  Cl H  CH.sub.2 C.tbd.CH                                                                      1 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 C.tbd.CH                                                                      2 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 CN                                                                            0 H              H  H  CH.sub.3                                  Cl H  CH.sub.2 CN                                                                            0 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 CN                                                                            1 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 CN                                                                            2 H              H  H  C.sub.2 H.sub.5                           Cl CH.sub.3                                                                          CH.sub.3                                                                               0 H              H  H  CH.sub.3                                  Cl CH.sub.3                                                                          CH.sub.3                                                                               0 H              H  H  C.sub.2 H.sub.5                           Cl CH.sub.3                                                                          CH.sub.3                                                                               0 H              H  H  iso-C.sub.4 H.sub.9                       Cl CH.sub.3                                                                          CH.sub.3                                                                               0 H              H  H  n-C.sub.4 H.sub.9                         Cl CH.sub.3                                                                          CH.sub.3                                                                               0 H              H  H  CH.sub.2 CF.sub.3                         Cl CH.sub.3                                                                          CH.sub.3                                                                               1 H              H  H  CH.sub.3                                  Cl CH.sub.3                                                                          CH.sub.3                                                                               1 H              H  H  C.sub.2 H.sub.5                           Cl CH.sub.3                                                                          CH.sub.3                                                                               1 H              H  H  iso-C.sub.4 H.sub.9                       Cl CH.sub.3                                                                          CH.sub.3                                                                               1 H              H  H  CH.sub.2 CF.sub.3                         Cl CH.sub.3                                                                          CH.sub.3                                                                               2 H              H  H  CH.sub.3                                  Cl CH.sub.3                                                                          CH.sub.3                                                                               2 H              H  H  C.sub.2 H.sub.5                           Cl CH.sub.3                                                                          CH.sub.3                                                                               2 H              H  H  iso-C.sub.4 H.sub.9                       Cl CH.sub.3                                                                          CH.sub.3                                                                               2 H              H  H  CH.sub.2 CF.sub.3                         Cl C.sub.2 H.sub.5                                                                   CH.sub.3                                                                               0 H              H  H  CH.sub.3                                  Cl C.sub.2 H.sub.5                                                                   CH.sub.3                                                                               0 H              H  H  C.sub.2 H.sub.5                           Cl C.sub.2 H.sub.5                                                                   CH.sub.3                                                                               1 H              H  H  C.sub.2 H.sub.5                           Cl C.sub.2 H.sub.5                                                                   CH.sub.3                                                                               2 H              H  H  C.sub.2 H.sub.5                           Cl n-C.sub.3 H.sub.7                                                                 CH.sub.3                                                                               0 H              H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               0 H              H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               0 H              H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               0 H              H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               0 H              H  H  iso-C.sub.3 H.sub.7                       Br H  CH.sub.3                                                                               0 H              H  H  n-C.sub.4 H.sub.9                         Br H  CH.sub.3                                                                               0 H              H  H  sec-C.sub.4 H.sub.9                       Br H  CH.sub.3                                                                               0 H              H  H  iso-C.sub.4 H.sub.9                       Br H  CH.sub.3                                                                               0 H              H  H  tert-C.sub.4 H.sub.9                      Br H  CH.sub.3                                                                               0 H              H  H  n-C.sub.5 H.sub.11                        Br H  CH.sub.3                                                                               0 H              H  H  n-C.sub.6 H.sub.13                        Br H  CH.sub.3                                                                               0 H              H  H  CH.sub.2 C.tbd.CH                         Br H  CH.sub.3                                                                               0 H              H  H  CH.sub.2 C.sub.6 H.sub.5                  Br H  CH.sub.3                                                                               0 H              H  H  CH.sub.2 CF.sub.3                         Br H  CH.sub.3                                                                               0 CH.sub.3       H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               0 CH.sub.3       H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               0 C.sub.2 H.sub.5                                                                               H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               0 C.sub.2 H.sub.5                                                                               H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               0 C.sub.2 H.sub.5                                                                               H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               0 C.sub.2 H.sub.5                                                                               H  H  iso-C.sub.3 H.sub.7                       Br H  CH.sub.3                                                                               0 C.sub.2 H.sub.5                                                                               H  H  n-C.sub.4 H.sub.9                         Br H  CH.sub.3                                                                               0 C.sub.2 H.sub.5                                                                               H  H  iso-C.sub.4 H.sub.9                       Br H  CH.sub.3                                                                               0 C.sub.2 H.sub.5                                                                               H  H  sec-C.sub.4 H.sub.9                       Br H  CH.sub.3                                                                               0 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 CF.sub.3                         Br H  CH.sub.3                                                                               0 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               0 iso-C.sub.3 H.sub.7                                                                           H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               0 iso-C.sub.3 H.sub.7                                                                           H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               0 iso-C.sub.3 H.sub.7                                                                           H  H  iso-C.sub.3 H.sub.7                       Br H  CH.sub.3                                                                               0 iso-C.sub.3 H.sub.7                                                                           H  H  iso-C.sub.4 H.sub.9                       Br H  CH.sub.3                                                                               0 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.2 CF.sub.3                         Br H  CH.sub.3                                                                               0 CH.sub.2 SCH.sub.3                                                                            H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               0 CH.sub.2 OCH.sub.3                                                                            H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               0 CH.sub.2 OCH.sub.3                                                                            H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               0 CH.sub.2 OC.sub.2 H.sub.5                                                                     H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               0 CH.sub.2 SCH.sub.3                                                                            H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               0 CHO            H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               0 COCH.sub.3     H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               0 COCH.sub.3     H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               0 COC.sub.2 H.sub.5                                                                             H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               0 COC.sub.2 H.sub.5                                                                             H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               0 COC.sub.2 H.sub.5                                                                             H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               0 COC.sub.3 H.sub.7 -n                                                                          H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               0 COC.sub.3 H.sub.7 -n                                                                          H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               0 COC.sub.3 H.sub.7 -n                                                                          H  H  iso-C.sub.3 H.sub.7                       Br H  CH.sub.3                                                                               0 COC.sub.3 H.sub.7 -n                                                                          H  H  iso-C.sub.4 H.sub.9                       Br H  CH.sub.3                                                                               0 COCH.sub.3 -n  H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               0 COCH.sub.2 OCH.sub.3                                                                          H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               0 COC.sub.6 H.sub.5                                                                             H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               0 COC.sub.6 H.sub.5                                                                             H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               0                                                                                 ##STR45##     H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               0 COCH═CHC.sub.6 H.sub.5                                                                    H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               0 COCH.sub.2 OCH.sub.3                                                                          H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               0 COCH.sub.2 OCH.sub.3                                                                          H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               1 H              H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               1 H              H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               1 H              H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               1 H              H  H  iso-C.sub.3 H.sub.7                       Br H  CH.sub.3                                                                               1 H              H  H  iso-C.sub.4 H.sub.9                       Br H  CH.sub.3                                                                               1 H              H  H  CH.sub.2 CF.sub.3                         Br H  CH.sub.3                                                                               1 C.sub.2 H.sub.5                                                                               H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               1 C.sub.2 H.sub.5                                                                               H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               1 C.sub.2 H.sub.5                                                                               H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               1 C.sub.2 H.sub.5                                                                               H  H  iso-C.sub.3 H.sub.7                       Br H  CH.sub.3                                                                               1 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               1 iso-C.sub.3 H.sub.7                                                                           H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               1 iso-C.sub.3 H.sub.7                                                                           H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               1 iso-C.sub.3 H.sub.7                                                                           H  H  iso-C.sub.3 H.sub.7                       Br H  CH.sub.3                                                                               1 COC.sub.2 H.sub.5                                                                             H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               1 COC.sub.2 H.sub.5                                                                             H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               1 COC.sub.3 H.sub.7 -n                                                                          H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               1 COC.sub.3 H.sub.7 -n                                                                          H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               1 COC.sub.2 H.sub.5                                                                             H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               1 COC.sub.3 H.sub.7 -n                                                                          H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               1 COCH.sub.2 OCH.sub.3                                                                          H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               1 COCH.sub.2 OCH.sub.3                                                                          H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               1 COCH.sub.2 OCH.sub.3                                                                          H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               1 COC.sub.3 H.sub.7 -n                                                                          H  H  iso-C.sub.3 H.sub.7                       Br H  CH.sub.3                                                                               2 H              H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               2 H              H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               2 H              H  H  iso-C.sub.3 H.sub.7                       Br H  CH.sub.3                                                                               2 H              H  H  iso-C.sub.4 H.sub.9                       Br H  CH.sub.3                                                                               2 H              H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               2 H              H  H  CH.sub.2 CF.sub.3                         Br H  CH.sub.3                                                                               2 C.sub.2 H.sub.5                                                                               H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               2 C.sub.2 H.sub.5                                                                               H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               2 C.sub.2 H.sub.5                                                                               H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               2 C.sub.2 H.sub.5                                                                               H  H  iso-C.sub.3 H.sub.7                       Br H  CH.sub.3                                                                               2 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               2 iso-C.sub.3 H.sub.7                                                                           H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               2 iso-C.sub.3 H.sub.7                                                                           H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               2 iso-C.sub.3 H.sub.7                                                                           H  H  iso-C.sub.3 H.sub.7                       Br H  CH.sub.3                                                                               2 CH.sub.2 OCH.sub.3                                                                            H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               2 COC.sub.2 H.sub.5                                                                             H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               2 COCH.sub.2 OCH.sub.3                                                                          H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               2 COC.sub.2 H.sub.5                                                                             H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               2 COC.sub.2 H.sub.5                                                                             H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               2 COC.sub.3 H.sub.7 -n                                                                          H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               2 COC.sub.3 H.sub.7 -n                                                                          H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               2 COC.sub.3 H.sub.7 -n                                                                          H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               2 COC.sub.3 H.sub.7 -n                                                                          H  H  iso-C.sub.3 H.sub.7                       Br H  CH.sub.3                                                                               2 COCH.sub.2 OCH.sub.3                                                                          H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               2 COCH.sub.2 OCH.sub.3                                                                          H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               2 COC.sub.6 H.sub.5                                                                             H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        0 H              H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        0 H              H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        0 H              H  H  n-C.sub.3 H.sub.7                         Br H  C.sub.2 H.sub.5                                                                        0 H              H  H  iso-C.sub.4 H.sub.9                       Br H  C.sub.2 H.sub.5                                                                        0 H              H  H  CH.sub.2 CF.sub.3                         Br H  C.sub.2 H.sub.5                                                                        0 CH.sub.3       H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        0 CH.sub.3       H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        0 C.sub.2 H.sub.5                                                                               H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        0 C.sub.2 H.sub.5                                                                               H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        0 C.sub.2 H.sub.5                                                                               H  H  n-C.sub.3 H.sub.7                         Br H  C.sub.2 H.sub.5                                                                        0 C.sub.2 H.sub.5                                                                               H  H  iso-C.sub.3 H.sub.7                       Br H  C.sub.2 H.sub.5                                                                        0 C.sub.2 H.sub.5                                                                               H  H  n-C.sub.4 H.sub.9                         Br H  C.sub.2 H.sub.5                                                                        0 C.sub.2 H.sub.5                                                                               H  H  iso-C.sub.4 H.sub.9                       Br H  C.sub.2 H.sub.5                                                                        0 C.sub.2 H.sub.5                                                                               H  H  sec-C.sub.4 H.sub.9                       Br H  C.sub.2 H.sub.5                                                                        0 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 CF.sub.3                         Br H  C.sub.2 H.sub.5                                                                        0 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        0 iso-C.sub.3 H.sub.7                                                                           H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        0 iso-C.sub.3 H.sub.7                                                                           H  H  n-C.sub.3 H.sub.7                         Br H  C.sub.2 H.sub.5                                                                        0 iso-C.sub.3 H.sub.7                                                                           H  H  iso-C.sub.3 H.sub.7                       Br H  C.sub.2 H.sub.5                                                                        0 iso-C.sub.3 H.sub.7                                                                           H  H  iso-C.sub.4 H.sub.9                       Br H  C.sub.2 H.sub.5                                                                        0 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.2 CF.sub.3                         Br H  C.sub.2 H.sub.5                                                                        0 CH.sub.2 OCH.sub.3                                                                            H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        0 CH.sub.2 OCH.sub.3                                                                            H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        0 CH.sub.2 SCH.sub.3                                                                            H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        0 CH.sub.2 SCH.sub.3                                                                            H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        0 CHO            H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        0 COCH.sub.3     H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        0 COC.sub.2 H.sub.5                                                                             H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        0 COC.sub.2 H.sub.5                                                                             H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        0 COC.sub.2 H.sub.5                                                                             H  H  n-C.sub.3 H.sub.7                         Br H  C.sub.2 H.sub.5                                                                        0 COC.sub.2 H.sub.5                                                                             H  H  iso-C.sub.3 H.sub.7                       Br H  C.sub.2 H.sub.5                                                                        0 COC.sub.3 H.sub.7 -n                                                                          H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        0 COC.sub.3 H.sub.7 -n                                                                          H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        0 COC.sub.3 H.sub.7 -n                                                                          H  H  n-C.sub.3 H.sub.7                         Br H  C.sub.2 H.sub.5                                                                        0 COC.sub.3 H.sub.7 -n                                                                          H  H  iso-C.sub.3 H.sub.7                       Br H  C.sub.2 H.sub.5                                                                        0 COC.sub.3 H.sub.7 -n                                                                          H  H  iso-C.sub.4 H.sub.9                       Br H  C.sub.2 H.sub.5                                                                        0 COCH.sub.2 OCH.sub.3                                                                          H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        0 COCH.sub.2 OCH.sub.3                                                                          H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        0 COCH.sub.2 OCH.sub.3                                                                          H  H  n-C.sub.3 H.sub.7                         Br H  C.sub.2 H.sub.5                                                                        0 COC.sub.6 H.sub.5                                                                             H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        0 COC.sub.6 H.sub.5                                                                             H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        1 H              H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        1 H              H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        1 H              H  H  n-C.sub.3 H.sub.7                         Br H  C.sub.2 H.sub.5                                                                        1 H              H  H  iso-C.sub.3 H.sub.7                       Br H  C.sub.2 H.sub.5                                                                        1 H              H  H  iso-C.sub.4 H.sub.9                       Br H  C.sub.2 H.sub.5                                                                        1 H              H  H  CH.sub.2 CF.sub.3                         Br H  C.sub.2 H.sub.5                                                                        1 C.sub.2 H.sub.5                                                                               H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        1 C.sub.2 H.sub.5                                                                               H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        1 C.sub.2 H.sub.5                                                                               H  H  n-C.sub.3 H.sub.7                         Br H  C.sub.2 H.sub.5                                                                        1 C.sub.2 H.sub.5                                                                               H  H  iso-C.sub.3 H.sub.7                       Br H  C.sub.2 H.sub.5                                                                        1 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        1 is6-C.sub.3 H.sub.7                                                                           H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        1 iso-C.sub.3 H.sub.7                                                                           H  H  n-C.sub.3 H.sub.7                         Br H  C.sub.2 H.sub.5                                                                        1 COC.sub.2 H.sub.5                                                                             H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        1 COC.sub.2 H.sub.5                                                                             H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        1 COC.sub.2 H.sub.5                                                                             H  H  n-C.sub.3 H.sub.7                         Br H  C.sub.2 H.sub.5                                                                        1 COC.sub.3 H.sub.7 -n                                                                          H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        1 COC.sub.3 H.sub.7 -n                                                                          H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        1 COC.sub.3 H.sub.7 -n                                                                          H  H  n-C.sub.3 H.sub.7                         Br H  C.sub.2 H.sub.5                                                                        1 COC.sub.3 H.sub.7 -n                                                                          H  H  iso-C.sub.3 H.sub.7                       Br H  C.sub.2 H.sub.5                                                                        1 iso-C.sub.3 H.sub.7                                                                           H  H  iso-C.sub.3 H.sub.7                       Br H  C.sub.2 H.sub.5                                                                        1 COCH.sub.2 OCH.sub.3                                                                          H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        1 COCH.sub.2 OCH.sub.3                                                                          H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        1 COCH.sub.2 OCH.sub.3                                                                          H  H  n-C.sub.3 H.sub.7                         Br H  C.sub.2 H.sub.5                                                                        2 H              H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        2 H              H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        2 H              H  H  n-C.sub.3 H.sub.7                         Br H  C.sub.2 H.sub.5                                                                        2 H              H  H  iso-C.sub.3 H.sub.7                       Br H  C.sub.2 H.sub.5                                                                        2 H              H  H  iso-C.sub.4 H.sub.9                       Br H  C.sub.2 H.sub.5                                                                        2 H              H  H  CH.sub.2 CF.sub.3                         Br H  C.sub.2 H.sub.5                                                                        2 C.sub.2 H.sub.5                                                                               H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        2 C.sub.2 H.sub.5                                                                               H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        2 C.sub.2 H.sub.5                                                                               H  H  n-C.sub.3 H.sub.7                         Br H  C.sub.2 H.sub.5                                                                        2 C.sub.2 H.sub.5                                                                               H  H  iso-C.sub.3 H.sub.7                       Br H  C.sub.2 H.sub.5                                                                        2 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        2 iso-C.sub.3 H.sub.7                                                                           H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        2 iso-C.sub.3 H.sub.7                                                                           H  H  n-C.sub.3 H.sub.7                         Br H  C.sub.2 H.sub.5                                                                        2 iso-C.sub.3 H.sub.7                                                                           H  H  iso-C.sub.3 H.sub.7                       Br H  C.sub.2 H.sub.5                                                                        2 CH.sub.2 OCH.sub.3                                                                            H  H  C.sub.2 H.sub.5 --                        Br H  C.sub.2 H.sub.5                                                                        2 COC.sub.2 H.sub.5                                                                             H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        2 COC.sub.2 H.sub.5                                                                             H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        2 COC.sub.2 H.sub.5                                                                             H  H  n-C.sub.3 H.sub.7                         Br H  C.sub.2 H.sub.5                                                                        2 COC.sub.3 H.sub.7 -n                                                                          H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        2 COC.sub.3 H.sub.7 -n                                                                          H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        2 COC.sub.3 H.sub.7 -n                                                                          H  H  iso-C.sub.3 H.sub.7                       Br H  C.sub.2 H.sub.5                                                                        2 COC.sub.3 H.sub.7 -n                                                                          H  H  n-C.sub.3 H.sub.7                         Br H  C.sub.2 H.sub.5                                                                        2 COCH.sub.2 OCH.sub.3                                                                          H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        2 COCH.sub.2 OCH.sub.3                                                                          H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        2 COCH.sub.2 OCH.sub.3                                                                          H  H  n-C.sub.3 H.sub.7                         Br H  n-C.sub.3 H.sub.7                                                                      0 H              H  H  C.sub.2 H.sub.5                           Br H  n-C.sub.3 H.sub.7                                                                      1 H              H  H  CH.sub.3                                  Br H  n-C.sub.3 H.sub.7                                                                      1 H              H  H  C.sub.2 H.sub.5                           Br H  n-C.sub.3 H.sub.7                                                                      1 H              H  H  n-C.sub.3 H.sub.7                         Br H  n-C.sub.3 H.sub.7                                                                      1 H              H  H  iso-C.sub.3 H.sub.7                       Br H  n-C.sub.3 H.sub.7                                                                      1 H              H  H  iso-C.sub.4 H.sub.9                       Br H  n-C.sub.3 H.sub.7                                                                      1 H              H  H  CH.sub.2 CF.sub.3                         Br H  n-C.sub.3 H.sub.7                                                                      2 H              H  H  CH.sub.3                                  Br H  n-C.sub.3 H.sub.7                                                                      2 H              H  H  C.sub.2 H.sub.5                           Br H  n-C.sub.3 H.sub.7                                                                      2 H              H  H  n-C.sub.3 H.sub.7                         Br H  n-C.sub.3 H.sub.7                                                                      2 H              H  H  iso-C.sub.3 H.sub.7                       Br H  n-C.sub.3 H.sub.7                                                                      2 H              H  H  iso-C.sub.4 H.sub.9                       Br H  n-C.sub.3 H.sub.7                                                                      2 H              H  H  CH.sub.2 CF.sub.3                         Br H  CH.sub.2 CH═CH.sub.2                                                               0 H              H  H  C.sub.2 H.sub.5                           Br H  CH.sub.2 CH═CH.sub.2                                                               2 H              H  H  C.sub.2 H.sub.5                           Br H  CH.sub.2 F                                                                             1 H              H  H  CH.sub.3                                  Br H  CH.sub.2 F                                                                             1 H              H  H  C.sub.2 H.sub.5                           Br H  CH.sub.2 F                                                                             1 H              H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.2 F                                                                             1 H              H  H  iso-C.sub.3 H.sub.7                       Br H  CH.sub.2 F                                                                             1 H              H  H  iso-C.sub.4 H.sub.9                       Br H  CH.sub.2 F                                                                             1 H              H  H  CH.sub.2 CF.sub.3                         Br H  CHF.sub.2                                                                              0 H              H  H  C.sub.2 H.sub.5                           Br H  CHF.sub.2                                                                              0 H              H  H  CH.sub.2 CF.sub.3                         Br H  CHF.sub.2                                                                              0 H              H  H  CH.sub.3                                  Br H  CHF.sub.2                                                                              0 H              H  H  iso-C.sub.4 H.sub.9                       Br H  CHF.sub.2                                                                              0 H              H  H  n-C.sub.3 H.sub.7                         Br H  CHF.sub.2                                                                              1 H              H  H  CH.sub.3                                  Br H  CHF.sub.2                                                                              1 H              H  H  C.sub.2 H.sub.5                           Br H  CHF.sub.2                                                                              1 H              H  H  n-C.sub.3 H.sub.7                         Br H  CHF.sub.2                                                                              1 H              H  H  iso-C.sub.3 H.sub.7                       Br H  CHF.sub.2                                                                              1 H              H  H  iso-C.sub.4 H.sub.9                       Br H  CHF.sub.2                                                                              1 H              H  H  CH.sub.2 CF.sub.3                         Br H  CF.sub.3                                                                               0 H              H  H  C.sub.2 H.sub.5                           Br H  CF.sub.3                                                                               0 H              H  H  CH.sub.2 CF.sub.3                         Br H  CF.sub.3                                                                               0 H              H  H  CH.sub.3                                  Br H  CF.sub.3                                                                               0 H              H  H  iso-C.sub.4 H.sub.9                       Br H  CF.sub.3                                                                               0 H              H  H  n-C.sub.4 H.sub.9                         Br H  CH.sub.2 CH.sub.2 F                                                                    0 H              H  H  CH.sub.3                                  Br H  CH.sub.2 CH.sub.2 F                                                                    0 H              H  H  C.sub.2 H.sub.5                           Br H  CH.sub.2 CH.sub.2 F                                                                    1 H              H  H  CH.sub.3                                  Br H  CH.sub.2 CH.sub.2 F                                                                    1 H              H  H  C.sub.2 H.sub.5                           Br H  CH.sub.2 CH.sub.2 F                                                                    1 H              H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.2 CH.sub.2 F                                                                    1 H              H  H  iso-C.sub.3 H.sub.7                       Br H  CH.sub.2 CH.sub.2 F                                                                    1 H              H  H  iso-C.sub.4 H.sub.9                       Br H  CH.sub.2 CH.sub.2 F                                                                    1 H              H  H  CH.sub.2 CF.sub.3                         Br H  CH.sub.2 CH.sub.2 F                                                                    2 H              H  H  CH.sub.3                                  Br H  CH.sub.2 CH.sub.2 F                                                                    2 H              H  H  C.sub.2 H.sub.5                           Br H  CH.sub.2 CH.sub.2 F                                                                    2 H              H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.2 CH.sub.2 F                                                                    2 H              H  H  iso-C.sub.3 H.sub.7                       Br H  CH.sub.2 CH.sub.2 F                                                                    2 H              H  H  iso-C.sub.4 H.sub.9                       Br H  CH.sub.2 CH.sub.2 F                                                                    2 H              H  H  CH.sub.2 CF.sub.3                         Br H  CH.sub.2 CHF.sub.2                                                                     0 H              H  H  C.sub.2 H.sub.5                           Br H  CH.sub.2 CHF.sub.2                                                                     0 H              H  H  CH.sub.3                                  Br H  CH.sub.2 CHF.sub.2                                                                     1 H              H  H  CH.sub.3                                  Br H  CH.sub.2 CHF.sub.2                                                                     1 H              H  H  C.sub.2 H.sub.5                           Br H  CH.sub.2 CHF.sub.2                                                                     1 H              H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.2 CHF.sub.2                                                                     1 H              H  H  iso-C.sub.3 H.sub.7                       Br H  CH.sub.2 CHF.sub.2                                                                     1 H              H  H  iso-C.sub.4 H.sub.9                       Br H  CH.sub.2 CHF.sub.2                                                                     1 H              H  H  CH.sub.2 CF.sub.3                         Br H  CH.sub.2 CHF.sub.2                                                                     2 H              H  H  C.sub.2 H.sub.5                           Br H  CH.sub.2 CHF.sub.2                                                                     2 H              H  H  CH.sub.3                                  Br H  CH.sub.2 CF.sub.3                                                                      0 H              H  H  C.sub.2 H.sub.5                           Br H  CH.sub.2 CF.sub.3                                                                      0 H              H  H  CH.sub.3                                  Br H  CH.sub.2 CF.sub.3                                                                      0 C.sub.2 H.sub.5                                                                               H  H  C.sub.2 H.sub.5                           Br H  CH.sub.2 CF.sub.3                                                                      0 C.sub.2 H.sub.5                                                                               H  H  CH.sub.3                                  Br H  CH.sub.2 CF.sub.3                                                                      1 H              H  H  CH.sub.3                                  Br H  CH.sub.2 CF.sub.3                                                                      1 H              H  H  C.sub.2 H.sub.5                           Br H  CH.sub.2 CF.sub.3                                                                      1 H              H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.2 CF.sub.3                                                                      1 H              H  H  iso-C.sub.3 H.sub.7                       Br H  CH.sub.2 CF.sub.3                                                                      1 H              H  H  iso-C.sub.4 H.sub.9                       Br H  CH.sub.2 CF.sub.3                                                                      1 H              H  H  CH.sub.2 CF.sub.3                         Br H  CH.sub.2 CF.sub.3                                                                      2 H              H  H  CH.sub.3                                  Br H  CH.sub.2 CF.sub.3                                                                      2 H              H  H  C.sub.2 H.sub.5                           Br H  CH.sub.2 CF.sub.3                                                                      2 H              H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.2 CF.sub.3                                                                      2 H              H  H  iso-C.sub.3 H.sub.7                       Br H  CH.sub.2 CF.sub.3                                                                      2 H              H  H  iso-C.sub.4 H.sub.9                       Br H  CH.sub.2 CF.sub.3                                                                      2 H              H  H  CH.sub.2 CF.sub.3                         Br CH.sub.3                                                                          CH.sub.3                                                                               0 H              H  H  CH.sub.3                                  Br CH.sub.3                                                                          CH.sub.3                                                                               0 H              H  H  C.sub.2 H.sub.5                           Br CH.sub.3                                                                          CH.sub.3                                                                               1 H              H  H  CH.sub.3                                  Br CH.sub.3                                                                          CH.sub.3                                                                               1 H              H  H  C.sub.2 H.sub.5                           Br CH.sub.3                                                                          CH.sub.3                                                                               2 H              H  H  CH.sub.3                                  Br CH.sub.3                                                                          CH.sub.3                                                                               2 H              H  H  C.sub.2 H.sub.5                           I  H  CH.sub.3                                                                               0 H              H  H  CH.sub.3                                  I  H  CH.sub.3                                                                               0 H              H  H  C.sub.2 H.sub.5                           I  H  CH.sub.3                                                                               0 H              H  H  iso-C.sub.4 H.sub.9                       I  H  CH.sub.3                                                                               1 H              H  H  C.sub.2 H.sub.5                           I  H  CH.sub.3                                                                               1 H              H  H  CH.sub.3                                  I  H  CH.sub.3                                                                               1 H              H  H  iso-C.sub.4 H.sub.9                       I  H  CH.sub.3                                                                               2 H              H  H  CH.sub.3                                  I  H  CH.sub.3                                                                               2 H              H  H  C.sub.2 H.sub.5                           I  H  CH.sub.3                                                                               2 H              H  H  iso-C.sub.4 H.sub.9                       I  H  C.sub.2 H.sub.5                                                                        0 H              H  H  C.sub.2 H.sub.5                           I  H  C.sub.2 H.sub.5                                                                        1 H              H  H  CH.sub.3                                  I  H  C.sub.2 H.sub.5                                                                        1 H              H  H  C.sub.2 H.sub.5                           I  H  C.sub.2 H.sub.5                                                                        2 H              H  H  C.sub.2 H.sub.5                           I  H  C.sub.2 H.sub.5                                                                        2 H              H  H  CH.sub.3                                  I  H  CHF.sub.2                                                                              0 H              H  H  C.sub.2 H.sub.5                           I  H  CF.sub.3                                                                               0 H              H  H  C.sub.2 H.sub.5                           I  H  CH.sub.2 CH.sub.2 F                                                                    0 H              H  H  C.sub.2 H.sub.5                           I  H  CH.sub.2 CHF.sub.2                                                                     0 H              H  H  C.sub.2 H.sub.5                           I  H  CH.sub.2 CF.sub.3                                                                      0 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 CH.sub.2 CN    H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0 CH.sub.2 CN    H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 CH═CH.sub.2                                                                               H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0 CH═CH.sub.2                                                                               H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 CH.sub.2 CH═CH.sub.2                                                                      H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0 CH.sub.2 CH═CH.sub.2                                                                      H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 CH.sub.2 C.tbd.CH                                                                             H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0 CH.sub.2 C.tbd.CH                                                                             H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0 CO.sub.2 CH.sub.3                                                                             H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 CO.sub.2 CH.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               0 CO.sub.2 CH.sub.3                                                                             H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               0 CO.sub.2 CH.sub.3                                                                             H  H  n-C.sub.4 H.sub.9                         Cl H  CH.sub.3                                                                               0 CO.sub.2 CH.sub.3                                                                             H  H  iso-C.sub.4 H.sub.9                       Cl H  CH.sub.3                                                                               0 CO.sub.2 CH.sub.3                                                                             H  H  sec-C.sub.4 H.sub.9                       Cl H  CH.sub.3                                                                               0 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               0 CO.sub.2 CH.sub.3                                                                             H  H                                                                                  ##STR46##                                Cl H  CH.sub.3                                                                               0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  n-C.sub.4 H.sub.9                         Cl H  CH.sub.3                                                                               0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  iso-C.sub.4 H.sub.9                       Cl H  CH.sub.3                                                                               0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  sec-C.sub.4 H.sub.9                       Cl H  CH.sub.3                                                                               0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H                                                                                  ##STR47##                                Cl H  CH.sub.3                                                                               1 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               1 CO.sub.2 CH.sub.3                                                                             H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               1 CO.sub.2 CH.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               1 CO.sub.2 CH.sub.3                                                                             H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               1 CO.sub.2 CH.sub.3                                                                             H  H  n-C.sub.4 H.sub.9                         Cl H  CH.sub.3                                                                               1 CO.sub.2 CH.sub.3                                                                             H  H  iso-C.sub.4 H.sub.9                       Cl H  CH.sub.3                                                                               1 CO2 CH.sub.3   H  H  sec-C.sub.4 H.sub.9                       Cl H  CH.sub.3                                                                               1 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               1 CO.sub.2 CH.sub.3                                                                             H  H                                                                                  ##STR48##                                Cl H  CH.sub.3                                                                               1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  n-C.sub.4 H.sub.9                         Cl H  CH.sub.3                                                                               1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  iso-C.sub.4 H.sub.9                       Cl H  CH.sub.3                                                                               1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  sec-C.sub.4 H.sub.9                       Cl H  CH.sub.3                                                                               1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H                                                                                  ##STR49##                                Cl H  CH.sub.3                                                                               2 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               2 CO.sub.2 CH.sub.3                                                                             H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               2 CO.sub.2 CH.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               2 CO.sub.2 CH.sub.3                                                                             H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               2 CO.sub.2 CH.sub.3                                                                             H  H  n-C.sub.4 H.sub.9                         Cl H  CH.sub.3                                                                               2 CO.sub.2 CH.sub.3                                                                             H  H  iso-C.sub.4 H.sub.9                       Cl H  CH.sub.3                                                                               2 CO.sub.2 CH.sub.3                                                                             H  H  sec-C.sub.4 H.sub.9                       Cl H  CH.sub.3                                                                               2 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               2 CO.sub.2 CH.sub.3                                                                             H  H                                                                                  ##STR50##                                Cl H  CH.sub.3                                                                               2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  n-C.sub.4 H.sub.9                         Cl H  CH.sub.3                                                                               2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  iso-C.sub.4 H.sub.9                       Cl H  CH.sub.3                                                                               2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  sec-C.sub.4 H.sub.9                       Cl H  CH.sub.3                                                                               2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H                                                                                  ##STR51##                                Br H  CH.sub.3                                                                               2 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               2 CO.sub.2 CH.sub.3                                                                             H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               2 CO.sub.2 CH.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               2 CO.sub.2 CH.sub.3                                                                             H  H  iso-C.sub.3 H.sub.7                       Br H  CH.sub.3                                                                               2 CO.sub.2 CH.sub.3                                                                             H  H  n-C.sub.4 H.sub.9                         Br H  CH.sub.3                                                                               2 CO.sub.2 CH.sub.3                                                                             H  H  iso-C.sub.4 H.sub.9                       Br H  CH.sub.3                                                                               2 CO.sub.2 CH.sub.3                                                                             H  H  sec-C.sub.4 H.sub.9                       Br H  CH.sub.3                                                                               2 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.2 CF.sub.3                         Br H  CH.sub.3                                                                               2 CO.sub.2 CH.sub.3                                                                             H  H                                                                                  ##STR52##                                Br H  CH.sub.3                                                                               2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  iso-C.sub.3 H.sub.7                       Br H  CH.sub.3                                                                               2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  n-C.sub.4 H.sub.9                         Br H  CH.sub.3                                                                               2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  iso-C.sub.4 H.sub.9                       Br H  CH.sub.3                                                                               2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  sec-C.sub.4 H.sub.9                       Br H  CH.sub.3                                                                               2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  CH.sub.2 CF.sub.3                         Br H  CH.sub.3                                                                               2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H                                                                                  ##STR53##                                Br H  CH.sub.3                                                                               1 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               1 CO.sub.2 CH.sub.3                                                                             H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               1 CO.sub.2 CH.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               1 CO.sub.2 CH.sub.3                                                                             H  H  iso-C.sub.3 H.sub.7                       Br H  CH.sub.3                                                                               1 CO.sub.2 CH.sub.3                                                                             H  H  n-C.sub.4 H.sub.9                         Br H  CH.sub.3                                                                               1 CO.sub.2 CH.sub.3                                                                             H  H  iso-C.sub.4 H.sub.9                       Br H  CH.sub.3                                                                               1 CO.sub.2 CH.sub.3                                                                             H  H  sec-C.sub.4 H.sub.9                       Br H  CH.sub.3                                                                               1 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.2 CF.sub.3                         Br H  CH.sub.3                                                                               1 CO.sub.2 CH.sub.3                                                                             H  H                                                                                  ##STR54##                                Br H  CH.sub.3                                                                               1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  iso-C.sub.3 H.sub.7                       Br H  CH.sub.3                                                                               1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  n-C.sub.4 H.sub.9                         Br H  CH.sub.3                                                                               1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  iso-C.sub.4 H.sub.9                       Br H  CH.sub.3                                                                               1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  sec-C.sub.4 H.sub.9                       Br H  CH.sub.3                                                                               1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  CH.sub.2 CF.sub.3                         Br H  CH.sub.3                                                                               1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H                                                                                  ##STR55##                                Br H  CH.sub.3                                                                               0 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               0 CO.sub.2 CH.sub.3                                                                             H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               0 CO.sub.2 CH.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               0 CO.sub.2 CH.sub.3                                                                             H  H  iso-C.sub.3 H.sub.7                       Br H  CH.sub.3                                                                               0 CO.sub.2 CH.sub.3                                                                             H  H  n-C.sub.4 H.sub.9                         Br H  CH.sub.3                                                                               0 CO.sub.2 CH.sub.3                                                                             H  H  iso-C.sub.4 H.sub.9                       Br H  CH.sub.3                                                                               0 CO.sub.2 CH.sub.3                                                                             H  H  sec-C.sub.4 H.sub.9                       Br H  CH.sub.3                                                                               0 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.2 CF.sub.3                         Br H  CH.sub.3                                                                               0 CO.sub.2 CH.sub.3                                                                             H  H                                                                                  ##STR56##                                Br H  CH.sub.3                                                                               0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  iso-C.sub.3 H.sub.7                       Br H  CH.sub.3                                                                               0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  n-C.sub.4 H.sub.9                         Br H  CH.sub.3                                                                               0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  iso-C.sub.4 H.sub.9                       Br H  CH.sub.3                                                                               0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  sec-C.sub.4 H.sub.9                       Br H  CH.sub.3                                                                               0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  CH.sub.2 CF.sub.3                         Br H  CH.sub.3                                                                               0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H                                                                                  ##STR57##                                Br H  C.sub.2 H.sub.5                                                                        0 C.sub.2 H.sub.5                                                                               H  H                                                                                  ##STR58##                                Br H  C.sub.2 H.sub.5                                                                        0 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  C.sub.2 H.sub.5                                                                        0 CH.sub.3       H  H  CH.sub.2 CF.sub.3                         Br H  C.sub.2 H.sub.5                                                                        0 CH.sub.3       H  H                                                                                  ##STR59##                                Br H  C.sub.2 H.sub.5                                                                        0 CH.sub.3       H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  C.sub.2 H.sub.5                                                                        0 H              H  H  sec-C.sub.4 H.sub.9                       Br H  C.sub.2 H.sub.5                                                                        0 H              H  H                                                                                  ##STR60##                                Br H  C.sub.2 H.sub.5                                                                        0 H              H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  C.sub.2 H.sub.5                                                                        0 iso-C.sub.3 H.sub.7                                                                           H  H                                                                                  ##STR61##                                Br H  C.sub.2 H.sub.5                                                                        0 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  C.sub.2 H.sub.5                                                                        0 iso-C.sub.3 H.sub.7                                                                           H  H  n-C.sub.4 H.sub.9                         Br H  C.sub.2 H.sub.5                                                                        0 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        0 n-C.sub.3 H.sub.7                                                                             H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        0 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 CF.sub.3                         Br H  C.sub.2 H.sub.5                                                                        0 n-C.sub.3 H.sub.7                                                                             H  H                                                                                  ##STR62##                                Br H  C.sub.2 H.sub.5                                                                        0 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  C.sub.2 H.sub.5                                                                        0 n-C.sub.4 H.sub.9                                                                             H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        0 n-C.sub.4 H.sub.9                                                                             H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        1 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 CF.sub.3                         Br H  C.sub.2 H.sub.5                                                                        1 C.sub.2 H.sub.5                                                                               H  H                                                                                  ##STR63##                                Br H  C.sub.2 H.sub.5                                                                        1 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  C.sub.2 H.sub.5                                                                        1 CH.sub.3       H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        1 CH.sub.3       H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        1 CH.sub.3       H  H  CH.sub.2 CF.sub.3                         Br H  C.sub.2 H.sub.5                                                                        1 CH.sub.3       H  H                                                                                  ##STR64##                                Br H  C.sub.2 H.sub.5                                                                        1 CH.sub.3       H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  C.sub.2 H.sub.5                                                                        1 H              H  H  n-C.sub.4 H.sub.9                         Br H  C.sub.2 H.sub.5                                                                        1 H              H  H  sec-C.sub.4 H.sub.9                       Br H  C.sub.2 H.sub.5                                                                        1 H              H  H                                                                                  ##STR65##                                Br H  C.sub.2 H.sub.5                                                                        1 H              H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  C.sub.2 H.sub.5                                                                        1 iso-C.sub.3 H.sub.7                                                                           H  H  iso-C.sub.3 H.sub.7                       Br H  C.sub.2 H.sub.5                                                                        1 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.2 CF.sub.3                         Br H  C.sub.2 H.sub.5                                                                        1 iso-C.sub.3 H.sub.7                                                                           H  H                                                                                  ##STR66##                                Br H  C.sub.2 H.sub.5                                                                        1 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  C.sub.2 H.sub.5                                                                        1 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        1 n-C.sub.3 H.sub.7                                                                             H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        1 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 CF.sub.3                         Br H  C.sub.2 H.sub.5                                                                        1 n-C.sub.3 H.sub.7                                                                             H  H                                                                                  ##STR67##                                Br H  C.sub.2 H.sub.5                                                                        1 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  C.sub.2 H.sub.5                                                                        1 n-C.sub.4 H.sub.9                                                                             H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        1 n-C.sub.4 H.sub.9                                                                             H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        2 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 CF.sub.3                         Br H  C.sub.2 H.sub.5                                                                        2 C.sub.2 H.sub.5                                                                               H  H                                                                                  ##STR68##                                Br H  C.sub.2 H.sub.5                                                                        2 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  C.sub.2 H.sub.5                                                                        2 CH.sub.3       H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        2 CH.sub.3       H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        2 CH.sub.3       H  H  CH.sub.2 CF.sub.3                         Br H  C.sub.2 H.sub.5                                                                        2 CH.sub.3       H  H                                                                                  ##STR69##                                Br H  C.sub.2 H.sub.5                                                                        2 CH.sub.3       H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  C.sub.2 H.sub.5                                                                        2 H              H  H  n-C.sub.4 H.sub.9                         Br H  C.sub.2 H.sub.5                                                                        2 H              H  H  sec-C.sub.4 H.sub.9                       Br H  C.sub.2 H.sub.5                                                                        2 H              H  H                                                                                  ##STR70##                                Br H  C.sub.2 H.sub.5                                                                        2 H              H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  C.sub.2 H.sub.5                                                                        2 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.2 CF.sub.3                         Br H  C.sub.2 H.sub.5                                                                        2 iso-C.sub.3 H.sub.7                                                                           H  H                                                                                  ##STR71##                                Br H  C.sub.2 H.sub.5                                                                        2 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  C.sub.2 H.sub.5                                                                        2 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        2 n-C.sub.3 H.sub.7                                                                             H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        2 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 CF.sub.3                         Br H  C.sub.2 H.sub.5                                                                        2 n-C.sub.3 H.sub.7                                                                             H  H                                                                                  ##STR72##                                Br H  C.sub.2 H.sub.5                                                                        2 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  C.sub.2 H.sub.5                                                                        2 n-C.sub.4 H.sub.9                                                                             H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        2 n-C.sub.4 H.sub.9                                                                             H  H  C.sub.2 H.sub.5                           Br H  CH.sub.2 CF.sub.3                                                                      0 H              H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.2 CF.sub.3                                                                      0 H              H  H  iso-C.sub.3 H.sub.7                       Br H  CH.sub.2 CF.sub.3                                                                      0 H              H  H  iso-C.sub.4 H.sub.9                       Br H  CH.sub.2 CF.sub.3                                                                      0 H              H  H  CH.sub.2 CF.sub.3                         Br H  CH.sub.3                                                                               0 C.sub.2 H.sub.5                                                                               H  H                                                                                  ##STR73##                                Br H  CH.sub.3                                                                               0 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  CH.sub.3                                                                               0 CH.sub.3       H  H  CH.sub.2 CF.sub.3                         Br H  CH.sub.3                                                                               0 CH.sub.3       H  H                                                                                  ##STR74##                                Br H  CH.sub.3                                                                               0 CH.sub.3       H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  CH.sub.3                                                                               0 H              H  H                                                                                  ##STR75##                                Br H  CH.sub.3                                                                               0 H              H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  CH.sub.3                                                                               0 iso-C.sub.3 H.sub.7                                                                           H  H                                                                                  ##STR76##                                Br H  CH.sub.3                                                                               0 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  CH.sub.3                                                                               0 iso-C.sub.3 H.sub.7                                                                           H  H  n-C.sub.4 H.sub.9                         Br H  CH.sub.3                                                                               0 n-C.sub.3 H.sub.7                                                                             H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               0 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               0 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 CF.sub.3                         Br H  CH.sub.3                                                                               0 n-C.sub.3 H.sub.7                                                                             H  H                                                                                  ##STR77##                                Br H  CH.sub.3                                                                               0 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  CH.sub.3                                                                               0 n-C.sub.4 H.sub.9                                                                             H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               0 n-C.sub.4 H.sub.9                                                                             H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               1 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 CF.sub.3                         Br H  CH.sub.3                                                                               1 C.sub.2 H.sub.5                                                                               H  H                                                                                  ##STR78##                                Br H  CH.sub.3                                                                               1 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  CH.sub.3                                                                               1 CH.sub.3       H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               1 CH.sub.3       H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               1 CH.sub.3       H  H  CH.sub.2 CF.sub.3                         Br H  CH.sub.3                                                                               1 CH.sub.3       H  H                                                                                  ##STR79##                                Br H  CH.sub.3                                                                               2 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  CH.sub.3                                                                               2 n-C.sub.3 H.sub.7                                                                             H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               2 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               2 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 CF.sub.3                         Br H  CH.sub.3                                                                               2 n-C.sub.3 H.sub.7                                                                             H  H                                                                                  ##STR80##                                Br H  CH.sub.3                                                                               1 CH.sub.3       H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  CH.sub.3                                                                               1 H              H  H  n-C.sub.4 H.sub.9                         Br H  CH.sub.3                                                                               1 H              H  H  sec-C.sub.4 H.sub.9                       Br H  CH.sub.3                                                                               1 H              H  H                                                                                  ##STR81##                                Br H  CH.sub.3                                                                               1 H              H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  CH.sub.3                                                                               1 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.2 CF.sub.3                         Br H  CH.sub.3                                                                               1 iso-C.sub.3 H.sub.7                                                                           H  H                                                                                  ##STR82##                                Br H  CH.sub.3                                                                               1 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  CH.sub.3                                                                               1 n-C.sub.3 H.sub.7                                                                             H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               1 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               1 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 CF.sub.3                         Br H  CH.sub.3                                                                               1 n-C.sub.3 H.sub.7                                                                             H  H                                                                                  ##STR83##                                Br H  CH.sub.3                                                                               1 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  CH.sub.3                                                                               1 n-C.sub.4 H.sub.9                                                                             H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               1 n-C.sub.4 H.sub.9                                                                             H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               2 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 CF.sub.3                         Br H  CH.sub.3                                                                               2 C.sub.2 H.sub.5                                                                               H  H                                                                                  ##STR84##                                Br H  CH.sub.3                                                                               2 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  CH.sub.3                                                                               2 CH.sub.3       H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               2 CH.sub.3       H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               2 CH.sub.3       H  H  CH.sub.2 CF.sub.3                         Br H  CH.sub.3                                                                               2 CH.sub.3       H  H                                                                                  ##STR85##                                Br H  CH.sub.3                                                                               2 CH.sub.3       H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  CH.sub.3                                                                               2 H              H  H  n-C.sub.4 H.sub.9                         Br H  CH.sub.3                                                                               2 H              H  H  sec-C.sub.4 H.sub.9                       Br H  CH.sub.3                                                                               2 H              H  H                                                                                  ##STR86##                                Br H  CH.sub.3                                                                               2 H              H  H  iso-C.sub.4 H.sub.9                       Br H  CH.sub.3                                                                               2 H              H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  CH.sub.3                                                                               2 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.2 CF.sub.3                         Br H  CH.sub.3                                                                               2 iso-C.sub.3 H.sub.7                                                                           H  H                                                                                  ##STR87##                                Br H  CH.sub.3                                                                               2 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 Si(CH.sub.3).sub.3               Br H  CH.sub.3                                                                               2 n-C.sub.4 H.sub.9                                                                             H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               2 n-C.sub.4 H.sub.9                                                                             H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        0 C.sub.2 H.sub.5                                                                               H  H                                                                                  ##STR88##                                Cl H  C.sub.2 H.sub.5                                                                        0 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  C.sub.2 H.sub.5                                                                        0 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 CF.sub.2 CHF.sub.2               Cl H  C.sub.2 H.sub.5                                                                        0 CH═CH.sub.2                                                                               H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        0 CH.sub.2 CF.sub.3                                                                             H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        0 CH.sub.2 CHF.sub.2                                                                            H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        0 CH.sub.3       H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        0 CH.sub.3       H  H                                                                                  ##STR89##                                Cl H  C.sub.2 H.sub.5                                                                        0 CH.sub.3       H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  C.sub.2 H.sub.5                                                                        0 CH.sub.3       H  H  CH.sub.2 CF.sub.2 CHF.sub.2               Cl H  C.sub.2 H.sub.5                                                                        0 H              H  H                                                                                  ##STR90##                                Cl H  C.sub.2 H.sub.5                                                                        0 H              H  H                                                                                  ##STR91##                                Cl H  C.sub.2 H.sub.5                                                                        0 H              H  H                                                                                  ##STR92##                                Cl H  C.sub.2 H.sub.5                                                                        0 H              H  H  CH.sub.2 CF.sub.2 CHF.sub.2               Cl H  C.sub.2 H.sub.5                                                                        0 iso-C.sub.3 H.sub.7                                                                           H  H                                                                                  ##STR93##                                Cl H  C.sub.2 H.sub.5                                                                        0 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  C.sub.2 H.sub.5                                                                        0 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        0 n-C.sub.3 H.sub.7                                                                             H  H                                                                                  ##STR94##                                Cl H  C.sub.2 H.sub.5                                                                        0 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  C.sub.2 H.sub.5                                                                        0 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 CF.sub.2 CHF.sub.2               Cl H  C.sub.2 H.sub.5                                                                        1 C.sub.2 H.sub.5                                                                               H  H                                                                                  ##STR95##                                Cl H  C.sub.2 H.sub.5                                                                        1 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  C.sub.2 H.sub.5                                                                        1 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 CF.sub.2 CHF.sub.2               Cl H  C.sub.2 H.sub.5                                                                        1 CH.sub.3       H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        1 CH.sub.3       H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        1 CH.sub.3       H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        1 CH.sub.3       H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        1 CH.sub.3       H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        1 CH.sub.3       H  H                                                                                  ##STR96##                                Cl H  C.sub.2 H.sub.5                                                                        1 CH.sub.3       H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  C.sub.2 H.sub.5                                                                        1 H              H  H  n-C.sub.4 H.sub.9                         Cl H  C.sub.2 H.sub.5                                                                        1 H              H  H  sec-C.sub.4 H.sub.9                       Cl H  C.sub.2 H.sub.5                                                                        1 H              H  H                                                                                  ##STR97##                                Cl H  C.sub.2 H.sub.5                                                                        1 H              H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  C.sub.2 H.sub.5                                                                        1 H              H  H  CH.sub.2 CF.sub.2 CHF.sub.2               Cl H  C.sub.2 H.sub.5                                                                        1 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        1 iso-C.sub.3 H.sub.7                                                                           H  H                                                                                  ##STR98##                                Cl H  C.sub.2 H.sub.5                                                                        1 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  C.sub.2 H.sub.5                                                                        1 n-C.sub.3 H.sub.7                                                                             H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        1 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        1 n-C.sub.3 H.sub.7                                                                             H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        1 n-C.sub.3 H.sub.7                                                                             H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        1 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        1 n-C.sub.3 H.sub.7                                                                             H  H                                                                                  ##STR99##                                Cl H  C.sub.2 H.sub.5                                                                        1 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  C.sub.2 H.sub.5                                                                        1 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 CF.sub.2 CHF.sub.2               Cl H  C.sub.2 H.sub.5                                                                        1 n-C.sub.4 H.sub.9                                                                             H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        1 n-C.sub.4 H.sub.9                                                                             H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        2 C.sub.2 H.sub.5                                                                               H  H                                                                                  ##STR100##                               Cl H  C.sub.2 H.sub.5                                                                        2 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  C.sub.2 H.sub.5                                                                        2 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 CF.sub.2 CHF.sub.2               Cl H  C.sub.2 H.sub.5                                                                        2 CH.sub.3       H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        2 CH.sub.3       H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        2 CH.sub.3       H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        2 CH.sub.3       H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        2 CH.sub.3       H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        2 CH.sub.3       H  H                                                                                  ##STR101##                               Cl H  C.sub.2 H.sub.5                                                                        2 CH.sub.3       H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  C.sub.2 H.sub.5                                                                        2 H              H  H  n-C.sub.4 H.sub.9                         Cl H  C.sub.2 H.sub.5                                                                        2 H              H  H  iso-C.sub.4 H.sub.9                       Cl H  C.sub.2 H.sub.5                                                                        2 H              H  H  sec-C.sub.4 H.sub.9                       Cl H  C.sub.2 H.sub.5                                                                        2 H              H  H                                                                                  ##STR102##                               Cl H  C.sub.2 H.sub.5                                                                        2 H              H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  C.sub.2 H.sub.5                                                                        2 H              H  H  CH.sub.2 CF.sub.2 CHF.sub.2               Cl H  C.sub.2 H.sub.5                                                                        2 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        2 iso-C.sub.3 H.sub.7                                                                           H  H                                                                                  ##STR103##                               Cl H  C.sub.2 H.sub.5                                                                        2 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  C.sub.2 H.sub.5                                                                        2 n-C.sub.3 H.sub.7                                                                             H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        2 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        2 n-C.sub.3 H.sub.7                                                                             H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        2 n-C.sub.3 H.sub.7                                                                             H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        2 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        2 n-C.sub.3 H.sub.7                                                                             H  H                                                                                  ##STR104##                               Cl H  C.sub.2 H.sub.5                                                                        2 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  C.sub.2 H.sub.5                                                                        2 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 CF.sub.2 CHF.sub.2               Cl H  C.sub.2 H.sub.5                                                                        2 n-C.sub.4 H.sub.9                                                                             H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        2 n-C.sub.4 H.sub.9                                                                             H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 CH═CHCH.sub.3                                                             0 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 CH.sub.2 CH.sub.3 F                                                           1 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.2 CH.sub.2 Cl                                                                   1 H              H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 C.sub.2 H.sub.5                                                                               H  H                                                                                  ##STR105##                               Cl H  CH.sub.3                                                                               0 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  CH.sub.3                                                                               0 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 CF.sub.2 CHF.sub.2               Cl H  CH.sub.3                                                                               0 CH.sub.2 C.tbd.CH                                                                             H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 CH.sub.2 CH═CH.sub.2                                                                      H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 CH.sub.2 CH.sub.2 Cl                                                                          H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 CH.sub.2 CH.sub.3 F                                                                           H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 CH.sub.2 CN    H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 CH.sub.3       H  H  n-C.sub.4 H.sub.9                         Cl H  CH.sub.3                                                                               0 CH.sub.3       H  H  iso-C.sub.4 H.sub.9                       Cl H  CH.sub.3                                                                               0 CH.sub.3       H  H  sec-C.sub.4 H.sub.9                       Cl H  CH.sub.3                                                                               0 CH.sub.3       H  H                                                                                  ##STR106##                               Cl H  CH.sub.3                                                                               0 CH.sub.3       H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  CH.sub.3                                                                               0 CH.sub.3       H  H  CH.sub.2 CF.sub.2 CHF.sub.2               Cl H  CH.sub.3                                                                               0 H              H  H                                                                                  ##STR107##                               Cl H  CH.sub.3                                                                               0 H              H  H  CH.sub.2 CF.sub.2 CHF.sub.2               Cl H  CH.sub.3                                                                               0 iso-C.sub.3 H.sub.7                                                                           H  H                                                                                  ##STR108##                               Cl H  CH.sub.3                                                                               0 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  CH.sub.3                                                                               0 iso-C.sub.4 H.sub.9                                                                           H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 iso-C.sub.4 H.sub.9                                                                           H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0 n-C.sub.3 H.sub.7                                                                             H  H                                                                                  ##STR109##                               Cl H  CH.sub.3                                                                               0 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  CH.sub.3                                                                               0 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 CF.sub.2 CHF.sub.2               Cl H  CH.sub.3                                                                               0 n-C.sub.6 H.sub.13                                                                            H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               0 n-C.sub.7 H.sub.15                                                                            H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               1 C.sub.2 H.sub.5                                                                               H  H                                                                                  ##STR110##                               Cl H  CH.sub.3                                                                               1 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  CH.sub.3                                                                               1 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 CF.sub.2 CHF.sub.2               Cl H  CH.sub.3                                                                               1 CH.sub.3       H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               1 CH.sub.3       H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               1 CH.sub.3       H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               1 CH.sub.3       H  H                                                                                  ##STR111##                               Cl H  CH.sub.3                                                                               1 CH.sub.3       H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  CH.sub.3                                                                               1 H              H  H  n-C.sub.4 H.sub.9                         Cl H  CH.sub.3                                                                               1 H              H  H  sec-C.sub.4 H.sub.9                       Cl H  CH.sub.3                                                                               1 H              H  H                                                                                  ##STR112##                               Cl H  CH.sub.3                                                                               1 H              H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  CH.sub.3                                                                               1 H              H  H  CH.sub.2 CF.sub.2 CHF.sub.2               Cl H  CH.sub.3                                                                               1 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               1 iso-C.sub.3 H.sub.7                                                                           H  H                                                                                  ##STR113##                               Cl H  CH.sub.3                                                                               1 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  CH.sub.3                                                                               1 n-C.sub.3 H.sub.7                                                                             H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               1 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               1 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               1 n-C.sub.3 H.sub.7                                                                             H  H                                                                                  ##STR114##                               Cl H  CH.sub.3                                                                               1 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  CH.sub.3                                                                               1 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 CF.sub.2 CHF.sub.2               Cl H  CH.sub.3                                                                               1 n-C.sub.4 H.sub.9                                                                             H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               1 n-C.sub.4 H.sub.9                                                                             H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               2 C.sub.2 H.sub.5                                                                               H  H                                                                                  ##STR115##                               Cl H  CH.sub.3                                                                               2 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  CH.sub.3                                                                               2 C.sub.2 H.sub.5                                                                               H  H  CH.sub.2 CF.sub.2 CHF.sub.2               Cl H  CH.sub.3                                                                               2 CH.sub.3       H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               2 CH.sub.3       H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               2 CH.sub.3       H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               2 CH.sub.3       H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               2 CH.sub.3       H  H                                                                                  ##STR116##                               Cl H  CH.sub.3                                                                               2 CH.sub.3       H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  CH.sub.3                                                                               2 H              H  H  n-C.sub.4 H.sub.9                         Cl H  CH.sub.3                                                                               2 H              H  H                                                                                  ##STR117##                               Cl H  CH.sub.3                                                                               2 H              H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  CH.sub.3                                                                               2 H              H  H  CH.sub.2 CF.sub.2 CHF.sub.2               Cl H  CH.sub.3                                                                               2 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               2 iso-C.sub.3 H.sub.7                                                                           H  H                                                                                  ##STR118##                               Cl H  CH.sub.3                                                                               2 iso-C.sub.3 H.sub.7                                                                           H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  CH.sub.3                                                                               2 n-C.sub.3 H.sub.7                                                                             H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               2 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               2 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               2 n-C.sub.3 H.sub.7                                                                             H  H                                                                                  ##STR119##                               Cl H  CH.sub.3                                                                               2 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 Si(CH.sub.3).sub.3               Cl H  CH.sub.3                                                                               2 n-C.sub.3 H.sub.7                                                                             H  H  CH.sub.2 CF.sub.2 CHF.sub.2               Cl H  CH.sub.3                                                                               2 n-C.sub.4 H.sub.9                                                                             H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               2 n-C.sub.4 H.sub.9                                                                             H  H  CH.sub.3                                  Cl H  CN.sub.3                                                                               0 H              H  H  C.sub.2 H.sub.5                           Cl H  CSOC.sub.2 H.sub.3                                                                     0 H              H  H  C.sub.2 H.sub.5                           Cl H  COCH.sub.3                                                                             0 H              H  H  C.sub.2 H.sub.5                           Cl H  sec-C.sub.4 H.sub.9                                                                    0 H              H  H  CH.sub.3                                  F  H  n-C.sub.3 H.sub.7                                                                      0 H              H  H  C.sub.2 H.sub.5                           F  H  n-C.sub.3 H.sub.7                                                                      0 H              H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               0 CO.sub.2 CH.sub.3                                                                             H  H                                                                                  ##STR120##                               Cl H  CH.sub.3                                                                               1 CO.sub.2 CH.sub.3                                                                             H  H                                                                                  ##STR121##                               Cl H  CH.sub.3                                                                               2 CO.sub.2 CH.sub.3                                                                             H  H                                                                                  ##STR122##                               Cl H  CH.sub.3                                                                               0 CO.sub.2 CH.sub.3                                                                             H  H                                                                                  ##STR123##                               Cl H  CH.sub.3                                                                               1 CO.sub.2 CH.sub.3                                                                             H  H                                                                                  ##STR124##                               Cl H  CH.sub.3                                                                               2 CO.sub.2 CH.sub.3                                                                             H  H                                                                                  ##STR125##                               Cl H  CH.sub.3                                                                               0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H                                                                                  ##STR126##                               Cl H  CH.sub.3                                                                               1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H                                                                                  ##STR127##                               Cl H  CH.sub.3                                                                               2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H                                                                                  ##STR128##                               Cl H  CH.sub.3                                                                               0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H                                                                                  ##STR129##                               Cl H  CH.sub.3                                                                               1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H                                                                                  ##STR130##                               Cl H  CH.sub.3                                                                               2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H                                                                                  ##STR131##                               Cl H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 CH.sub.3                                                                             H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 CH.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 CH.sub.3                                                                             H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 CH.sub.3                                                                             H  H  n-C.sub.4 H.sub.9                         Cl H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 CH.sub.3                                                                             H  H  iso-C.sub.4 H.sub.9                       Cl H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 CH.sub.3                                                                             H  H  sec-C.sub.4 H.sub.9                       Cl H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 CH.sub.3                                                                             H  H                                                                                  ##STR132##                               Cl H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  n-C.sub.4 H.sub.9                         Cl H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  iso-C.sub.4 H.sub.9                       Cl H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  sec-C.sub.4 H.sub.9                       Cl H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H                                                                                  ##STR133##                               Cl H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 CH.sub.3                                                                             H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 CH.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 CH.sub.3                                                                             H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 CH.sub.3                                                                             H  H  n-C.sub.4 H.sub.9                         Cl H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 CH.sub.3                                                                             H  H  iso-C.sub.4 H.sub.9                       Cl H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 CH.sub.3                                                                             H  H  sec-C.sub.4 H.sub.9                       Cl H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 CH.sub.3                                                                             H  H                                                                                  ##STR134##                               Cl H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  n-C.sub.4 H.sub.9                         Cl H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  iso-C.sub.4 H.sub.9                       Cl H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  sec-C.sub.4 H.sub.9                       Cl H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H                                                                                  ##STR135##                               Cl H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 CH.sub.3                                                                             H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 CH.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 CH.sub.3                                                                             H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 CH.sub.3                                                                             H  H  n-C.sub.4 H.sub.9                         Cl H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 CH.sub.3                                                                             H  H  iso-C.sub.4 H.sub.9                       Cl H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 CH.sub.3                                                                             H  H  sec-C.sub.4 H.sub.9                       Cl H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 CH.sub.3                                                                             H  H                                                                                  ##STR136##                               Cl H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  n-C.sub.4 H.sub.9                         Cl H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  iso-C.sub.4 H.sub.9                       Cl H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  sec-C.sub.4 H.sub.9                       Cl H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H                                                                                  ##STR137##                               Br H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 CH.sub.3                                                                             H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 CH.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                         Br H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 CH.sub.3                                                                             H  H  iso-C.sub.3 H.sub.7                       Br H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 CH.sub.3                                                                             H  H  n-C.sub.4 H.sub.9                         Br H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 CH.sub.3                                                                             H  H  iso-C.sub.4 H.sub.9                       Br H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 CH.sub.3                                                                             H  H  sec-C.sub.4 H.sub.9                       Br H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.2 CF.sub.3                         Br H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 CH.sub.3                                                                             H  H                                                                                  ##STR138##                               Br H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  n-C.sub.3 H.sub.7                         Br H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  iso-C.sub.3 H.sub.7                       Br H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  n-C.sub.4 H.sub.9                         Br H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  iso-C.sub.4 H.sub.9                       Br H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  sec-C.sub.4 H.sub.9                       Br H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  CH.sub.2 CF.sub.3                         Br H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H                                                                                  ##STR139##                               Br H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 CH.sub.3                                                                             H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 CH.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                         Br H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 CH.sub.3                                                                             H  H  iso-C.sub.3 H.sub.7                       Br H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 CH.sub.3                                                                             H  H  n-C.sub.4 H.sub.9                         Br H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 CH.sub.3                                                                             H  H  iso-C.sub.4 H.sub.9                       Br H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 CH.sub.3                                                                             H  H  sec-C.sub.4 H.sub.9                       Br H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.2 CF.sub.3                         Br H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 CH.sub.3                                                                             H  H                                                                                  ##STR140##                               Br H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  n-C.sub.3 H.sub.7                         Br H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  iso-C.sub.3 H.sub.7                       Br H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  n-C.sub.4 H.sub.9                         Br H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  iso-C.sub.4 H.sub.9                       Br H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  sec-C.sub.4 H.sub.9                       Br H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  CH.sub.2 CF.sub.3                         Br H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H                                                                                  ##STR141##                               Br H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 CH.sub.3                                                                             H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 CH.sub.3                                                                             H  H  n-C.sub.3 H.sub.7                         Br H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 CH.sub.3                                                                             H  H  iso-C.sub.3 H.sub.7                       Br H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 CH.sub.3                                                                             H  H  n-C.sub.4 H.sub.9                         Br H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 CH.sub.3                                                                             H  H  iso-C.sub.4 H.sub.9                       Br H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 CH.sub.3                                                                             H  H  sec-C.sub.4 H.sub.9                       Br H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.2 CF.sub.3                         Br H  C.sub.2 H.sub.5                                                                        a CO.sub.2 CH.sub.3                                                                             H  H                                                                                  ##STR142##                               Br H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  n-C.sub.3 H.sub.7                         Br H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  iso-C.sub.3 H.sub.7                       Br H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  n-C.sub.4 H.sub.9                         Br H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  iso-C.sub.4 H.sub.9                       Br H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  sec-C.sub.4 H.sub.9                       Br H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  CH.sub.2 CF.sub.3                         Br H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H                                                                                  ##STR143##                               Cl H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 CH.sub.3                                                                             H  H                                                                                  ##STR144##                               Cl H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 CH.sub.3                                                                             H  H                                                                                  ##STR145##                               Cl H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 CH.sub.3                                                                             H  H                                                                                  ##STR146##                               Cl H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 CH.sub.3                                                                             H  H                                                                                  ##STR147##                               Cl H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 CH.sub.3                                                                             H  H                                                                                  ##STR148##                               Cl H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 CH.sub.3                                                                             H  H                                                                                  ##STR149##                               Cl H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H                                                                                  ##STR150##                               Cl H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H                                                                                  ##STR151##                               Cl H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H                                                                                  ##STR152##                               Cl H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H                                                                                  ##STR153##                               Cl H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H                                                                                  ##STR154##                               Cl H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H                                                                                  ##STR155##                               Cl H  CH.sub.3                                                                               1 COCH.sub.3     H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               1 COC.sub.4 H.sub.9 -n                                                                          H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               2 COC.sub.4 H.sub.9 -n                                                                          H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               0 COC.sub.4 H.sub.9 -n                                                                          H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               1 COC.sub.4 H.sub.9 -n                                                                          H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               2 COC.sub.4 H.sub.9 -n                                                                          H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               0                                                                                 ##STR156##    H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               1                                                                                 ##STR157##    H  H  CH.sub.3                                  Br H  CH.sub.3                                                                               2                                                                                 ##STR158##    H  H  CH.sub.3                                  Cl H  CH.sub.3                                                                               1 COC.sub.4 H.sub.9 -n                                                                          H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               2 COC.sub.4 H.sub.9 -n                                                                          H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               0 COC.sub.4 H.sub.9 -n                                                                          H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               1 COC.sub.4 H.sub.9 -n                                                                          H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               2 COC.sub.4 H.sub.9 -n                                                                          H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               0                                                                                 ##STR159##    H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               1                                                                                 ##STR160##    H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               2                                                                                 ##STR161##    H  H  C.sub.2 H.sub.5                           Br H  CH.sub.3                                                                               1 COC.sub.6 H.sub.5                                                                             H  H  C.sub.2 H.sub.5                           Cl H  CH.sub.3                                                                               1 COCH.sub.3     H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               1 COC.sub.4 H.sub.9 -n                                                                          H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               2 COC.sub.4 H.sub.9 -n                                                                          H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               0 COC.sub.4 H.sub.9 -n                                                                          H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               1 COC.sub.4 H.sub.9 -n                                                                          H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               2 COC.sub.4 H.sub.9 -n                                                                          H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               0                                                                                 ##STR162##    H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               1                                                                                 ##STR163##    H  H  n-C.sub.3 H.sub.7                         Br H  CH.sub.3                                                                               2                                                                                 ##STR164##    H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               0 COCH.sub.2 OCH.sub.3                                                                          H  H  n-C.sub.3 H.sub.7                         Cl H  CH.sub.3                                                                               0 COCH.sub.2 OCH.sub.3                                                                          H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               1 COCH.sub.2 OCH.sub.3                                                                          H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               2 COCH.sub.2 OCH.sub.3                                                                          H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               1 COCH.sub.3     H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               0 COC.sub.3 H.sub.7 -iso                                                                        H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               1 COC.sub.4 H.sub.9 -n                                                                          H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               2 COC.sub.4 H.sub.9 -n                                                                          H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               0                                                                                 ##STR165##    H  H  iso-C.sub.3 H.sub.7                       Cl H  CH.sub.3                                                                               1 COC.sub.2 H.sub.5                                                                             H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               2 COC.sub.2 H.sub.5                                                                             H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               1 COC.sub.3 H.sub.7 -n                                                                          H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               2 COC.sub.3 H.sub.7 -n                                                                          H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               0 COC.sub.4 H.sub.9 -n                                                                          H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               1 COC.sub.4 H.sub.9 -n                                                                          H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               2 COC.sub.4 H.sub.9 -n                                                                          H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               0                                                                                 ##STR166##    H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               1                                                                                 ##STR167##    H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               2                                                                                 ##STR168##    H  H  CH.sub.2 CF.sub.3                         Cl H  CH.sub.3                                                                               0 COC.sub.2 H.sub.5                                                                             H  H                                                                                  ##STR169##                               Cl H  CH.sub.3                                                                               1 COC.sub.2 H.sub.5                                                                             H  H                                                                                  ##STR170##                               Cl H  CH.sub.3                                                                               2 COC.sub.2 H.sub.5                                                                             H  H                                                                                  ##STR171##                               Cl H  CH.sub.3                                                                               0 COC.sub.3 H.sub.7 -n                                                                          H  H                                                                                  ##STR172##                               Cl H  CH.sub.3                                                                               1 COC.sub.3 H.sub.7 -n                                                                          H  H                                                                                  ##STR173##                               Cl H  CH.sub.3                                                                               2 COC.sub.3 H.sub.7 -n                                                                          H  H                                                                                  ##STR174##                               Cl H  CH.sub.3                                                                               0 COC.sub.4 H.sub.9 -n                                                                          H  H                                                                                  ##STR175##                               Cl H  CH.sub.3                                                                               1 COC.sub.4 H.sub.9 -n                                                                          H  H                                                                                  ##STR176##                               Cl H  CH.sub.3                                                                               2 COC.sub.4 H.sub.9 -n                                                                          H  H                                                                                  ##STR177##                               Cl H  CH.sub.3                                                                               0                                                                                 ##STR178##    H  H                                                                                  ##STR179##                               Cl H  CH.sub.3                                                                               1                                                                                 ##STR180##    H  H                                                                                  ##STR181##                               Cl H  CH.sub.3                                                                               2                                                                                 ##STR182##    H  H                                                                                  ##STR183##                               Cl H  C.sub.2 H.sub.5                                                                        1 COCH.sub.3     H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        2 COCH.sub.3     H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        1 COC.sub.4 H.sub.9 -n                                                                          H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        2 COC.sub.4 H.sub.9 -n                                                                          H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        0 COCH.sub.3     H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        0 COC.sub.4 H.sub.9 -n                                                                          H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        1 COC.sub.4 H.sub.9 -n                                                                          H  H  CH.sub.3                                  Br H  C.sub.2 H.sub.5                                                                        2 COC.sub.4 H.sub.9 -n                                                                          H  H  CH.sub.3                                  Cl H  C.sub.2 H.sub.5                                                                        1 COCH.sub.3     H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        2 COCH.sub.3     H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        1 COC.sub.4 H.sub.9 -n                                                                          H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        2 COC.sub.4 H.sub.9 -n                                                                          H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        1 COCH.sub.3     H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        2 COCH.sub.3     H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        0 COC.sub.4 H.sub.9 -n                                                                          H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        1 COC.sub.4 H.sub.9 -n                                                                          H  H  C.sub.2 H.sub.5                           Br H  C.sub.2 H.sub.5                                                                        2 COC.sub.4 H.sub.9 -n                                                                          H  H  C.sub.2 H.sub.5                           Cl H  C.sub.2 H.sub.5                                                                        1 COCH.sub.3     H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        2 COCH.sub.3     H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        1 COC.sub.4 H.sub.9 -n                                                                          H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        2 COC.sub.4 H.sub.9 -n                                                                          H  H  n-C.sub.3 H.sub.7                         Br H  C.sub.2 H.sub.5                                                                        0 COC.sub.4 H.sub.9 -n                                                                          H  H  n-C.sub.3 H.sub.7                         Br H  C.sub.2 H.sub.5                                                                        1 COC.sub.4 H.sub.9 -n                                                                          H  H  n-C.sub.3 H.sub.7                         Br H  C.sub.2 H.sub.5                                                                        2 COC.sub.4 H.sub.9 -n                                                                          H  H  n-C.sub.3 H.sub.7                         Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.3 H.sub.7 -iso                                                                        H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        1 COC.sub.4 H.sub.9 -n                                                                          H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        2 COC.sub.4 H.sub.9 -n                                                                          H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        0                                                                                 ##STR184##    H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        2 COC.sub.6 H.sub.5                                                                             H  H  iso-C.sub.3 H.sub.7                       Br H  C.sub.2 H.sub.5                                                                        1 COC.sub.2 H.sub.5                                                                             H  H  iso-C.sub.3 H.sub.7                       Br H  C.sub.2 H.sub.5                                                                        2 COC.sub.2 H.sub.5                                                                             H  H  iso-C.sub.3 H.sub.7                       Cl H  C.sub.2 H.sub.5                                                                        1 COC.sub.2 H.sub.5                                                                             H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        2 COC.sub.2 H.sub.5                                                                             H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        1 COC.sub.3 H.sub.7 -n                                                                          H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        2 COC.sub.3 H.sub.7 -n                                                                          H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.4 H.sub.9 -n                                                                          H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        1 COC.sub.4 H.sub.9 -n                                                                          H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        2 COC.sub.4 H.sub.9 -n                                                                          H  H  CH.sub.2 CF.sub.3                         Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.2 H.sub.5                                                                             H  H                                                                                  ##STR185##                               Cl H  C.sub.2 H.sub.5                                                                        1 COC.sub.2 H.sub.5                                                                             H  H                                                                                  ##STR186##                               Cl H  C.sub.2 H.sub.5                                                                        2 COC.sub.2 H.sub.5                                                                             H  H                                                                                  ##STR187##                               Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.3 H.sub.7 -n                                                                          H  H                                                                                  ##STR188##                               Cl H  C.sub.2 H.sub.5                                                                        1 COC.sub.3 H.sub.7 -n                                                                          H  H                                                                                  ##STR189##                               Cl H  C.sub.2 H.sub.5                                                                        2 COC.sub.3 H.sub.7 -n                                                                          H  H                                                                                  ##STR190##                               Cl H  C.sub.2 H.sub.5                                                                        0 COC.sub.4 H.sub.9 -n                                                                          H  H                                                                                  ##STR191##                               Cl H  C.sub.2 H.sub.5                                                                        1 COC.sub.4 H.sub.9 -n                                                                          H  H                                                                                  ##STR192##                               Cl H  C.sub.2 H.sub.5                                                                        2 COC.sub.4 H.sub.9 -n                                                                          H  H                                                                                  ##STR193##                               Cl H  CH.sub.3                                                                               0 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.2 CH═CH.sub.2                  Cl H  CH.sub.3                                                                               1 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.2 CH═CH.sub.2                  Cl H  CH.sub.3                                                                               2 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.2 CH═CH.sub.2                  Cl H  CH.sub.3                                                                               0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  CH.sub.2 CH═CH.sub.2                  Cl H  CH.sub.3                                                                               1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  CH.sub.2 CH═CH.sub.2                  Cl H  CH.sub.3                                                                               2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  CH.sub.2 CH═CH.sub.2                  Cl H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.2 CH═CH.sub.2                  Cl H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.2 CH═CH.sub.2                  Cl H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 CH.sub.3                                                                             H  H  CH.sub.2 CH═CH.sub.2                  Cl H  C.sub.2 H.sub.5                                                                        0 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  CH.sub.2 CH═CH.sub.2                  Cl H  C.sub.2 H.sub.5                                                                        1 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  CH.sub.2 CH═CH.sub.2                  Cl H  C.sub.2 H.sub.5                                                                        2 CO.sub.2 C.sub.2 H.sub.5                                                                      H  H  CH.sub.2 CH═CH.sub.2                  __________________________________________________________________________

                                      TABLE 2                                      __________________________________________________________________________      ##STR194##                                                                    R.sup.1                                                                           R.sup.2                                                                           R.sup.3                                                                             n R.sup.5                                                                              R.sup.6                                                                          R.sup.7                                                                           R.sup.8                                                __________________________________________________________________________     F  H  CH.sub.3                                                                            0 H     H H  CH.sub.3                                               F  H  CH.sub.3                                                                            0 H     H H  C.sub.2 H.sub.5                                        F  H  CH.sub.3                                                                            0 H     H H  n-C.sub.3 H.sub.7                                      F  H  CH.sub.3                                                                            0 H     H H  iso-C.sub.3 H.sub.7                                    F  H  CH.sub.3                                                                            0 H     H H  n-C.sub.4 H.sub.9                                      F  H  CH.sub.3                                                                            0 H     H H  iso-C.sub.4 H.sub.9                                    F  H  CH.sub.3                                                                            0 H     H H  tert-C.sub.4 H.sub.9                                   F  H  CH.sub.3                                                                            0 H     H H  (CH.sub.2).sub.3 Cl                                    F  H  CH.sub.3                                                                            0 H     H H  CH.sub.2 CN                                            F  H  CH.sub.3                                                                            0 H     H H  C.sub.6 H.sub.5                                        F  H  CH.sub.3                                                                            0 H     H H                                                                                  ##STR195##                                            F  H  CH.sub.3                                                                            0 H     H H                                                                                  ##STR196##                                            F  H  CH.sub.3                                                                            0 H     H H                                                                                  ##STR197##                                            F  H  CH.sub.3                                                                            1 H     H H  CH.sub.3                                               F  H  CH.sub.3                                                                            1 H     H H  C.sub.2 H.sub.5                                        F  H  CH.sub.3                                                                            1 H     H H  n-C.sub.3 H.sub.7                                      F  H  CH.sub.3                                                                            1 H     H H  iso-C.sub.3 H.sub.7                                    F  H  CH.sub.3                                                                            1 H     H H  n-C.sub.4 H.sub.9                                      F  H  CH.sub.3                                                                            1 H     H H  iso-C.sub.4 H.sub.9                                    F  H  CH.sub.3                                                                            1 H     H H  tert-C.sub.4 H.sub.9                                   F  H  CH.sub.3                                                                            1 H     H H  (CH.sub.2).sub.3 Cl                                    F  H  CH.sub.3                                                                            1 H     H H  CH.sub.2 CN                                            F  H  CH.sub.3                                                                            1 H     H H  C.sub.6 H.sub.5                                        F  H  CH.sub.3                                                                            1 H     H H                                                                                  ##STR198##                                            F  H  CH.sub.3                                                                            1 H     H H                                                                                  ##STR199##                                            F  H  CH.sub.3                                                                            1 H     H H                                                                                  ##STR200##                                            F  H  CH.sub.3                                                                            2 H     H H  CH.sub.3                                               F  H  CH.sub.3                                                                            2 H     H H  C.sub.2 H.sub.5                                        F  H  CH.sub.3                                                                            2 H     H H  n-C.sub.3 H.sub.7                                      F  H  CH.sub.3                                                                            2 H     H H  iso-C.sub.3 H.sub.7                                    F  H  CH.sub.3                                                                            2 H     H H  n-C.sub.4 H.sub.9                                      F  H  CH.sub.3                                                                            2 H     H H  iso-C.sub.4 H.sub.9                                    F  H  CH.sub.3                                                                            2 H     H H  tert-C.sub.4 H.sub.9                                   F  H  CH.sub.3                                                                            2 H     H H  (CH.sub.2).sub.3 Cl                                    F  H  CH.sub.3                                                                            2 H     H H  CH.sub.2 CN                                            F  H  CH.sub.3                                                                            2 H     H H  C.sub.6 H.sub.5                                        F  H  CH.sub.3                                                                            2 H     H H                                                                                  ##STR201##                                            F  H  CH.sub.3                                                                            2 H     H H                                                                                  ##STR202##                                            F  H  CH.sub.3                                                                            2 H     H H                                                                                  ##STR203##                                            F  H  C.sub.2 H.sub.5                                                                     0 H     H H  CH.sub.3                                               F  H  C.sub.2 H.sub.5                                                                     0 H     H H  C.sub.2 H.sub.5                                        F  H  C.sub.2 H.sub.5                                                                     0 H     H H  n-C.sub.3 H.sub.7                                      F  H  C.sub.2 H.sub.5                                                                     0 H     H H  iso-C.sub.3 H.sub.7                                    F  H  C.sub.2 H.sub.5                                                                     0 H     H H  n-C.sub.4 H.sub.9                                      F  H  C.sub.2 H.sub.5                                                                     0 H     H H  iso-C.sub.4 H.sub.9                                    F  H  C.sub.2 H.sub.5                                                                     0 H     H H  tert-C.sub.4 H.sub.9                                   F  H  C.sub.2 H.sub.5                                                                     0 H     H H  (CH.sub.2).sub.3 Cl                                    F  H  C.sub.2 H.sub.5                                                                     0 H     H H  CH.sub.2 CN                                            F  H  C.sub.2 H.sub.5                                                                     0 H     H H  C.sub.6 H.sub.5                                        F  H  C.sub.2 H.sub.5                                                                     0 H     H H                                                                                  ##STR204##                                            F  H  C.sub.2 H.sub.5                                                                     0 H     H H                                                                                  ##STR205##                                            F  H  C.sub.2 H.sub.5                                                                     0 H     H H                                                                                  ##STR206##                                            F  H  C.sub.2 H.sub.5                                                                     1 H     H H  CH.sub.3                                               F  H  C.sub.2 H.sub.5                                                                     1 H     H H  C.sub.2 H.sub.5                                        F  H  C.sub.2 H.sub.5                                                                     1 H     H H  n-C.sub.3 H.sub.7                                      F  H  C.sub.2 H.sub.5                                                                     1 H     H H  iso-C.sub.3 H.sub.7                                    F  H  C.sub.2 H.sub.5                                                                     1 H     H H  n-C.sub.4 H.sub.9                                      F  H  C.sub.2 H.sub.5                                                                     1 H     H H  iso-C.sub.4 H.sub.9                                    F  H  C.sub.2 H.sub.5                                                                     1 H     H H  tert-C.sub.4 H.sub.9                                   F  H  C.sub.2 H.sub.5                                                                     1 H     H H  (CH.sub.2).sub.3 Cl                                    F  H  C.sub.2 H.sub.5                                                                     1 H     H H  CH.sub.2 CN                                            F  H  C.sub.2 H.sub.5                                                                     1 H     H H  C.sub.6 H.sub.5                                        F  H  C.sub.2 H.sub.5                                                                     1 H     H H                                                                                  ##STR207##                                            F  H  C.sub.2 H.sub.5                                                                     1 H     H H                                                                                  ##STR208##                                            F  H  C.sub.2 H.sub.5                                                                     1 H     H H                                                                                  ##STR209##                                            F  H  C.sub.2 H.sub.5                                                                     2 H     H H  CH.sub.3                                               F  H  C.sub.2 H.sub.5                                                                     2 H     H H  C.sub.2 H.sub.5                                        F  H  C.sub.2 H.sub.5                                                                     2 H     H H  n-C.sub.3 H.sub.7                                      F  H  C.sub.2 H.sub.5                                                                     2 H     H H  iso-C.sub.3 H.sub.7                                    F  H  C.sub.2 H.sub.5                                                                     2 H     H H  n-C.sub.4 H.sub.9                                      F  H  C.sub.2 H.sub.5                                                                     2 H     H H  iso-C.sub.4 H.sub.9                                    F  H  C.sub.2 H.sub.5                                                                     2 H     H H  tert-C.sub.4 H.sub.9                                   F  H  C.sub.2 H.sub.5                                                                     2 H     H H  (CH.sub.2).sub.3 Cl                                    F  H  C.sub.2 H.sub.5                                                                     2 H     H H  CH.sub.2 CN                                            F  H  C.sub.2 H.sub.5                                                                     2 H     H H  C.sub.6 H.sub.5                                        F  H  C.sub.2 H.sub.5                                                                     2 H     H H                                                                                  ##STR210##                                            F  H  C.sub.2 H.sub.5                                                                     2 H     H H                                                                                  ##STR211##                                            F  H  C.sub.2 H.sub.5                                                                     2 H     H H                                                                                  ##STR212##                                            Cl H  CH.sub.3                                                                            0 H     H H  H                                                      Cl H  CH.sub.3                                                                            0 H     H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            0 H     H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            0 H     H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            0 H     H H  iso-C.sub.3 H.sub.7                                    Cl H  CH.sub.3                                                                            0 H     H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            0 H     H H  sec-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            0 H     H H  iso-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            0 H     H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            0 H     H H  n-C.sub.5 H.sub.11                                     Cl H  CH.sub.3                                                                            0 H     H H  n-C.sub.5 H.sub.13                                     Cl H  CH.sub.3                                                                            0 H     H H  C.sub.6 H.sub.5                                        Cl H  CH.sub.3                                                                            0 H     H H                                                                                  ##STR213##                                            Cl H  CH.sub.3                                                                            0 H     H H                                                                                  ##STR214##                                            Cl H  CH.sub.3                                                                            0 H     H H                                                                                  ##STR215##                                            Cl H  CH.sub.3                                                                            0 H     H H                                                                                  ##STR216##                                            Cl H  CH.sub.3                                                                            0 H     H H                                                                                  ##STR217##                                            Cl H  CH.sub.3                                                                            0 H     H H                                                                                  ##STR218##                                            Cl H  CH.sub.3                                                                            0 H     H H                                                                                  ##STR219##                                            Cl H  CH.sub.3                                                                            0 H     H H                                                                                  ##STR220##                                            Cl H  CH.sub.3                                                                            0 H     H H                                                                                  ##STR221##                                            Cl H  CH.sub.3                                                                            0 H     H H  CH═CH.sub.2                                        Cl H  CH.sub.3                                                                            0 H     H H  CH═CHC.sub.6 H.sub.5                               Cl H  CH.sub.3                                                                            0 H     H H  CH═CHCH.sub.3                                      Cl H  CH.sub.3                                                                            0 H     H H  C(═CH.sub.2)CH.sub.3                               Cl H  CH.sub.3                                                                            0 H     H H  CH.sub.2 CF═CF.sub.2                               Cl H  CH.sub.3                                                                            0 H     H H                                                                                  ##STR222##                                            Cl H  CH.sub.3                                                                            0 H     H H  CH.sub.2 CH.sub.2 Cl                                   Cl H  CH.sub.3                                                                            0 H     H H  (CH.sub.2).sub.4 Cl                                    Cl H  CH.sub.3                                                                            0 H     H H  (CH.sub.2).sub.3 Cl                                    Cl H  CH.sub.3                                                                            0 H     H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            0 H     H H  CH.sub.2 CH.sub.2 OCH.sub.3                            Cl H  CH.sub.3                                                                            0 H     H H  CH.sub.2 CN                                            Cl H  CH.sub.3                                                                            0 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  CH.sub.3                                                                            0 H     H H                                                                                  ##STR223##                                            Cl H  CH.sub.3                                                                            0 H     H H                                                                                  ##STR224##                                            Cl H  CH.sub.3                                                                            0 H     H H                                                                                  ##STR225##                                            Cl H  CH.sub.3                                                                            0 H     H H                                                                                  ##STR226##                                            Cl H  CH.sub.3                                                                            0 H     H H                                                                                  ##STR227##                                            Cl H  CH.sub.3                                                                            0 H     2-Cl                                                                             H  CH.sub.3                                               Cl H  CH.sub.3                                                                            0 H     2-Cl                                                                             H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            0 H     2-Cl                                                                             H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            0 H     2-Cl                                                                             H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            0 H     3-Cl                                                                             H  CH.sub.3                                               Cl H  CH.sub.3                                                                            0 H     3-Cl                                                                             H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            0 H     3-Cl                                                                             H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            0 H     3-Cl                                                                             H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            0 H     2-F                                                                              H  CH.sub.3                                               Cl H  CH.sub.3                                                                            0 H     2-F                                                                              H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            0 H     2-F                                                                              H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            0 H     2-F                                                                              H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            0 H     3-F                                                                              H  CH.sub.3                                               Cl H  CH.sub.3                                                                            0 H     3-F                                                                              H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            0 H     3-F                                                                              H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            0 H     3-F                                                                              H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            0 H     3-F                                                                              H  sec-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  iso-C.sub.3 H.sub.7                                    Cl H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  sec-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  iso-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  C.sub.6 H.sub.5                                        Cl H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H                                                                                  ##STR228##                                            Cl H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  (CH.sub.2).sub.3 Cl                                    Cl H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  (CH.sub.2).sub.4 Cl                                    Cl H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  CH.sub.2 CN                                            Cl H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H                                                                                  ##STR229##                                            Cl H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  iso-C.sub.3 H.sub.7                                    Cl H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  iso-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  sec-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  (CH.sub.2).sub.3 Cl                                    Cl H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  (CH.sub.2).sub.4 Cl                                    Cl H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 CN                                            Cl H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  C.sub.6 H.sub.5                                        Cl H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H                                                                                  ##STR230##                                            Cl H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H  iso-C.sub.3 H.sub.7                                    Cl H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H  iso-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H  sec-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H  (CH.sub.2).sub.3 Cl                                    Cl H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H  (CH.sub.2).sub.4 Cl                                    Cl H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 CN                                            Cl H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H  C.sub.6 H.sub.5                                        Cl H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H  iso-C.sub.3 H.sub.7                                    Cl H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  K H  iso-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H  sec-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H  (CH.sub.2).sub.3 Cl                                    Cl H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H  (CH.sub.2).sub.4 Cl                                    Cl H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 CN                                            Cl H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H  C.sub.6 H.sub.5                                        Cl H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H                                                                                  ##STR231##                                            Cl H  CH.sub.3                                                                            0 CH.sub.2 OCH.sub.3                                                                   H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            0 CH.sub.2 OCH.sub.3                                                                   H H  C.sub.6 H.sub.5                                        Cl H  CH.sub.3                                                                            0 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            0 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            0 CH.sub.2 SCH.sub.3                                                                   H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            0 CH.sub.2 SCH.sub.3                                                                   H H  C.sub.6 H.sub.5                                        Cl H  CH.sub.3                                                                            0 COCH.sub.3                                                                           H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            0 COC.sub.2 H.sub.5                                                                    H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            0 COC.sub.2 H.sub.5                                                                    H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            1 H     H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            1 H     H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            1 H     H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            1 H     H H  iso-C.sub.3 H.sub.7                                    Cl H  CH.sub.3                                                                            1 H     H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            1 H     H H  iso-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            1 H     H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            1 H     H H  (CH.sub.2).sub.3 Cl                                    Cl H  CH.sub.3                                                                            1 H     H H  CH.sub.2 CN                                            Cl H  CH.sub.3                                                                            1 H     H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            1 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  CH.sub.3                                                                            1 H     H H                                                                                  ##STR232##                                            Cl H  CH.sub.3                                                                            1 H     H H                                                                                  ##STR233##                                            Cl H  CH.sub.3                                                                            1 H     H H  C.sub.6 H.sub.5                                        Cl H  CH.sub.3                                                                            1 H     H H                                                                                  ##STR234##                                            Cl H  CH.sub.3                                                                            1 H     2-Cl                                                                             H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            1 H     3-Cl                                                                             H  CH.sub.3                                               Cl H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  iso-C.sub.3 H.sub.7                                    Cl H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  iso-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  sec-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  (CH.sub.2).sub.3 Cl                                    Cl H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  (CH.sub.2).sub.4 Cl                                    Cl H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  CH.sub.2 CN                                            Cl H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  C.sub.6 H.sub.5                                        Cl H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H                                                                                  ##STR235##                                            Cl H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  iso-C.sub.3 H.sub.7                                    Cl H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  iso-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  sec-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  (CH.sub.2).sub.3 Cl                                    Cl H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  (CH.sub.2).sub.4 Cl                                    Cl H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 CN                                            Cl H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  C.sub.6 H.sub.5                                        Cl H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H                                                                                  ##STR236##                                            Cl H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H  iso-C.sub.3 H.sub.7                                    Cl H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H  iso-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H  sec-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H  (CH.sub.2).sub.3 Cl                                    Cl H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H  (CH.sub.2)ACl                                          Cl H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 CN                                            Cl H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H  C.sub.6 H.sub.5                                        Cl H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H                                                                                  ##STR237##                                            Cl H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H  iso-C.sub.3 H.sub.7                                    Cl H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H  iso-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H  sec-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H  (CH.sub.2).sub.3 Cl                                    Cl H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H  (CH.sub.2).sub.4 Cl                                    Cl H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 CN                                            Cl H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H  C.sub.6 H.sub.5                                        Cl H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H                                                                                  ##STR238##                                            Cl H  CH.sub.3                                                                            2 H     H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            2 H     H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            2 H     H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            2 H     H H  iso-C.sub.3 H.sub.7                                    Cl H  CH.sub.3                                                                            2 H     H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            2 H     H H  iso-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            2 H     H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            2 H     H H  (CH.sub.2).sub.3 Cl                                    Cl H  CH.sub.3                                                                            2 H     H H  CH.sub.2 CN                                            Cl H  CH.sub.3                                                                            2 H     H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            2 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  CH.sub.3                                                                            2 H     H H                                                                                  ##STR239##                                            Cl H  CH.sub.3                                                                            2 H     H H                                                                                  ##STR240##                                            Cl H  CH.sub.3                                                                            2 H     H H  C.sub.6 H.sub.5                                        Cl H  CH.sub.3                                                                            2 H     H H                                                                                  ##STR241##                                            Cl H  CH.sub.3                                                                            2 H     2-Cl                                                                             H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            2 H     3-Cl                                                                             H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  iso-C.sub.3 H.sub.7                                    Cl H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  iso-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  sec-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  (CH.sub.2).sub.3 Cl                                    Cl H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  (CH.sub.2).sub.4 Cl                                    Cl H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  CH.sub.2 CN                                            Cl H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  C.sub.6 H.sub.5                                        Cl H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H                                                                                  ##STR242##                                            Cl H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  iso-C.sub.3 H.sub.7                                    Cl H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  n-C.sub.2 H.sub.5                                      Cl H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  iso-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  sec-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  (CH.sub.2).sub.3 Cl                                    Cl H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  (CH.sub.2).sub.4 Cl                                    Cl H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 CN                                            Cl H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  C.sub.6 H.sub.5                                        Cl H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H                                                                                  ##STR243##                                            Cl H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  iso-C.sub.3 H.sub.7                                    Cl H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  iso-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  sec-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  (CH.sub.2).sub.3 Cl                                    Cl H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  (CH.sub.2).sub.4 Cl                                    Cl H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 CN                                            Cl H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  C.sub.6 H.sub.5                                        Cl H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H                                                                                  ##STR244##                                            Cl H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H  iso-C.sub.3 H.sub.7                                    Cl H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H  iso-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H  sec-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H  C.sub.6 H.sub.5                                        Cl H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H                                                                                  ##STR245##                                            Cl H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H  (CH.sub.2).sub.3 Cl                                    Cl H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H  (CH.sub.2).sub.4 Cl                                    Cl H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 CN                                            Cl H  CH.sub.3                                                                            2 iso-C3 H.sub.7                                                                       H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     0 H     H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     0 H     H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     0 H     H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     0 H     H H  iso-C.sub.3 H.sub.7                                    Cl H  C.sub.2 H.sub.5                                                                     0 H     H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     0 H     H H  iso-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     0 H     H H  sec-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     0 H     H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     0 H     H H  n-C.sub.5 H.sub.11                                     Cl H  C.sub.2 H.sub.5                                                                     0 H     H H  n-C.sub.6 H.sub.13                                     Cl H  C.sub.2 H.sub.5                                                                     0 H     H H  C.sub.6 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     0 H     H H                                                                                  ##STR246##                                            Cl H  C.sub.2 H.sub.5                                                                     0 H     H H                                                                                  ##STR247##                                            Cl H  C.sub.2 H.sub.5                                                                     0 H     H H                                                                                  ##STR248##                                            Cl H  C.sub.2 H.sub.5                                                                     0 H     H H                                                                                  ##STR249##                                            Cl H  C.sub.2 H.sub.5                                                                     0 H     H H                                                                                  ##STR250##                                            Cl H  C.sub.2 H.sub.5                                                                     0 H     H H                                                                                  ##STR251##                                            Cl H  C.sub.2 H.sub.5                                                                     0 H     H H  CH═CH.sub.2                                        Cl H  C.sub.2 H.sub.5                                                                     0 H     H H  CH═CHC.sub.6 H.sub.5                               Cl H  C.sub.2 H.sub.5                                                                     0 H     H H  CH.sub.2 CF═CF.sub.2                               Cl H  C.sub.2 H.sub.5                                                                     0 H     H H  (CH.sub.2).sub.4 Cl                                    Cl H  C.sub.2 H.sub.5                                                                     0 H     H H  (CH.sub.2).sub.3 Cl                                    Cl H  C.sub.2 H.sub.5                                                                     0 H     H H  CH.sub.2 CN                                            Cl H  C.sub.2 H.sub.5                                                                     0 H     H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     0 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  iso-C.sub.3 H.sub.7                                    Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  iso-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  sec-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  (CH.sub.2).sub.3 Cl                                    Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  (CH.sub.2).sub.4 Cl                                    Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  CH.sub.2 CN                                            Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  C.sub.6 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H                                                                                  ##STR252##                                            Cl H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  iso-C.sub.3 H.sub.7                                    Cl H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  iso-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  sec-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  (CH.sub.2).sub.3 Cl                                    Cl H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  (CH.sub.2).sub.4 Cl                                    Cl H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 CN                                            Cl H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  C.sub.6 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H                                                                                  ##STR253##                                            Cl H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  iso-C.sub.3 H.sub.7                                    Cl H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  iso-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  sec-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  (CH.sub.2).sub.3 Cl                                    Cl H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  (CH.sub.2).sub.4 Cl                                    Cl H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 CN                                            Cl H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  C.sub.6 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H                                                                                  ##STR254##                                            Cl H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  iso-C.sub.3 H.sub.7                                    Cl H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  iso-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  sec-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  CH.sub.2 CN                                            Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  CH.sub.2 CH.sub.3                                      Cl H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  (CH.sub.2).sub.3 Cl                                    Cl H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  (CH.sub.2).sub.4 Cl                                    Cl H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 CN                                            Cl H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  C.sub.6 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H                                                                                  ##STR255##                                            Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.2 OCH.sub.3                                                                   H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.2 SCH.sub.3                                                                   H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     0 COC.sub.2 H.sub.5                                                                    H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     0 COC.sub.2 H.sub.5                                                                    H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     0 COC.sub.3 H.sub.7 -n                                                                 H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     1 H     H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     1 H     H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     1 H     H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     1 H     H H  iso-C.sub.3 H.sub.7                                    Cl H  C.sub.2 H.sub.5                                                                     1 H     H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     1 H     H H  iso-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     1 H     H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     1 H     H H  (CH.sub.2).sub.3 Cl                                    Cl H  C.sub.2 H.sub.5                                                                     1 H     H H  CH.sub.2 CN                                            Cl H  C.sub.2 H.sub.5                                                                     1 H     H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     1 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  C.sub.2 H.sub.5                                                                     1 H     H H                                                                                  ##STR256##                                            Cl H  C.sub.2 H.sub.5                                                                     1 H     H H                                                                                  ##STR257##                                            Cl H  C.sub.2 H.sub.5                                                                     1 H     H H  C.sub.6 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     1 H     H H                                                                                  ##STR258##                                            Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  iso-C.sub.3 H.sub.7                                    Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  iso-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  sec-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  (CH.sub.2).sub.3 Cl                                    Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  (CH.sub.2).sub.4 Cl                                    Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  CH.sub.2 CN                                            Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  C.sub.6 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H                                                                                  ##STR259##                                            Cl H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  iso-C.sub.3 H.sub.7                                    Cl H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  iso-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  sec-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  (CH.sub.2).sub.3 Cl                                    Cl H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  (CH.sub.2).sub.4 Cl                                    Cl H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 CN                                            Cl H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  C.sub.6 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H                                                                                  ##STR260##                                            Cl H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  iso-C.sub.3 H.sub.7                                    Cl H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  iso-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  sec-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  (CH.sub.2).sub.3 Cl                                    Cl H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  (CH.sub.2).sub.4 Cl                                    Cl H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 CN                                            Cl H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  C.sub.6 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H                                                                                  ##STR261##                                            Cl H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  iso-C.sub.3 H.sub.7                                    Cl H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  iso-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  sec-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  (CH.sub.2).sub.3 Cl                                    Cl H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  (CH.sub.2).sub.4 Cl                                    Cl H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 CN                                            Cl H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  C.sub.6 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H                                                                                  ##STR262##                                            Cl H  C.sub.2 H.sub.5                                                                     2 H     H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     2 H     H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     2 H     H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     2 H     H H  iso-C.sub.3 H.sub.7                                    Cl H  C.sub.2 H.sub.5                                                                     2 H     H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     2 H     H H  iso-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     2 H     H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     2 H     H H  (CH.sub.2).sub.3 Cl                                    Cl H  C.sub.2 H.sub.5                                                                     2 H     H H  CH.sub.2 CN                                            Cl H  C.sub.2 H.sub.5                                                                     2 H     H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     2 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  C.sub.2 H.sub.5                                                                     2 H     H H                                                                                  ##STR263##                                            Cl H  C.sub.2 H.sub.5                                                                     2 H     H H                                                                                  ##STR264##                                            Cl H  C.sub.2 H.sub.5                                                                     2 H     H H  C.sub.6 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     2 H     H H                                                                                  ##STR265##                                            Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  iso-C.sub.3 H.sub.7                                    Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  iso-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  sec-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  (CH.sub.2).sub.3 Cl                                    Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  (CH.sub.2).sub.4 Cl                                    Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  CH.sub.2 CN                                            Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  C.sub.6 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H                                                                                  ##STR266##                                            Cl H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  iso-C.sub.3 H.sub.7                                    Cl H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  iso-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  sec-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  (CH.sub.2).sub.3 Cl                                    Cl H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  (CH.sub.2).sub.4 Cl                                    Cl H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 CN                                            Cl H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  C.sub.6 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H                                                                                  ##STR267##                                            Cl H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  iso-C.sub.3 H.sub.7                                    Cl H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  iso-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  sec-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  (CH.sub.2).sub.3 Cl                                    Cl H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  (CH.sub.2).sub.4 Cl                                    Cl H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 CN                                            Cl H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  C.sub.6 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H                                                                                  ##STR268##                                            Cl H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  iso-C.sub.3 H.sub.7                                    Cl H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  iso-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  sec-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  (CH.sub.2).sub.3 Cl                                    Cl H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  (CH.sub.2).sub.4 Cl                                    Cl H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 CN                                            Cl H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  C.sub.6 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H                                                                                  ##STR269##                                            Cl H  n-C.sub.3 H.sub.7                                                                   0 H     H H  CH.sub.3                                               Cl H  n-C.sub.3 H.sub.7                                                                   0 H     H H  C.sub.2 H.sub.5                                        Cl H  n-C.sub.3 H.sub.7                                                                   0 H     H H  n-C.sub.3 H.sub.7                                      Cl H  n-C.sub.3 H.sub.7                                                                   0 H     H H  iso-C.sub.3 H.sub.7                                    Cl H  n-C.sub.3 H.sub.7                                                                   0 H     H H  n-C.sub.4 H.sub.9                                      Cl H  n-C.sub.3 H.sub.7                                                                   0 H     H H  iso-C.sub.4 H.sub.9                                    Cl H  n-C.sub.3 H.sub.7                                                                   0 H     H H  tert-C.sub.4 H.sub.9                                   Cl H  n-C.sub.3 H.sub.7                                                                   0 H     H H  (CH.sub.2).sub.3 Cl                                    Cl H  n-C.sub.3 H.sub.7                                                                   0 H     H H  CH.sub.2 CN                                            Cl H  n-C.sub.3 H.sub.7                                                                   0 H     H H  CH.sub.2 OCH.sub.3                                     Cl H  n-C.sub.3 H.sub.7                                                                   0 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  n-C.sub.3 H.sub.7                                                                   0 H     H H                                                                                  ##STR270##                                            Cl H  n-C.sub.3 H.sub.7                                                                   0 H     H H                                                                                  ##STR271##                                            Cl H  n-C.sub.3 H.sub.7                                                                   0 H     H H  C.sub.6 H.sub.5                                        Cl H  n-C.sub.3 H.sub.7                                                                   0 H     H H                                                                                  ##STR272##                                            Cl H  n-C.sub.3 H.sub.7                                                                   1 H     H H  CH.sub.3                                               Cl H  n-C.sub.3 H.sub.7                                                                   1 H     H H  C.sub.2 H.sub.5                                        Cl H  n-C.sub.3 H.sub.7                                                                   1 H     H H  n-C.sub.3 H.sub.7                                      Cl H  n-C.sub.3 H.sub.7                                                                   1 H     H H  iso-C.sub.3 H.sub.7                                    Cl H  n-C.sub.3 H.sub.7                                                                   1 H     H H  n-C.sub.4 H.sub.9                                      Cl H  n-C.sub.3 H.sub.7                                                                   1 H     H H  iso-C.sub.4 H.sub.9                                    Cl H  n-C.sub.3 H.sub.7                                                                   1 H     H H  tert-C.sub.4 H.sub.9                                   Cl H  n-C.sub.3 H.sub.7                                                                   1 H     H H  (CH.sub.2).sub.3 Cl                                    Cl H  n-C.sub.3 H.sub.7                                                                   1 H     H H  CH.sub.2 CN                                            Cl H  n-C.sub.3 H.sub.7                                                                   1 H     H H  CH.sub.2 OCH.sub.3                                     Cl H  n-C.sub.3 H.sub.7                                                                   1 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  n-C.sub.3 H.sub.7                                                                   1 H     H H                                                                                  ##STR273##                                            Cl H  n-C.sub.3 H.sub.7                                                                   1 H     H H                                                                                  ##STR274##                                            Cl H  n-C.sub.3 H.sub.7                                                                   1 H     H H  C.sub.6 H.sub.5                                        Cl H  n-C.sub.3 H.sub.7                                                                   1 H     H H                                                                                  ##STR275##                                            Cl H  n-C.sub.3 H.sub.7                                                                   2 H     H H  CH.sub.3                                               Cl H  n-C.sub.3 H.sub.7                                                                   2 H     H H  C.sub.2 H.sub.5                                        Cl H  n-C.sub.3 H.sub.7                                                                   2 H     H H  n-C.sub.3 H.sub.7                                      Cl H  n-C.sub.3 H.sub.7                                                                   2 H     H H  iso-C.sub.3 H.sub.7                                    Cl H  n-C.sub.3 H.sub.7                                                                   2 H     H H  n-C.sub.4 H.sub.9                                      Cl H  n-C.sub.3 H.sub.7                                                                   2 H     H H  iso-C.sub.4 H.sub.9                                    Cl H  n-C.sub.3 H.sub.7                                                                   2 H     H H  tert-C.sub.4 H.sub.9                                   Cl H  n-C.sub.3 H.sub.7                                                                   2 H     H H  (CH.sub.2).sub.3 Cl                                    Cl H  n-C.sub.3 H.sub.7                                                                   2 H     H H  CH.sub.2 CN                                            Cl H  n-C.sub.3 H.sub.7                                                                   2 H     H H  CH.sub.2 OCH.sub.3                                     Cl H  n-C.sub.3 H.sub.7                                                                   2 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  n-C.sub.3 H.sub.7                                                                   2 H     H H                                                                                  ##STR276##                                            Cl H  n-C.sub.3 H.sub.7                                                                   2 H     H H                                                                                  ##STR277##                                            Cl H  n-C.sub.3 H.sub.7                                                                   2 H     H H  C.sub.6 H.sub.5                                        Cl H  n-C.sub.3 H.sub.7                                                                   2 H     H H                                                                                  ##STR278##                                            Cl H  CH.sub.2 F                                                                          0 H     H H  CH.sub.3                                               Cl H  CH.sub.2 F                                                                          0 H     H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.2 F                                                                          0 H     H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.2 F                                                                          0 H     H H  iso-C.sub.3 H.sub.7                                    Cl H  CH.sub.2 F                                                                          0 H     H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.2 F                                                                          0 H     H H  iso-C.sub.4 H.sub.9                                    Cl H  CH.sub.2 F                                                                          0 H     H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.2 F                                                                          0 H     H H  (CH.sub.2).sub.3 Cl                                    Cl H  CH.sub.2 F                                                                          0 H     H H  CH.sub.2 CN                                            Cl H  CH.sub.2 F                                                                          0 H     H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.2 F                                                                          0 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  CH.sub.2 F                                                                          0 H     H H                                                                                  ##STR279##                                            Cl H  CH.sub.2 F                                                                          0 H     H H                                                                                  ##STR280##                                            Cl H  CH.sub.2 F                                                                          0 H     H H  C.sub.6 H.sub.5                                        Cl H  CH.sub.2 F                                                                          0 H     H H                                                                                  ##STR281##                                            Cl H  CH.sub.2 F                                                                          1 H     H H  CH.sub.3                                               Cl H  CH.sub.2 F                                                                          1 H     H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.2 F                                                                          1 H     H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.2 F                                                                          1 H     H H  iso-C.sub.3 H.sub.7                                    Cl H  CH.sub.2 F                                                                          1 H     H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.2 F                                                                          1 H     H H  iso-C.sub.4 H.sub.9                                    Cl H  CH.sub.2 F                                                                          1 H     H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.2 F                                                                          1 H     H H  (CH.sub.2).sub.3 Cl                                    Cl H  CH.sub.2 F                                                                          1 H     H H  CH.sub.2 CN                                            Cl H  CH.sub.2 F                                                                          1 H     H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.2 F                                                                          1 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  CH.sub.2 F                                                                          1 H     H H                                                                                  ##STR282##                                            Cl H  CH.sub.2 F                                                                          1 H     H H                                                                                  ##STR283##                                            Cl H  CH.sub.2 F                                                                          1 H     H H  C.sub.6 H.sub.5                                        Cl H  CH.sub.2 F                                                                          1 H     H H                                                                                  ##STR284##                                            Cl H  CH.sub.2 F                                                                          2 H     H H  CH.sub.3                                               Cl H  CH.sub.2 F                                                                          2 H     H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.2 F                                                                          2 H     H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.2 F                                                                          2 H     H H  iso-C.sub.3 H.sub.7                                    Cl H  CH.sub.2 F                                                                          2 H     H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.2 F                                                                          2 H     H H  iso-C.sub.4 H.sub.9                                    Cl H  CH.sub.2 F                                                                          2 H     H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.2 F                                                                          2 H     H H  (CH.sub.2).sub.3 Cl                                    Cl H  CH.sub.2 F                                                                          2 H     H H  CH.sub.2 CN                                            Cl H  CH.sub.2 F                                                                          2 H     H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.2 F                                                                          2 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  CH.sub.2 F                                                                          2 H     H H                                                                                  ##STR285##                                            Cl H  CH.sub.2 F                                                                          2 H     H H                                                                                  ##STR286##                                            Cl H  CH.sub.2 F                                                                          2 H     H H  C.sub.6 H.sub.5                                        Cl H  CH.sub.2 F                                                                          2 H     H H                                                                                  ##STR287##                                            Cl H  CHF.sub.2                                                                           0 H     H H  CH.sub.3                                               Cl H  CHF.sub.2                                                                           0 H     H H  C.sub.2 H.sub.5                                        Cl H  CHF.sub.2                                                                           0 H     H H  n-C.sub.3 H.sub.7                                      Cl H  CHF.sub.2                                                                           0 H     H H  iso-C.sub.3 H.sub.7                                    Cl H  CHF.sub.2                                                                           0 H     H H  n-C.sub.4 H.sub.9                                      Cl H  CHF.sub.2                                                                           0 H     H H  iso-C.sub.4 H.sub.9                                    Cl H  CHF.sub.2                                                                           0 H     H H  tert-C.sub.4 H.sub.9                                   Cl H  CHF.sub.2                                                                           0 H     H H  (CH.sub.2).sub.3 Cl                                    Cl H  CHF.sub.2                                                                           0 H     H H  CH.sub.2 CN                                            Cl H  CHF.sub.2                                                                           0 H     H H  CH.sub.2 OCH.sub.3                                     Cl H  CHF.sub.2                                                                           0 H     H H  CH.sub.2 CO.sub.2 H.sub.5                              Cl H  CHF.sub.2                                                                           0 H     H H                                                                                  ##STR288##                                            Cl H  CHF.sub.2                                                                           0 H     H H                                                                                  ##STR289##                                            Cl H  CHF.sub.2                                                                           0 H     H H  C.sub.6 H.sub.5                                        Cl H  CHF.sub.2                                                                           0 H     H H                                                                                  ##STR290##                                            Cl H  CHF.sub.2                                                                           1 H     H H  CH.sub.3                                               Cl H  CHF.sub.2                                                                           1 H     H H  C.sub.2 H.sub.5                                        Cl H  CHF.sub.2                                                                           1 H     H H  n-C.sub.3 H.sub.7                                      Cl H  CHF.sub.2                                                                           1 H     H H  iso-C.sub.3 H.sub.7                                    Cl H  CHF.sub.2                                                                           1 H     H H  n-C.sub.4 H.sub.9                                      Cl H  CHF.sub.2                                                                           1 H     H H  iso-C.sub.4 H.sub.9                                    Cl H  CHF.sub.2                                                                           1 H     H H  tert-C.sub.4 H.sub.9                                   Cl H  CHF.sub.2                                                                           1 H     H H  (CH.sub.2).sub.3 Cl                                    Cl H  CHF.sub.2                                                                           1 H     H H  CH.sub.2 CN                                            Cl H  CHF.sub.2                                                                           1 H     H H  CH.sub.2 OCH.sub.3                                     Cl H  CHF.sub.2                                                                           1 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  CHF.sub.2                                                                           1 H     H H                                                                                  ##STR291##                                            Cl H  CHF.sub.2                                                                           1 H     H H                                                                                  ##STR292##                                            Cl H  CHF.sub.2                                                                           1 H     H H  C.sub.6 H.sub.5                                        Cl H  CHF.sub.2                                                                           1 H     H H                                                                                  ##STR293##                                            Cl H  CHF.sub.2                                                                           2 H     H H  CH.sub.3                                               Cl H  CHF.sub.2                                                                           2 H     H H  C.sub.2 H.sub.5                                        Cl H  CHF.sub.2                                                                           2 H     H H  n-C.sub.3 H.sub.7                                      Cl H  CHF.sub.2                                                                           2 H     H H  iso-C.sub.3 H.sub.7                                    Cl H  CHF.sub.2                                                                           2 H     H H  n-C.sub.4 H.sub.9                                      Cl H  CHF.sub.2                                                                           2 H     H H  iso-C.sub.4 H.sub.9                                    Cl H  CHF.sub.2                                                                           2 H     H H  tert-C.sub.4 H.sub.9                                   Cl H  CHF.sub.2                                                                           2 H     H H  (CH.sub.2).sub.3 Cl                                    Cl H  CHF.sub.2                                                                           2 H     H H  CH.sub.2 CN                                            Cl H  CHF.sub.2                                                                           2 H     H H  CH.sub.2 OCH.sub.3                                     Cl H  CHF.sub.2                                                                           2 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  CHF.sub.2                                                                           2 H     H H                                                                                  ##STR294##                                            Cl H  CHF.sub.2                                                                           2 H     H H                                                                                  ##STR295##                                            Cl H  CHF.sub.2                                                                           2 H     H H  C.sub.6 H.sub.5                                        Cl H  CHF.sub.2                                                                           2 H     H H                                                                                  ##STR296##                                            Cl H  CF.sub.3                                                                            0 H     H H  CH.sub.3                                               Cl H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H  CH.sub.3                                               Cl H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H  iso-C.sub.3 H.sub.7                                    Cl H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H  iso-C.sub.4 H.sub.9                                    Cl H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H  (CH.sub.2).sub.3 Cl                                    Cl H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H  CH.sub.2 CN                                            Cl H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H                                                                                  ##STR297##                                            Cl H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H                                                                                  ##STR298##                                            Cl H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H  C.sub.6 H.sub.5                                        Cl H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H                                                                                  ##STR299##                                            Cl H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H  CH.sub.3                                               Cl H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H  iso-C.sub.3 H.sub.7                                    Cl H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H  iso-C.sub.4 H.sub.9                                    Cl H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H  (CH.sub.2).sub.3 Cl                                    Cl H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H  CH.sub.2 CN                                            Cl H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H                                                                                  ##STR300##                                            Cl H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H                                                                                  ##STR301##                                            Cl H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H  C.sub.6 H.sub.5                                        Cl H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H                                                                                  ##STR302##                                            Cl H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H  CH.sub.3                                               Cl H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H  iso-C.sub.3 H.sub.7                                    Cl H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H  iso-C.sub.4 H.sub.9                                    Cl H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H  (CH.sub.2).sub.3 Cl                                    Cl H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H  CH.sub.2 CN                                            Cl H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H                                                                                  ##STR303##                                            Cl H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H                                                                                  ##STR304##                                            Cl H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H  C.sub.6 H.sub.5                                        Cl H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H                                                                                  ##STR305##                                            Cl H  CH.sub.2 CHF.sub.2                                                                  0 H     H H  CH.sub.3                                               Cl H  CH.sub.2 CHF.sub.2                                                                  0 H     H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.2 CHF.sub.2                                                                  0 H     H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.2 CHF.sub.2                                                                  0 H     H H  iso-C.sub.3 H.sub.7                                    Cl H  CH.sub.2 CHF.sub.2                                                                  0 H     H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.2 CHF.sub.2                                                                  0 H     H H  iso-C.sub.4 H.sub.9                                    Cl H  CH.sub.2 CHF.sub.2                                                                  0 H     H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.2 CHF.sub.2                                                                  0 H     H H  (CH.sub.2).sub.3 Cl                                    Cl H  CH.sub.2 CHF.sub.2                                                                  0 H     H H  CH.sub.2 CN                                            Cl H  CH.sub.2 CHF.sub.2                                                                  0 H     H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.2 CHF.sub.2                                                                  0 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  CH.sub.2 CHF.sub.2                                                                  0 H     H H                                                                                  ##STR306##                                            Cl H  CH.sub.2 CHF.sub.2                                                                  0 H     H H                                                                                  ##STR307##                                            Cl H  CH.sub.2 CHF.sub.2                                                                  0 H     H H  C.sub.6 H.sub.5                                        Cl H  CH.sub.2 CHF.sub.2                                                                  0 H     H H                                                                                  ##STR308##                                            Cl H  CH.sub.2 CHF.sub.2                                                                  1 H     H H  CH.sub.3                                               Cl H  CH.sub.2 CHF.sub.2                                                                  1 H     H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.2 CHF.sub.2                                                                  1 H     H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.2 CHF.sub.2                                                                  1 H     H H  iso-C.sub.3 H.sub.7                                    Cl H  CH.sub.2 CHF.sub.2                                                                  1 H     H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.2 CHF.sub.2                                                                  1 H     H H  iso-C.sub.4 H.sub.9                                    Cl H  CH.sub.2 CHF.sub.2                                                                  1 H     H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.2 CHF.sub.2                                                                  1 H     H H  (CH.sub.2).sub.3 Cl                                    Cl H  CH.sub.2 CHF.sub.2                                                                  1 H     H H  CH.sub.2 CN                                            Cl H  CH.sub.2 CHF.sub.2                                                                  1 H     H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.2 CHF.sub.2                                                                  1 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  CH.sub.2 CHF.sub.2                                                                  1 H     H H                                                                                  ##STR309##                                            Cl H  CH.sub.2 CHF.sub.2                                                                  1 H     H H                                                                                  ##STR310##                                            Cl H  CH.sub.2 CHF.sub.2                                                                  1 H     H H  C.sub.6 H.sub.5                                        Cl H  CH.sub.2 CHF.sub.2                                                                  1 H     H H                                                                                  ##STR311##                                            Cl H  CH.sub.2 CHF.sub.2                                                                  2 H     H H  CH.sub.3                                               Cl H  CH.sub.2 CHF.sub.2                                                                  2 H     H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.2 CHF.sub.2                                                                  2 H     H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.2 CHF.sub.2                                                                  2 H     H H  iso-C.sub.3 H.sub.7                                    Cl H  CH.sub.2 CHF.sub.2                                                                  2 H     H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.2 CHF.sub.2                                                                  2 H     H H  iso-C.sub.4 H.sub.9                                    Cl H  CH.sub.2 CHF.sub.2                                                                  2 H     H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.2 CHF.sub.2                                                                  2 H     H H  (CH.sub.2).sub.3 Cl                                    Cl H  CH.sub.2 CHF.sub.2                                                                  2 H     H H  CH.sub.2 CN                                            Cl H  CH.sub.2 CHF.sub.2                                                                  2 H     H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.2 CHF.sub.2                                                                  2 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  CH.sub.2 CHF.sub.2                                                                  2 H     H H                                                                                  ##STR312##                                            Cl H  CH.sub.2 CHF.sub.2                                                                  2 H     H H                                                                                  ##STR313##                                            Cl H  CH.sub.2 CHF.sub.2                                                                  2 H     H H  C.sub.6 H.sub.5                                        Cl H  CH.sub.2 CHF.sub.2                                                                  2 H     H H                                                                                  ##STR314##                                            Cl H  CH.sub.2 CF.sub.3                                                                   0 H     H H  CH.sub.3                                               Cl H  CH.sub.2 CF.sub.3                                                                   0 H     H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.2 CF.sub.3                                                                   0 H     H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.2 CF.sub.3                                                                   0 H     H H  iso-C.sub.3 H.sub.7                                    Cl H  CH.sub.2 CF.sub.3                                                                   0 H     H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.2 CF.sub.3                                                                   0 H     H H  iso-C.sub.4 H.sub.9                                    Cl H  CH.sub.2 CF.sub.3                                                                   0 H     H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.2 CF.sub.3                                                                   0 H     H H  (CH.sub.2).sub.3 Cl                                    Cl H  CH.sub.2 CF.sub.3                                                                   0 H     H H  CH.sub.2 CN                                            Cl H  CH.sub.2 CF.sub.3                                                                   0 H     H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.2 CF.sub.3                                                                   0 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  CH.sub.2 CF.sub.3                                                                   0 H     H H                                                                                  ##STR315##                                            Cl H  CH.sub.2 CF.sub.3                                                                   0 H     H H                                                                                  ##STR316##                                            Cl H  CH.sub.2 CF.sub.3                                                                   0 H     H H  C.sub.6 H.sub.5                                        Cl H  CH.sub.2 CF.sub.3                                                                   0 H     H H                                                                                  ##STR317##                                            Cl H  CH.sub.2 CF.sub.3                                                                   1 H     H H  CH.sub.3                                               Cl H  CH.sub.2 CF.sub.3                                                                   1 H     H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.2 CF.sub.3                                                                   1 H     H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.2 CF.sub.3                                                                   1 H     H H  iso-C.sub.3 H.sub.7                                    Cl H  CH.sub.2 CF.sub.3                                                                   1 H     H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.2 CF.sub.3                                                                   1 H     H H  iso-C.sub.4 H.sub.9                                    Cl H  CH.sub.2 CF.sub.3                                                                   1 H     H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.2 CF.sub.3                                                                   1 H     H H  (CH.sub.2).sub.3 Cl                                    Cl H  CH.sub.2 CF.sub.3                                                                   1 H     H H  CH.sub.2 CN                                            Cl H  CH.sub.2 CF.sub.3                                                                   1 H     H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.2 CF.sub.3                                                                   1 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  CH.sub.2 CF.sub.3                                                                   1 H     H H                                                                                  ##STR318##                                            Cl H  CH.sub.2 CF.sub.3                                                                   1 H     H H                                                                                  ##STR319##                                            Cl H  CH.sub.2 CF.sub.3                                                                   1 H     H H  C.sub.6 H.sub.5                                        Cl H  CH.sub.2 CF.sub.3                                                                   1 H     H H                                                                                  ##STR320##                                            Cl H  CH.sub.2 CF.sub.3                                                                   2 H     H H  CH.sub.3                                               Cl H  CH.sub.2 CF.sub.3                                                                   2 H     H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.2 CF.sub.3                                                                   2 H     H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.2 CF.sub.3                                                                   2 H     H H  iso-C.sub.3 H.sub.7                                    Cl H  CH.sub.2 CF.sub.3                                                                   2 H     H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.2 CF.sub.3                                                                   2 H     H H  iso-C.sub.4 H.sub.9                                    Cl H  CH.sub.2 CF.sub.3                                                                   2 H     H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.2 CF.sub.3                                                                   2 H     H H  (CH.sub.2).sub.3 Cl                                    Cl H  CH.sub.2 CF.sub.3                                                                   2 H     H H  CH.sub.2 CN                                            Cl H  CH.sub.2 CF.sub.3                                                                   2 H     H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.2 CF.sub.3                                                                   2 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Cl H  CH.sub.2 CF.sub.3                                                                   2 H     H H                                                                                  ##STR321##                                            Cl H  CH.sub.2 CF.sub.3                                                                   2 H     H H                                                                                  ##STR322##                                            Cl H  CH.sub.2 CF.sub.3                                                                   2 H     H H  C.sub.6 H.sub.5                                        Cl H  CH.sub.2 CF.sub.3                                                                   2 H     H H                                                                                  ##STR323##                                            Cl CH.sub.3                                                                          CH.sub.3                                                                            0 H     H H  CH.sub.3                                               Cl CH.sub.3                                                                          CH.sub.3                                                                            1 H     H H  CH.sub.3                                               Cl CH.sub.3                                                                          CH.sub.3                                                                            2 H     H H  CH.sub.3                                               Br H  CH.sub.3                                                                            0 H     H H  CH.sub.2 OCH.sub.3                                     Br H  CH.sub.3                                                                            0 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  CH.sub.3                                                                            0 H     H H  CH.sub.3                                               Br H  CH.sub.3                                                                            0 H     H H  C.sub.2 H.sub.5                                        Br H  CH.sub.3                                                                            0 H     H H  n-C.sub.3 H.sub.7                                      Br H  CH.sub.3                                                                            0 H     H H  iso-C.sub.3 H.sub.7                                    Br H  CH.sub.3                                                                            0 H     H H  n-C.sub.4 H.sub.9                                      Br H  CH.sub.3                                                                            0 H     H H  sec-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            0 H     H H  iso-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            0 H     H H  tert-C.sub.4 H.sub.9                                   Br H  CH.sub.3                                                                            0 H     H H  n-C.sub.5 H.sub.11                                     Br H  CH.sub.3                                                                            0 H     H H  n-C.sub.6 H.sub.13                                     Br H  CH.sub.3                                                                            0 H     H H                                                                                  ##STR324##                                            Br H  CH.sub.3                                                                            0 H     H H                                                                                  ##STR325##                                            Br H  CH.sub.3                                                                            0 H     H H                                                                                  ##STR326##                                            Br H  CH.sub.3                                                                            0 H     H H                                                                                  ##STR327##                                            Br H  CH.sub.3                                                                            0 H     H H  C.sub.6 H.sub.5                                        Br H  CH.sub.3                                                                            0 H     H H                                                                                  ##STR328##                                            Br H  CH.sub.3                                                                            0 H     H H                                                                                  ##STR329##                                            Br H  CH.sub.3                                                                            0 H     H H  CH═CH.sub.2                                        Br H  CH.sub.3                                                                            0 H     H H  CH═CHCH.sub.3                                      Br H  CH.sub.3                                                                            0 H     H H  C(═CH.sub.2)CH.sub.3                               Br H  CH.sub.3                                                                            0 H     H H  CH═CHC.sub.6 H.sub.5                               Br H  CH.sub.3                                                                            0 H     H H                                                                                  ##STR330##                                            Br H  CH.sub.3                                                                            0 H     H H  (CH.sub.2).sub.4 Cl                                    Br H  CH.sub.3                                                                            0 H     H H  (CH.sub.2).sub.3 Cl                                    Br H  CH.sub.3                                                                            0 H     H H  CH.sub.2 CN                                            Br H  CH.sub.3                                                                            0 H     H H  CH.sub.2 OC.sub.6 H.sub.5                              Br H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  CH.sub.3                                               Br H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  C.sub.2 H.sub.5                                        Br H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  n-C.sub.3 H.sub.7                                      Br H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  iso-C.sub.3 H.sub.7                                    Br H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  n-C.sub.4 H.sub.9                                      Br H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  iso-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  sec-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  tert-C.sub.4 H.sub.9                                   Br H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  (CH.sub.2).sub.3 Cl                                    Br H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  (CH.sub.2).sub.4 Cl                                    Br H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  CH.sub.2 CN                                            Br H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  CH.sub.2 OCH.sub.3                                     Br H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  C.sub.6 H.sub.5                                        Br H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H                                                                                  ##STR331##                                            Br H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  CH.sub.3                                               Br H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  C.sub.2 H.sub.5                                        Br H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  n-C.sub.3 H.sub.7                                      Br H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  iso-C.sub.3 H.sub.7                                    Br H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  n-C.sub.4 H.sub.9                                      Br H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  iso-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  sec-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  tert-C.sub.4 H.sub.9                                   Br H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  (CH.sub.2).sub.3 Cl                                    Br H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  (CH.sub.2).sub.4 Cl                                    Br H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 CN                                            Br H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 OCH.sub.3                                     Br H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  C.sub.6 H.sub.5                                        Br H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H                                                                                  ##STR332##                                            Br H  CH.sub.3                                                                            0 n-C.sub.5 H7                                                                         H H  CH.sub.3                                               Br H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H  C.sub.2 H.sub.5                                        Br H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H  n-C.sub.3 H.sub.7                                      Br H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H  iso-C.sub.3 H.sub.7                                    Br H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H  n-C.sub.4 H.sub.9                                      Br H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H  iso-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H  sec-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H  tert-C.sub.4 H.sub.9                                   Br H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H  (CH.sub.2).sub.3 Cl                                    Br H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H  (CH.sub.2).sub.4 Cl                                    Br H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 CN                                            Br H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 OCH.sub.3                                     Br H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H  C.sub.6 H.sub.5                                        Br H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H                                                                                  ##STR333##                                            Br H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.3                                               Br H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H  C.sub.2 H.sub.5                                        Br H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H  n-C.sub.3 H.sub.7                                      Br H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H  iso-C.sub.3 H.sub.7                                    Br H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H  n-C.sub.4 H.sub.9                                      Br H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H  iso-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H  sec-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H  tert-C.sub.4 H.sub.9                                   Br H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H  (CH.sub.2).sub.3 Cl                                    Br H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H  (CH.sub.2).sub.4 Cl                                    Br H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 CN                                            Br H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 OCH.sub.3                                     Br H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H  C.sub.6 H.sub.5                                        Br H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H                                                                                  ##STR334##                                            Br H  CH.sub.3                                                                            0 CH.sub.2 CH.sub.3                                                                    H H  CH.sub.3                                               Br H  CH.sub.3                                                                            0 CH.sub.2 OCH.sub.3                                                                   H H  C.sub.6 H.sub.5                                        Br H  CH.sub.3                                                                            0 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  CH.sub.3                                               Br H  CH.sub.3                                                                            0 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  C.sub.6 H.sub.5                                        Br H  CH.sub.3                                                                            1 H     H H  CH.sub.3                                               Br H  CH.sub.3                                                                            1 H     H H  C.sub.2 H.sub.5                                        Br H  CH.sub.3                                                                            1 H     H H  n-C.sub.3 H.sub.7                                      Br H  CH.sub.3                                                                            1 H     H H  iso-C.sub.3 H.sub.7                                    Br H  CH.sub.3                                                                            1 H     H H  n-C.sub.4 H.sub.9                                      Br H  CH.sub.3                                                                            1 H     H H  iso-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            1 H     H H  tert-C.sub.4 H.sub.9                                   Br H  CH.sub.3                                                                            1 H     H H  (CH.sub.2).sub.3 Cl                                    Br H  CH.sub.3                                                                            1 H     H H  CH.sub.2 CN                                            Br H  CH.sub.3                                                                            1 H     H H  CH.sub.2 OCH.sub.3                                     Br H  CH.sub.3                                                                            1 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  CH.sub.3                                                                            1 H     H H                                                                                  ##STR335##                                            Br H  CH.sub.3                                                                            1 H     H H                                                                                  ##STR336##                                            Br H  CH.sub.3                                                                            1 H     H H  C.sub.6 H.sub.5                                        Br H  CH.sub.3                                                                            1 H     H H                                                                                  ##STR337##                                            Br H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  CH.sub.3                                               Br H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  C.sub.2 H.sub.5                                        Br H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  n-C.sub.3 H.sub.7                                      Br H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  iso-C.sub.3 H.sub.7                                    Br H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  n-C.sub.4 H.sub.9                                      Br H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  iso-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  sec-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  tert-C.sub.4 H.sub.9                                   Br H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  (CH.sub.2).sub.3 Cl                                    Br H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  (CH.sub.2).sub.4 Cl                                    Br H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  CH.sub.2 CN                                            Br H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  CH.sub.2 OCH.sub.3                                     Br H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  C.sub.6 H.sub.5                                        Br H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H                                                                                  ##STR338##                                            Br H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  CH.sub.3                                               Br H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  C.sub.2 H.sub.5                                        Br H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  n-C.sub.3 H.sub.7                                      Br H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  iso-C.sub.3 H.sub.7                                    Br H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  n-C.sub.4 H.sub.9                                      Br H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  iso-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  sec-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  tert-C.sub.4 H.sub.9                                   Br H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  (CH.sub.2).sub.3 Cl                                    Br H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  (CH.sub.2).sub.4 Cl                                    Br H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 CN                                            Br H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 OCH.sub.3                                     Br H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  C.sub.6 H.sub.5                                        Br H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H                                                                                  ##STR339##                                            Br H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.3                                               Br H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H  C.sub.2 H.sub.5                                        Br H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H  n-C.sub.3 H.sub.7                                      Br H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H  iso-C.sub.3 H.sub.7                                    Br H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H  n-C.sub.4 H.sub.9                                      Br H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H  iso-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H  sec-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H  tert-C.sub.4 H.sub.9                                   Br H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H  (CH.sub.2).sub.3 Cl                                    Br H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H  (CH.sub.2).sub.4 Cl                                    Br H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 CN                                            Br H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 OCH.sub.3                                     Br H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H  C.sub.6 H.sub.5                                        Br H  CH.sub.3                                                                            1 n-C.sub.3 H.sub.7                                                                    H H                                                                                  ##STR340##                                            Br H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.3                                               Br H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H  C.sub.2 H.sub.5                                        Br H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H  n-C.sub.3 H.sub.7                                      Br H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H  iso-C.sub.3 H.sub.7                                    Br H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H  n-C.sub.4 H.sub.9                                      Br H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H  iso-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H  sec-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H  tert-C.sub.4 H.sub.9                                   Br H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H  (CH.sub.2).sub.3 Cl                                    Br H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H  (CH.sub.2).sub.4 Cl                                    Br H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 CN                                            Br H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 OCH.sub.3                                     Br H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H  C.sub.6 H.sub.5                                        Br H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H                                                                                  ##STR341##                                            Br H  CH.sub.3                                                                            2 H     H H  CH.sub.3                                               Br H  CH.sub.3                                                                            2 H     H H  C.sub.2 H.sub.5                                        Br H  CH.sub.3                                                                            2 H     H H  n-C.sub.3 H.sub.7                                      Br H  CH.sub.3                                                                            2 H     H H  iso-C.sub.3 H.sub.7                                    Br H  CH.sub.3                                                                            2 H     H H  n-C.sub.4 H.sub.9                                      Br H  CH.sub.3                                                                            2 H     H H  iso-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            2 H     H H  tert-C.sub.4 H.sub.9                                   Br H  CH.sub.3                                                                            2 H     H H  (CH.sub.2).sub.3 Cl                                    Br H  CH.sub.3                                                                            2 H     H H  CH.sub.2 CN                                            Br H  CH.sub.3                                                                            2 H     H H  CH.sub.2 OCH.sub.3                                     Br H  CH.sub.3                                                                            2 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  CH.sub.3                                                                            2 H     H H                                                                                  ##STR342##                                            Br H  CH.sub.3                                                                            2 H     H H                                                                                  ##STR343##                                            Br H  CH.sub.3                                                                            2 H     H H  C.sub.6 H.sub.5                                        Br H  CH.sub.3                                                                            2 H     H H                                                                                  ##STR344##                                            Br H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  CH.sub.3                                               Br H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  C.sub.2 H.sub.5                                        Br H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  n-C.sub.3 H.sub.7                                      Br H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  iso-C.sub.3 H.sub.7                                    Br H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  n-C.sub.4 H.sub.9                                      Br H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  iso-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  sec-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  tert-C.sub.4 H.sub.9                                   Br H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  (CH.sub.2).sub.3 Cl                                    Br H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  (CH.sub.2).sub.4 Cl                                    Br H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  C.sub.6 H.sub.5                                        Br H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H                                                                                  ##STR345##                                            Br H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  CH.sub.3                                               Br H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  C.sub.2 H.sub.5                                        Br H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  n-C.sub.3 H.sub.7                                      Br H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  iso-C.sub.3 H.sub.7                                    Br H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  CH.sub.2 CN                                            Br H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  CH.sub.2 OCH.sub.3                                     Br H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  n-C.sub.4 H.sub.9                                      Br H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  iso-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  sec-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  tert-C.sub.4 H.sub.9                                   Br H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  (CH.sub.2).sub.3 Cl                                    Br H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  (CH.sub.2).sub.4 Cl                                    Br H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 CN                                            Br H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 OCH.sub.3                                     Br H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  C.sub.6 H.sub.5                                        Br H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H                                                                                  ##STR346##                                            Br H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.3                                               Br H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  C.sub.2 H.sub.5                                        Br H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  n-C.sub.3 H.sub.7                                      Br H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  iso-C.sub.3 H.sub.7                                    Br H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  n-C.sub.4 H.sub.9                                      Br H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  iso-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  sec-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  tert-C.sub.4 H.sub.9                                   Br H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  (CH.sub.2).sub.3 Cl                                    Br H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  (CH.sub.2).sub.4 Cl                                    Br H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 CN                                            Br H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 OCH.sub.3                                     Br H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  C.sub.6 H.sub.5                                        Br H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H                                                                                  ##STR347##                                            Br H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.3                                               Br H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H  C.sub.2 H.sub.5                                        Br H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H  n-C.sub.3 H.sub.7                                      Br H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H  iso-C.sub.3 H.sub.7                                    Br H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H  n-C.sub.4 H.sub.9                                      Br H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H  iso-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H  sec-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H  tert-C.sub.4 H.sub.9                                   Br H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H  (CH.sub.2).sub.3 Cl                                    Br H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H  (CH.sub.2).sub.4 Cl                                    Br H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 CN                                            Br H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 OCH.sub.3                                     Br H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H  C.sub.6 H.sub.5                                        Br H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H                                                                                  ##STR348##                                            Br H  C.sub.2 H.sub.5                                                                     0 H     H H  CH.sub.3                                               Br H  C.sub.2 H.sub.5                                                                     0 H     H H  C.sub.2 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     0 H     H H  n-C.sub.3 H.sub.7                                      Br H  C.sub.2 H.sub.5                                                                     0 H     H H  iso-C.sub.3 H.sub.7                                    Br H  C.sub.2 H.sub.5                                                                     0 H     H H  n-C.sub.4 H.sub.9                                      Br H  C.sub.2 H.sub.5                                                                     0 H     H H  iso-C.sub.4 H.sub.9                                    Br H  C.sub.2 H.sub.5                                                                     0 H     H H  sec-C.sub.4 H.sub.9                                    Br H  C.sub.2 H.sub.5                                                                     0 H     H H  tert-C.sub.4 H.sub.9                                   Br H  C.sub.2 H.sub.5                                                                     0 H     H H  n-C.sub.5 H.sub.11                                     Br H  C.sub.2 H.sub.5                                                                     0 H     H H  n-C.sub.5 H.sub.13                                     Br H  C.sub.2 H.sub.5                                                                     0 H     H H  (CH.sub.2).sub.4 Cl                                    Br H  C.sub.2 H.sub.5                                                                     0 H     H H  (CH.sub.2).sub.3 Cl                                    Br H  C.sub.2 H.sub.5                                                                     0 H     H H  CH.sub.2 CN                                            Br H  C.sub.2 H.sub.5                                                                     0 H     H H                                                                                  ##STR349##                                            Br H  C.sub.2 H.sub.5                                                                     0 H     H H                                                                                  ##STR350##                                            Br H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  CH.sub.3                                               Br H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  C.sub.2 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  n-C.sub.3 H.sub.7                                      Br H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  iso-C.sub.3 H.sub.7                                    Br H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  n-C.sub.4 H.sub.9                                      Br H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  iso-C.sub.4 H.sub.9                                    Br H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  sec-C.sub.4 H.sub.9                                    Br H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  tert-C.sub.4 H.sub.9                                   Br H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  (CH.sub.2).sub.3 Cl                                    Br H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  (CH.sub.2).sub.4 Cl                                    Br H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  CH.sub.2 CN                                            Br H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  CH.sub.2 OCH.sub.3                                     Br H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  C.sub.6 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H                                                                                  ##STR351##                                            Br H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  CH.sub.3                                               Br H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  C.sub.2 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  n-C.sub.3 H.sub.7                                      Br H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  iso-C.sub.3 H.sub.7                                    Br H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  n-C.sub.4 H.sub.9                                      Br H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  iso-C.sub.4 H.sub.9                                    Br H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  sec-C.sub.4 H.sub.9                                    Br H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  tert-C.sub.4 H.sub.9                                   Br H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  (CH.sub.2).sub.3 Cl                                    Br H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  (CH.sub.2).sub.4 Cl                                    Br H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 CN                                            Br H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 OCH.sub.3                                     Br H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  C.sub.6 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H                                                                                  ##STR352##                                            Br H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.3                                               Br H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  C.sub.2 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  n-C.sub.3 H.sub.7                                      Br H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  iso-C.sub.3 H.sub.7                                    Br H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  n-C.sub.4 H.sub.9                                      Br H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  iso-C.sub.4 H.sub.9                                    Br H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  sec-C.sub.4 H.sub.9                                    Br H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  tert-C.sub.4 H.sub.9                                   Br H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  (CH.sub.2).sub.3 Cl                                    Br H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  (CH.sub.2).sub.4 Cl                                    Br H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 CN                                            Br H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 OCH.sub.3                                     Br H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  C.sub.6 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H                                                                                  ##STR353##                                            Br H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.3                                               Br H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  C.sub.2 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  n-C.sub.3 H.sub.7                                      Br H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  iso-C.sub.3 H.sub.7                                    Br H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  n-C.sub.4 H.sub.9                                      Br H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  iso-C.sub.4 H.sub.9                                    Br H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  sec-C.sub.4 H.sub.9                                    Br H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  tert-C.sub.4 H.sub.9                                   Br H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  (CH.sub.2).sub.3 Cl                                    Br H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  (CH.sub.2).sub.4 Cl                                    Br H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 CN                                            Br H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 OCH.sub.3                                     Br H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  C.sub.6 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H                                                                                  ##STR354##                                            Br H  C.sub.2 H.sub.5                                                                     0 CH.sub.2 OCH.sub.3                                                                   H H  CH.sub.3                                               Br H  C.sub.2 H.sub.5                                                                     0 CH.sub.2 SCH.sub.3                                                                   H H  CH.sub.3                                               Br H  C.sub.2 H.sub.5                                                                     1 H     H H  CH.sub.3                                               Br H  C.sub.2 H.sub.5                                                                     1 H     H H  C.sub.2 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     1 H     H H  n-C.sub.3 H.sub.7                                      Br H  C.sub.2 H.sub.5                                                                     1 H     H H  n-C.sub.4 H.sub.9                                      Br H  C.sub.2 H.sub.5                                                                     1 H     H H  iso-C.sub.4 H.sub.9                                    Br H  C.sub.2 H.sub.5                                                                     1 H     H H  tert-C.sub.4 H.sub.9                                   Br H  C.sub.2 H.sub.5                                                                     1 H     H H  (CH.sub.2).sub.3 Cl                                    Br H  C.sub.2 H.sub.5                                                                     1 H     H H  CH.sub.2 CN                                            Br H  C.sub.2 H.sub.5                                                                     1 H     H H  CH.sub.2 OCH.sub.3                                     Br H  C.sub.2 H.sub.5                                                                     1 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  C.sub.2 H.sub.5                                                                     1 H     H H                                                                                  ##STR355##                                            Br H  C.sub.2 H.sub.5                                                                     1 H     H H                                                                                  ##STR356##                                            Br H  C.sub.2 H.sub.5                                                                     1 H     H H  C.sub.6 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     1 H     H H                                                                                  ##STR357##                                            Br H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  CH.sub.3                                               Br H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  C.sub.2 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  n-C.sub.3 H.sub.7                                      Br H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  iso-C.sub.3 H.sub.7                                    Br H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  n-C.sub.4 H.sub.9                                      Br H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  iso-C.sub.4 H.sub.9                                    Br H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  sec-C.sub.4 H.sub.9                                    Br H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  tert-C.sub.4 H.sub.9                                   Br H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  (CH.sub.2).sub.3 Cl                                    Br H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  (CH.sub.2).sub.4 Cl                                    Br H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  CH.sub.2 CN                                            Br H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  CH.sub.2 OCH.sub.3                                     Br H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  C.sub.6 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H                                                                                  ##STR358##                                            Br H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  CH.sub.3                                               Br H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  C.sub.2 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  n-C.sub.3 H.sub.7                                      Br H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  iso-C.sub.3 H.sub.7                                    Br H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  n-C.sub.4 H.sub.9                                      Br H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  iso-C.sub.4 H.sub.9                                    Br H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  sec-C.sub.4 H.sub.9                                    Br H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  tert-C.sub.4 H.sub.9                                   Br H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  (CH.sub.2).sub.3 Cl                                    Br H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  (CH.sub.2).sub.4 Cl                                    Br H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 CN                                            Br H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 OCH.sub.3                                     Br H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  C.sub.6 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H                                                                                  ##STR359##                                            Br H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.3                                               Br H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  C.sub.2 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  n-C.sub.3 H.sub.7                                      Br H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  iso-C.sub.3 H.sub.7                                    Br H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  n-C.sub.4 H.sub.9                                      Br H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  iso-C.sub.4 H.sub.9                                    Br H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  sec-C.sub.4 H.sub.9                                    Br H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  tert-C.sub.4 H.sub.9                                   Br H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  (CH.sub.2).sub.3 Cl                                    Br H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  (CH.sub.2).sub.4 Cl                                    Br H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 CN                                            Br H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 OCH.sub.3                                     Br H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  C.sub.6 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H                                                                                  ##STR360##                                            Br H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.3                                               Br H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  C.sub.2 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  n-C.sub.3 H.sub.7                                      Br H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  iso-C.sub.3 H.sub.7                                    Br H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  n-C.sub.4 H.sub.9                                      Br H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  iso-C.sub.4 H.sub.9                                    Br H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  sec-C.sub.4 H.sub.9                                    Br H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  tert-C.sub.4 H.sub.9                                   Br H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  (CH.sub.2).sub.3 Cl                                    Br H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  (CH.sub.2).sub.4 Cl                                    Br H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 CN                                            Br H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 OCH.sub.3                                     Br H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  C.sub.6 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H                                                                                  ##STR361##                                            Br H  C.sub.2 H.sub.5                                                                     2 H     H H  CH.sub.3                                               Br H  C.sub.2 H.sub.5                                                                     2 H     H H  C.sub.2 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     2 H     H H  n-C.sub.3 H.sub.7                                      Br H  C.sub.2 H.sub.5                                                                     2 H     H H  n-C.sub.4 H.sub.9                                      Br H  C.sub.2 H.sub.5                                                                     2 H     H H  iso-C.sub.4 H.sub.9                                    Br H  C.sub.2 H.sub.5                                                                     2 H     H H  tert-C.sub.4 H.sub.9                                   Br H  C.sub.2 H.sub.5                                                                     2 H     H H  (CH.sub.2).sub.3 Cl                                    Br H  C.sub.2 H.sub.5                                                                     2 H     H H  CH.sub.2 CN                                            Br H  C.sub.2 H.sub.5                                                                     2 H     H H  CH.sub.2 OCH.sub.3                                     Br H  C.sub.2 H.sub.5                                                                     2 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  C.sub.2 H.sub.5                                                                     2 H     H H                                                                                  ##STR362##                                            Br H  C.sub.2 H.sub.5                                                                     2 H     H H                                                                                  ##STR363##                                            Br H  C.sub.2 H.sub.5                                                                     2 H     H H  C.sub.6 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     2 H     H H                                                                                  ##STR364##                                            Br H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  CH.sub.3                                               Br H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  C.sub.2 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  n-C.sub.3 H.sub.7                                      Br H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  iso-C.sub.3 H.sub.7                                    Br H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  n-C.sub.4 H.sub.9                                      Br H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  iso-C.sub.4 H.sub.9                                    Br H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  sec-C.sub.4 H.sub.9                                    Br H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  tert-C.sub.4 H.sub.9                                   Br H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  (CH.sub.2).sub.3 Cl                                    Br H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  (CH.sub.2).sub.4 Cl                                    Br H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  CH.sub.2 CN                                            Br H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  CH.sub.2 OCH.sub.3                                     Br H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  C.sub.6 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H                                                                                  ##STR365##                                            Br H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  CH.sub.3                                               Br H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  C.sub.2 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  n-C.sub.3 H.sub.7                                      Br H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  iso-C.sub.3 H.sub.7                                    Br H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  n-C.sub.4 H.sub.9                                      Br H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  iso-C.sub.4 H.sub.9                                    Br H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  sec-C.sub.4 H.sub.9                                    Br H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  tert-C.sub.4 H.sub.9                                   Br H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  (CH.sub.2).sub.3 Cl                                    Br H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  (CH.sub.2).sub.4 Cl                                    Br H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 CN                                            Br H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 OCH.sub.3                                     Br H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  C.sub.6 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H                                                                                  ##STR366##                                            Br H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.3                                               Br H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  C.sub.2 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  n-C.sub.3 H.sub.7                                      Br H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  iso-C.sub.3 H.sub.7                                    Br H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  n-C.sub.4 H.sub.9                                      Br H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  iso-C.sub.4 H.sub.9                                    Br H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  sec-C.sub.4 H.sub.9                                    Br H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  tert-C.sub.4 H.sub.9                                   Br H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  (CH.sub.2).sub.3 Cl                                    Br H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  (CH.sub.2).sub.4 Cl                                    Br H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 CN                                            Br H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  CH.sub.2 OCH.sub.3                                     Br H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  C.sub.6 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H                                                                                  ##STR367##                                            Br H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.3                                               Br H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  C.sub.2 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  n-C.sub.3 H.sub.7                                      Br H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  iso-C.sub.3 H.sub.7                                    Br H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  n-C.sub.4 H.sub.9                                      Br H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  iso-C.sub.4 H.sub.9                                    Br H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  sec-C.sub.4 H.sub.9                                    Br H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  tert-C.sub.4 H.sub.9                                   Br H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  (CH.sub.2).sub.3 Cl                                    Br H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  (CH.sub.2).sub.4 Cl                                    Br H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 CN                                            Br H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  CH.sub.2 OCH.sub.3                                     Br H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  C.sub.6 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H                                                                                  ##STR368##                                            Br H  n-C.sub.3 H.sub.7                                                                   0 H     H H  CH.sub.3                                               Br H  n-C.sub.3 H.sub.7                                                                   0 H     H H  C.sub.2 H.sub.5                                        Br H  n-C.sub.3 H.sub.7                                                                   0 H     H H  n-C.sub.3 H.sub.7                                      Br H  n-C.sub.3 H.sub.7                                                                   0 H     H H  n-C.sub.4 H.sub.9                                      Br H  n-C.sub.3 H.sub.7                                                                   0 H     H H  iso-C.sub.4 H.sub.9                                    Br H  n-C.sub.3 H.sub.7                                                                   0 H     H H  tert-C.sub.4 H.sub.9                                   Br H  n-C.sub.3 H.sub.7                                                                   0 H     H H  (CH.sub.2).sub.3 Cl                                    Br H  n-C.sub.3 H.sub.7                                                                   0 H     H H  CH.sub.2 CN                                            Br H  n-C.sub.3 H.sub.7                                                                   0 H     H H  CH.sub.2 OCH.sub.3                                     Br H  n-C.sub.3 H.sub.7                                                                   0 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  n-C.sub.3 H.sub.7                                                                   0 H     H H                                                                                  ##STR369##                                            Br H  n-C.sub.3 H.sub.7                                                                   0 H     H H                                                                                  ##STR370##                                            Br H  n-C.sub.3 H.sub.7                                                                   0 H     H H  C.sub.6 H.sub.5                                        Br H  n-C.sub.3 H.sub.7                                                                   0 H     H H                                                                                  ##STR371##                                            Br H  n-C.sub.3 H.sub.7                                                                   1 H     H H  CH.sub.3                                               Br H  n-C.sub.3 H.sub.7                                                                   1 H     H H  C.sub.2 H.sub.5                                        Br H  n-C.sub.3 H.sub.7                                                                   1 H     H H  n-C.sub.3 H.sub.7                                      Br H  n-C.sub.3 H.sub.7                                                                   1 H     H H  n-C.sub.4 H.sub.9                                      Br H  n-C.sub.3 H.sub.7                                                                   1 H     H H  iso-C.sub.4 H.sub.9                                    Br H  n-C.sub.3 H.sub.7                                                                   1 H     H H  tert-C.sub.4 H.sub.9                                   Br H  n-C.sub.3 H.sub.7                                                                   1 H     H H  (CH.sub.2).sub.3 Cl                                    Br H  n-C.sub.3 H.sub.7                                                                   1 H     H H  CH.sub.2 CN                                            Br H  n-C.sub.3 H.sub.7                                                                   1 H     H H  CH.sub.2 OCH.sub.3                                     Br H  n-C.sub.3 H.sub.7                                                                   1 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  n-C.sub.3 H.sub.7                                                                   1 H     H H                                                                                  ##STR372##                                            Br H  n-C.sub.3 H.sub.7                                                                   1 H     H H                                                                                  ##STR373##                                            Br H  n-C.sub.3 H.sub.7                                                                   1 H     H H  C.sub.6 H.sub.5                                        Br H  n-C.sub.3 H.sub.7                                                                   1 H     H H                                                                                  ##STR374##                                            Br H  n-C.sub.3 H.sub.7                                                                   2 H     H H  CH.sub.3                                               Br H  n-C.sub.3 H.sub.7                                                                   2 H     H H  C.sub.2 H.sub.5                                        Br H  n-C.sub.3 H.sub.7                                                                   2 H     H H  n-C.sub.3 H.sub.7                                      Br H  n-C.sub.3 H.sub.7                                                                   2 H     H H  n-C.sub.4 H.sub.9                                      Br H  n-C.sub.3 H.sub.7                                                                   2 H     H H  iso-C.sub.4 H.sub.9                                    Br H  n-C.sub.3 H.sub.7                                                                   2 H     H H  tert-C.sub.4 H.sub.9                                   Br H  n-C.sub.3 H.sub.7                                                                   2 H     H H  (CH.sub.2).sub.3 Cl                                    Br H  n-C.sub.3 H.sub.7                                                                   2 H     H H  CH.sub.2 CN                                            Br H  n-C.sub.3 H.sub.7                                                                   2 H     H H  CH.sub.2 OCH.sub.3                                     Br H  n-C.sub.3 H.sub.7                                                                   2 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  n-C.sub.3 H.sub.7                                                                   2 H     H H                                                                                  ##STR375##                                            Br H  n-C.sub.3 H.sub.7                                                                   2 H     H H                                                                                  ##STR376##                                            Br H  n-C.sub.3 H.sub.7                                                                   2 H     H H  C.sub.6 H.sub.5                                        Br H  n-C.sub.3 H.sub.7                                                                   2 H     H H                                                                                  ##STR377##                                            Br H  CHF.sub.2                                                                           0 H     H H  CH.sub.3                                               Br H  CHF.sub.2                                                                           0 H     H H  C.sub.2 H.sub.5                                        Br H  CHF.sub.2                                                                           0 H     H H  n-C.sub.3 H.sub.7                                      Br H  CHF.sub.2                                                                           0 H     H H  n-C.sub.4 H.sub.9                                      Br H  CHF.sub.2                                                                           0 H     H H  iso-C.sub.4 H.sub.9                                    Br H  CHF.sub.2                                                                           0 H     H H  tert-C.sub.4 H.sub.9                                   Br H  CHF.sub.2                                                                           0 H     H H  (CH.sub.2).sub.3 Cl                                    Br H  CHF.sub.2                                                                           0 H     H H  CH.sub.2 CN                                            Br H  CHF.sub.2                                                                           0 H     H H  CH.sub.2 OCH.sub.3                                     Br H  CHF.sub.2                                                                           0 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  CHF.sub.2                                                                           0 H     H H                                                                                  ##STR378##                                            Br H  CHF.sub.2                                                                           0 H     H H                                                                                  ##STR379##                                            Br H  CHF.sub.2                                                                           0 H     H H  C.sub.6 H.sub.5                                        Br H  CHF.sub.2                                                                           0 H     H H                                                                                  ##STR380##                                            Br H  CHF.sub.2                                                                           1 H     H H  CH.sub.3                                               Br H  CHF.sub.2                                                                           1 H     H H  C.sub.2 H.sub.5                                        Br H  CHF.sub.2                                                                           1 H     H H  n-C.sub.3 H.sub.7                                      Br H  CHF.sub.2                                                                           1 H     H H  n-C.sub.4 H.sub.9                                      Br H  CHF.sub.2                                                                           1 H     H H  iso-C.sub.4 H.sub.9                                    Br H  CHF.sub.2                                                                           1 H     H H  tert-C.sub.4 H.sub.9                                   Br H  CHF.sub.2                                                                           1 H     H H  (CH.sub.2).sub.3 Cl                                    Br H  CHF.sub.2                                                                           1 H     H H  CH.sub.2 CN                                            Br H  CHF.sub.2                                                                           1 H     H H  CH.sub.2 OCH.sub.3                                     Br H  CHF.sub.2                                                                           1 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  CHF.sub.2                                                                           1 H     H H                                                                                  ##STR381##                                            Br H  CHF.sub.2                                                                           1 H     H H                                                                                  ##STR382##                                            Br H  CHF.sub.2                                                                           1 H     H H  C.sub.6 H.sub.5                                        Br H  CHF.sub.2                                                                           1 H     H H                                                                                  ##STR383##                                            Br H  CHF.sub.2                                                                           2 H     H H  CH.sub.3                                               Br H  CHF.sub.2                                                                           2 H     H H  C.sub.2 H.sub.5                                        Br H  CHF.sub.2                                                                           2 H     H H  n-C.sub.3 H.sub.7                                      Br H  CHF.sub.2                                                                           2 H     H H  n-C.sub.4 H.sub.9                                      Br H  CHF.sub.2                                                                           2 H     H H  iso-C.sub.4 H.sub.9                                    Br H  CHF.sub.2                                                                           2 H     H H  tert-C.sub.4 H.sub.9                                   Br H  CHF.sub.2                                                                           2 H     H H  (CH.sub.2).sub.3 Cl                                    Br H  CHF.sub.2                                                                           2 H     H H  CH.sub.2 CN                                            Br H  CHF.sub.2                                                                           2 H     H H  CH.sub.2 OCH.sub.3                                     Br H  CHF.sub.2                                                                           2 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  CHF.sub.2                                                                           2 H     H H                                                                                  ##STR384##                                            Br H  CHF.sub.2                                                                           2 H     H H                                                                                  ##STR385##                                            Br H  CHF.sub.2                                                                           2 H     H H  C.sub.6 H.sub.5                                        Br H  CHF.sub.2                                                                           2 H     H H                                                                                  ##STR386##                                            Br H  CF.sub.3                                                                            0 H     H H  C.sub.6 H.sub.5                                        Br H  CF.sub.3                                                                            0 H     H H  CH.sub.3                                               Br H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H  CH.sub.3                                               Br H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H  C.sub.2 H.sub.5                                        Br H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H  n-C.sub.3 H.sub.7                                      Br H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H  iso-C.sub.3 H.sub.7                                    Br H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H  n-C.sub.4 H.sub.9                                      Br H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H  iso-C.sub.4 H.sub.9                                    Br H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H  tert-C.sub.4 H.sub.9                                   Br H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H  (CH.sub.2).sub.3 Cl                                    Br H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H  CH.sub.2 CN                                            Br H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H  CH.sub.2 OCH.sub.3                                     Br H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H                                                                                  ##STR387##                                            Br H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H                                                                                  ##STR388##                                            Br H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H  C.sub.6 H.sub.5                                        Br H  CH.sub.2 CH.sub.2 F                                                                 0 H     H H                                                                                  ##STR389##                                            Br H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H  CH.sub.3                                               Br H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H  C.sub.2 H.sub.5                                        Br H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H  n-C.sub.3 H.sub.7                                      Br H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H  iso-C.sub.3 H.sub.7                                    Br H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H  n-C.sub.4 H.sub.9                                      Br H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H  iso-C.sub.4 H.sub.9                                    Br H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H  tert-C.sub.4 H.sub.9                                   Br H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H  (CH.sub.2).sub.3 Cl                                    Br H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H  CH.sub.2 CN                                            Br H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H  CH.sub.2 OCH.sub.3                                     Br H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H                                                                                  ##STR390##                                            Br H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H                                                                                  ##STR391##                                            Br H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H  C.sub.6 H.sub.5                                        Br H  CH.sub.2 CH.sub.2 F                                                                 1 H     H H                                                                                  ##STR392##                                            Br H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H  CH.sub.3                                               Br H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H  C.sub.2 H.sub.5                                        Br H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H  n-C.sub.3 H.sub.7                                      Br H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H  iso-C.sub.3 H.sub.7                                    Br H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H  n-C.sub.4 H.sub.9                                      Br H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H  iso-C.sub.4 H.sub.9                                    Br H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H  tert-C.sub.4 H.sub.9                                   Br H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H  (CH.sub.2).sub.3 Cl                                    Br H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H  CH.sub.2 CN                                            Br H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H  CH.sub.2 OCH.sub.3                                     Br H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H                                                                                  ##STR393##                                            Br H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H                                                                                  ##STR394##                                            Br H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H  C.sub.6 H.sub.5                                        Br H  CH.sub.2 CH.sub.2 F                                                                 2 H     H H                                                                                  ##STR395##                                            Br H  CH.sub.2 CHF.sub.2                                                                  0 H     H H  CH.sub.3                                               Br H  CH.sub.2 CHF.sub.2                                                                  0 H     H H  C.sub.2 H.sub.5                                        Br H  CH.sub.2 CHF.sub.2                                                                  0 H     H H  n-C.sub.3 H.sub.7                                      Br H  CH.sub.2 CHF.sub.2                                                                  0 H     H H  iso-C.sub.3 H.sub.7                                    Br H  CH.sub.2 CHF.sub.2                                                                  0 H     H H  n-C.sub.4 H.sub.9                                      Br H  CH.sub.2 CHF.sub.2                                                                  0 H     H H  iso-C.sub.4 H.sub.9                                    Br H  CH.sub.2 CHF.sub.2                                                                  0 H     H H  tert-C.sub.4 H.sub.9                                   Br H  CH.sub.2 CHF.sub.2                                                                  0 H     H H  (CH.sub.2).sub.3 Cl                                    Br H  CH.sub.2 CHF.sub.2                                                                  0 H     H H  CH.sub.2 CN                                            Br H  CH.sub.2 CHF.sub.2                                                                  0 H     H H  CH.sub.2 OCH.sub.3                                     Br H  CH.sub.2 CHF.sub.2                                                                  0 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  CH.sub.2 CHF.sub.2                                                                  0 H     H H                                                                                  ##STR396##                                            Br H  CH.sub.2 CHF.sub.2                                                                  0 H     H H                                                                                  ##STR397##                                            Br H  CH.sub.2 CHF.sub.2                                                                  0 H     H H  C.sub.6 H.sub.5                                        Br H  CH.sub.2 CHF.sub.2                                                                  0 H     H H                                                                                  ##STR398##                                            Br H  CH.sub.2 CHF.sub.2                                                                  1 H     H H  CH.sub.3                                               Br H  CH.sub.2 CHF.sub.2                                                                  1 H     H H  C.sub.2 H.sub.5                                        Br H  CH.sub.2 CHF.sub.2                                                                  1 H     H H  n-C.sub.3 H.sub.7                                      Br H  CH.sub.2 CHF.sub.2                                                                  1 H     H H  iso-C.sub.3 H.sub.7                                    Br H  CH.sub.2 CHF.sub.2                                                                  1 H     H H  n-C.sub.4 H.sub.9                                      Br H  CH.sub.2 CHF.sub.2                                                                  1 H     H H  iso-C.sub.4 H.sub.9                                    Br H  CH.sub.2 CHF.sub.2                                                                  1 H     H H  tert-C.sub.4 H.sub.9                                   Br H  CH.sub.2 CHF.sub.2                                                                  1 H     H H  (CH.sub.2).sub.3 Cl                                    Br H  CH.sub.2 CHF.sub.2                                                                  1 H     H H  CH.sub.2 CN                                            Br H  CH.sub.2 CHF.sub.2                                                                  1 H     H H  CH.sub.2 OCH.sub.3                                     Br H  CH.sub.2 CHF.sub.2                                                                  1 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  CH.sub.2 CHF.sub.2                                                                  1 H     H H                                                                                  ##STR399##                                            Br H  CH.sub.2 CHF.sub.2                                                                  1 H     H H                                                                                  ##STR400##                                            Br H  CH.sub.2 CHF.sub.2                                                                  1 H     H H  C.sub.6 H.sub.5                                        Br H  CH.sub.2 CHF.sub.2                                                                  1 H     H H                                                                                  ##STR401##                                            Br H  CH.sub.2 CHF.sub.2                                                                  2 H     H H  CH.sub.3                                               Br H  CH.sub.2 CHF.sub.2                                                                  2 H     H H  C.sub.2 H.sub.5                                        Br H  CH.sub.2 CHF.sub.2                                                                  2 H     H H  n-C.sub.3 H.sub.7                                      Br H  CH.sub.2 CHF.sub.2                                                                  2 H     H H  iso-C.sub.3 H.sub.7                                    Br H  CH.sub.2 CHF.sub.2                                                                  2 H     H H  n-C.sub.4 H.sub.9                                      Br H  CH.sub.2 CHF.sub.2                                                                  2 H     H H  iso-C.sub.4 H.sub.9                                    Br H  CH.sub.2 CHF.sub.2                                                                  2 H     H H  tert-C.sub.4 H.sub.9                                   Br H  CH.sub.2 CHF.sub.2                                                                  2 H     H H  (CH.sub.2).sub.3 Cl                                    Br H  CH.sub.2 CHF.sub.2                                                                  2 H     H H  CH.sub.2 CN                                            Br H  CH.sub.2 CHF.sub.2                                                                  2 H     H H  CH.sub.2 OCH.sub.3                                     Br H  CH.sub.2 CHF.sub.2                                                                  2 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  CH.sub.2 CHF.sub.2                                                                  2 H     H H                                                                                  ##STR402##                                            Br H  CH.sub.2 CHF.sub.2                                                                  2 H     H H                                                                                  ##STR403##                                            Br H  CH.sub.2 CHF.sub.2                                                                  2 H     H H  C.sub.6 H.sub.5                                        Br H  CH.sub.2 CHF.sub.2                                                                  2 H     H H                                                                                  ##STR404##                                            Br H  CH.sub.2 CF.sub.3                                                                   0 H     H H  CH.sub.3                                               Br H  CH.sub.2 CF.sub.3                                                                   0 H     H H  C.sub.2 H.sub.5                                        Br H  CH.sub.2 CF.sub.3                                                                   0 H     H H  n-C.sub.3 H.sub.7                                      Br H  CH.sub.2 CF.sub.3                                                                   0 H     H H  iso-C.sub.3 H.sub.7                                    Br H  CH.sub.2 CF.sub.3                                                                   0 H     H H  n-C.sub.4 H.sub.9                                      Br H  CH.sub.2 CF.sub.3                                                                   0 H     H H  iso-C.sub.4 H.sub.9                                    Br H  CH.sub.2 CF.sub.3                                                                   0 H     H H  tert-C.sub.4 H.sub.9                                   Br H  CH.sub.2 CF.sub.3                                                                   0 H     H H  (CH.sub.2).sub.3 Cl                                    Br H  CH.sub.2 CF.sub.3                                                                   0 H     H H  CH.sub.2 CN                                            Br H  CH.sub.2 CF.sub.3                                                                   0 H     H H  CH.sub.2 OCH.sub.3                                     Br H  CH.sub.2 CF.sub.3                                                                   0 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  CH.sub.2 CF.sub.3                                                                   0 H     H H                                                                                  ##STR405##                                            Br H  CH.sub.2 CF.sub.3                                                                   0 H     H H                                                                                  ##STR406##                                            Br H  CH.sub.2 CF.sub.3                                                                   0 H     H H  C.sub.6 H.sub.5                                        Br H  CH.sub.2 CF.sub.3                                                                   0 H     H H                                                                                  ##STR407##                                            Br H  CH.sub.2 CF.sub.3                                                                   1 H     H H  CH.sub.3                                               Br H  CH.sub.2 CF.sub.3                                                                   1 H     H H  C.sub.2 H.sub.5                                        Br H  CH.sub.2 CF.sub.3                                                                   1 H     H H  n-C.sub.3 H.sub.7                                      Br H  CH.sub.2 CF.sub.3                                                                   1 H     H H  iso-C.sub.3 H.sub.7                                    Br H  CH.sub.2 CF.sub.3                                                                   1 H     H H  n-C.sub.4 H.sub.9                                      Br H  CH.sub.2 CF.sub.3                                                                   1 H     H H  iso-C.sub.4 H.sub.9                                    Br H  CH.sub.2 CF.sub.3                                                                   1 H     H H  tert-C.sub.4 H.sub.9                                   Br H  CH.sub.2 CF.sub.3                                                                   1 H     H H  (CH.sub.2).sub.3 Cl                                    Br H  CH.sub.2 CF.sub.3                                                                   1 H     H H  CH.sub.2 CN                                            Br H  CH.sub.2 CF.sub.3                                                                   1 H     H H  CH.sub.2 OCH.sub.3                                     Br H  CH.sub.2 CF.sub.3                                                                   1 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  CH.sub.2 CF.sub.3                                                                   1 H     H H                                                                                  ##STR408##                                            Br H  CH.sub.2 CF.sub.3                                                                   1 H     H H                                                                                  ##STR409##                                            Br H  CH.sub.2 CF.sub.3                                                                   1 H     H H  C.sub.6 H.sub.5                                        Br H  CH.sub.2 CF.sub.3                                                                   1 H     H H                                                                                  ##STR410##                                            Br H  CH.sub.2 CF.sub.3                                                                   2 H     H H  CH.sub.3                                               Br H  CH.sub.2 CF.sub.3                                                                   2 H     H H  C.sub.2 H.sub.5                                        Br H  CH.sub.2 CF.sub.3                                                                   2 H     H H  n-C.sub.3 H.sub.7                                      Br H  CH.sub.2 CF.sub.3                                                                   2 H     H H  iso-C.sub.3 H.sub.7                                    Br H  CH.sub.2 CF.sub.3                                                                   2 H     H H  n-C.sub.4 H.sub.9                                      Br H  CH.sub.2 CF.sub.3                                                                   2 H     H H  iso-C.sub.4 H.sub.9                                    Br H  CH.sub.2 CF.sub.3                                                                   2 H     H H  tert-C.sub.4 H.sub.9                                   Br H  CH.sub.2 CF.sub.3                                                                   2 H     H H  (CH.sub.2).sub.3 Cl                                    Br H  CH.sub.2 CF.sub.3                                                                   2 H     H H  CH.sub.2 CN                                            Br H  CH.sub.2 CF.sub.3                                                                   2 H     H H  CH.sub.2 OCH.sub.3                                     Br H  CH.sub.2 CF.sub.3                                                                   2 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  CH.sub.2 CF.sub.3                                                                   2 H     H H                                                                                  ##STR411##                                            Br H  CH.sub.2 CF.sub.3                                                                   2 H     H H                                                                                  ##STR412##                                            Br H  CH.sub.2 CF.sub.3                                                                   2 H     H H  C.sub.6 H.sub.5                                        Br H  CH.sub.2 CF.sub.3                                                                   2 H     H H                                                                                  ##STR413##                                            I  H  C.sub.2 H.sub.5                                                                     0 H     H H  C.sub.6 H.sub.5                                        I  H  CH.sub.3                                                                            0 H     H H  CH.sub.3                                               I  H  CH.sub.3                                                                            0 H     H H  C.sub.2 H.sub.5                                        I  H  CH.sub.3                                                                            0 H     H H  n-C.sub.3 H.sub.7                                      I  H  CH.sub.3                                                                            0 H     H H  iso-C.sub.3 H.sub.7                                    I  H  CH.sub.3                                                                            0 H     H H  n-C.sub.4 H.sub.9                                      I  H  CH.sub.3                                                                            2 H     H H  C.sub.2 H.sub.5                                        I  H  CH.sub.3                                                                            1 H     H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            0 H     H H  COCH.sub.3                                             Cl H  CH.sub.3                                                                            1 H     H H  COCH.sub.3                                             Cl H  CH.sub.3                                                                            2 H     H H  COCH.sub.3                                             Cl H  C.sub.2 H.sub.5                                                                     0 H     H H  COCH.sub.3                                             Cl H  CH.sub.3                                                                            0 H     H H  CO.sub.2 CH.sub.3                                      Cl H  CH.sub.3                                                                            1 H     H H  CO.sub.2 CH.sub.3                                      Cl H  CH.sub.3                                                                            2 H     H H  CO.sub.2 CH.sub.3                                      Cl H  C.sub.2 H.sub.5                                                                     0 H     H H  CO.sub.2 CH.sub.3                                      Cl H  C.sub.2 H.sub.5                                                                     1 H     H H  CO.sub.2 CH.sub.3                                      Cl H  C.sub.2 H.sub.5                                                                     2 H     H H  CO.sub.2 CH.sub.3                                      Cl H  CH.sub.3                                                                            0 H     H H  CO.sub.2 C.sub.2 H.sub.5                               Cl H  CH.sub.3                                                                            1 H     H H  CO.sub.2 C.sub.2 H.sub.5                               Cl H  CH.sub.3                                                                            2 H     H H  CO.sub.2 C.sub.2 H.sub.5                               Cl H  C.sub.2 H.sub.5                                                                     0 H     H H  CO.sub.2 C.sub.2 H.sub.5                               Cl H  C.sub.2 H.sub.5                                                                     1 H     H H  CO.sub.2 C.sub.2 H.sub.5                               Cl H  C.sub.2 H.sub.5                                                                     2 H     H H  CO.sub.2 C.sub.2 H.sub.5                               Br H  C.sub.2 H.sub.5                                                                     0 H     H H                                                                                  ##STR414##                                            Br H  C.sub.2 H.sub.5                                                                     0 H     H H                                                                                  ##STR415##                                            Br H  C.sub.2 H.sub.5                                                                     0 H     H H  C.sub.6 H.sub.5                                        Br H  C.sub.2 H.sub.5                                                                     0 H     H H  CH.sub.2 CO.sub.2 C.sub.2 H.sub.5                      Br H  C.sub.2 H.sub.5                                                                     0 H     H H  CH.sub.2 OCH.sub.3                                     Br H  C.sub.2 H.sub.5                                                                     0 H     H H                                                                                  ##STR416##                                            Br H  C.sub.2 H.sub.5                                                                     1 H     H H  iso-C.sub.3 H.sub.7                                    Br H  C.sub.2 H.sub.5                                                                     1 H     H H  sec-C.sub.4 H.sub.9                                    Br H  C.sub.2 H.sub.5                                                                     2 H     H H  iso-C.sub.3 H.sub.7                                    Br H  C.sub.2 H.sub.5                                                                     2 H     H H  sec-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            1 H     H H  sec-C.sub.4 H.sub.9                                    Br H  CH.sub.3                                                                            2 H     H H  sec-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H                                                                                  ##STR417##                                            Cl H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  COCH.sub.3                                             Cl H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  CO.sub.2 C.sub.2 H.sub.5                               Cl H  C.sub.2 H.sub.5                                                                     0 C.sub.2 H.sub.5                                                                      H H  CO.sub.2 CH.sub.3                                      Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.2 OCH.sub.3                                                                   H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.2 OCH.sub.3                                                                   H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.2 OCH.sub.3                                                                   H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.2 OCH.sub.3                                                                   H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.2 OCH.sub.3                                                                   H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.2 SCH.sub.3                                                                   H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.2 SCH.sub.3                                                                   H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.2 SCH.sub.3                                                                   H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.2 SCH.sub.3                                                                   H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.2 SCH.sub.3                                                                   H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H                                                                                  ##STR418##                                            Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  COCH.sub.3                                             Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  CO.sub.2 C.sub.2 H.sub.5                               Cl H  C.sub.2 H.sub.5                                                                     0 CH.sub.3                                                                             H H  CO.sub.2 CH.sub.3                                      Cl H  C.sub.2 H.sub.5                                                                     0 COC.sub.2 H.sub.5                                                                    H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     0 COC.sub.2 H.sub.5                                                                    H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     0 COC.sub.2 H.sub.5                                                                    H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     0 COC.sub.2 H.sub.5                                                                    H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     0 COC.sub.3 H.sub.7 -n                                                                 H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     0 COC.sub.3 H.sub.7 -n                                                                 H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     0 COC.sub.3 H.sub.7 -n                                                                 H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     0 COC.sub.3 H.sub.7 -n                                                                 H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     0 COC.sub.3 H.sub.7 -n                                                                 H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     0 COCH.sub.3                                                                           H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     0 COCH.sub.3                                                                           H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     0 COCH.sub.3                                                                           H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     0 COCH.sub.3                                                                           H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     0 COCH.sub.3                                                                           H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     0 COCH.sub.3                                                                           H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     0 H     H H  (CH.sub.2).sub.5 Br                                    Cl H  C.sub.2 H.sub.5                                                                     0 H     H H  CH.sub.2 CH.sub.2 CO.sub.2 H                           Cl H  C.sub.2 H.sub.5                                                                     0 H     H H  CH.sub.2 CH.sub.2 SCH.sub.3                            Cl H  C.sub.2 H.sub.5                                                                     0 H     H H  CO.sub.2 C.sub.2 H.sub.5                               Cl H  C.sub.2 H.sub.5                                                                     0 H     H H  CO.sub.2 CH.sub.3                                      Cl H  C.sub.2 H.sub.5                                                                     0 H     H H  COCH.sub.3                                             Cl H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H                                                                                  ##STR419##                                            Cl H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  COCH.sub.3                                             Cl H  C.sub.2 H.sub.5                                                                     0 iso-C.sub.3 H.sub.7                                                                  H H  CO.sub.2 CH.sub.3                                      Cl H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H                                                                                  ##STR420##                                            Cl H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  COCH.sub.3                                             Cl H  C.sub.2 H.sub.5                                                                     0 n-C.sub.3 H.sub.7                                                                    H H  CO.sub.2 CH.sub.3                                      Cl H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H                                                                                  ##STR421##                                            Cl H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  COCH.sub.3                                             Cl H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  CO.sub.2 C.sub.2 H.sub.5                               Cl H  C.sub.2 H.sub.5                                                                     1 C.sub.2 H.sub.5                                                                      H H  CO.sub.2 CH.sub.3                                      Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.2 OCH.sub.3                                                                   H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.2 OCH.sub.3                                                                   H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.2 OCH.sub.3                                                                   H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.2 OCH.sub.3                                                                   H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.2 OCH.sub.3                                                                   H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.2 OCH.sub.3                                                                   H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.2 SCH.sub.3                                                                   H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.2 SCH.sub.3                                                                   H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.2 SCH.sub.3                                                                   H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.2 SCH.sub.3                                                                   H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.2 SCH.sub.3                                                                   H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.2 SCH.sub.3                                                                   H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H                                                                                  ##STR422##                                            Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  COCH.sub.3                                             Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  CO.sub.2 C.sub.2 H.sub.5                               Cl H  C.sub.2 H.sub.5                                                                     1 CH.sub.3                                                                             H H  CO.sub.2 CH.sub.3                                      Cl H  C.sub.2 H.sub.5                                                                     1 COC.sub.2 H.sub.5                                                                    H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     1 COC.sub.2 H.sub.5                                                                    H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     1 COC.sub.2 H.sub.5                                                                    H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     1 COC.sub.2 H.sub.5                                                                    H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     1 COC.sub.2 H.sub.5                                                                    H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     1 COC.sub.2 H.sub.5                                                                    H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     1 COC.sub.3 H.sub.7 -n                                                                 H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     1 COC.sub.3 H.sub.7 -n                                                                 H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     1 COC.sub.3 H.sub.7 -n                                                                 H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     1 COC.sub.3 H.sub.7 -n                                                                 H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     1 COC.sub.3 H.sub.7 -n                                                                 H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     1 COC.sub.3 H.sub.7 -n                                                                 H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     1 COCH.sub.3                                                                           H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     1 COCH.sub.3                                                                           H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     1 COCH.sub.3                                                                           H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     1 COCH.sub.3                                                                           H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     1 COCH.sub.3                                                                           H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     1 COCH.sub.3                                                                           H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     1 H     H H  (CH.sub.2)sBr                                          Cl H  C.sub.2 H.sub.5                                                                     1 H     H H  CH.sub.2 CH.sub.2 CO.sub.2 H                           Cl H  C.sub.2 H.sub.5                                                                     1 H     H H  CH.sub.2 CH.sub.2 SCH.sub.3                            Cl H  C.sub.2 H.sub.5                                                                     1 H     H H  CO.sub.2 C.sub.2 H.sub.5                               Cl H  C.sub.2 H.sub.5                                                                     1 H     H H  CO.sub.2 CH.sub.3                                      Cl H  C.sub.2 H.sub.5                                                                     1 H     H H  COCH.sub.3                                             Cl H  C.sub.2 H.sub.5                                                                     1 H     H H                                                                                  ##STR423##                                            Cl H  C.sub.2 H.sub.5                                                                     1 H     H H                                                                                  ##STR424##                                            Cl H  C.sub.2 H.sub.5                                                                     1 H     H H  sec-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H                                                                                  ##STR425##                                            Cl H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  COCH.sub.3                                             Cl H  C.sub.2 H.sub.5                                                                     1 iso-C.sub.3 H.sub.7                                                                  H H  CO.sub.2 CH.sub.3                                      Cl H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H                                                                                  ##STR426##                                            Cl H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  COCH.sub.3                                             Cl H  C.sub.2 H.sub.5                                                                     1 n-C.sub.3 H.sub.7                                                                    H H  CO.sub.2 CH.sub.3                                      Cl H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H                                                                                  ##STR427##                                            Cl H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  COCH.sub.3                                             Cl H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  CO.sub.2 C.sub.2 H.sub.5                               Cl H  C.sub.2 H.sub.5                                                                     2 C.sub.2 H.sub.5                                                                      H H  CO.sub.2 CH.sub.3                                      Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.2 OCH.sub.3                                                                   H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.2 OCH.sub.3                                                                   H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.2 OCH.sub.3                                                                   H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.2 OCH.sub.3                                                                   H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.2 OCH.sub.3                                                                   H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.2 OCH.sub.3                                                                   H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.2 SCH.sub.3                                                                   H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.2 SCH.sub.3                                                                   H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.2 SCH.sub.3                                                                   H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.2 SCH.sub.3                                                                   H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.2 SCH.sub.3                                                                   H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.2 SCH.sub.3                                                                   H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H                                                                                  ##STR428##                                            Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  COCH.sub.3                                             Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  CO.sub.2 C.sub.2 H.sub.5                               Cl H  C.sub.2 H.sub.5                                                                     2 CH.sub.3                                                                             H H  CO.sub.2 CH.sub.3                                      Cl H  C.sub.2 H.sub.5                                                                     2 COC.sub.2 H.sub.5                                                                    H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     2 COC.sub.2 H.sub.5                                                                    H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     2 COC.sub.2 H.sub.5                                                                    H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     2 COC.sub.2 H.sub.5                                                                    H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     2 COC.sub.2 H.sub.5                                                                    H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     2 COC.sub.2 H.sub.5                                                                    H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     2 COC.sub.3 H.sub.7 -n                                                                 H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     2 COC.sub.3 H.sub.7 -n                                                                 H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     2 COC.sub.3 H.sub.7 -n                                                                 H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     2 COC.sub.3 H.sub.7 -n                                                                 H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     2 COC.sub.3 H.sub.7 -n                                                                 H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     2 COC.sub.3 H.sub.7 -n                                                                 H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     2 COCH.sub.3                                                                           H H  C.sub.2 H.sub.5                                        Cl H  C.sub.2 H.sub.5                                                                     2 COCH.sub.3                                                                           H H  CH.sub.2 OCH.sub.3                                     Cl H  C.sub.2 H.sub.5                                                                     2 COCH.sub.3                                                                           H H  CH.sub.3                                               Cl H  C.sub.2 H.sub.5                                                                     2 COCH.sub.3                                                                           H H  n-C.sub.3 H.sub.7                                      Cl H  C.sub.2 H.sub.5                                                                     2 COCH.sub.3                                                                           H H  n-C.sub.4 H.sub.9                                      Cl H  C.sub.2 H.sub.5                                                                     2 COCH.sub.3                                                                           H H  tert-C.sub.4 H.sub.9                                   Cl H  C.sub.2 H.sub.5                                                                     2 H     H H  (CH.sub.2).sub.5 Br                                    Cl H  C.sub.2 H.sub.5                                                                     2 H     H H  CH.sub.2 CH.sub.2 CO.sub.2 H                           Cl H  C.sub.2 H.sub.5                                                                     2 H     H H  CH.sub.2 CH.sub.2 SCH.sub.3                            Cl H  C.sub.2 H.sub.5                                                                     2 H     H H  CO.sub.2 C.sub.2 H.sub.5                               Cl H  C.sub.2 H.sub.5                                                                     2 H     H H  CO.sub.2 CH.sub.3                                      Cl H  C.sub.2 H.sub.5                                                                     2 H     H H  COCH.sub.3                                             Cl H  C.sub.2 H.sub.5                                                                     2 H     H H                                                                                  ##STR429##                                            Cl H  C.sub.2 H.sub.5                                                                     2 H     H H                                                                                  ##STR430##                                            Cl H  C.sub.2 H.sub.5                                                                     2 H     H H  sec-C.sub.4 H.sub.9                                    Cl H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H                                                                                  ##STR431##                                            Cl H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  COCH.sub.3                                             Cl H  C.sub.2 H.sub.5                                                                     2 iso-C.sub.3 H.sub.7                                                                  H H  CO.sub.2 CH.sub.3                                      Cl H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H                                                                                  ##STR432##                                            Cl H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  COCH.sub.3                                             Cl H  C.sub.2 H.sub.5                                                                     2 n-C.sub.3 H.sub.7                                                                    H H  CO.sub.2 CH.sub.3                                      Cl H  CH.sub.2 CF.sub.3                                                                   0 C.sub.2 H.sub.5                                                                      H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.2 CF.sub.3                                                                   0 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.2 CF.sub.3                                                                   0 C.sub.2 H.sub.5                                                                      H H  CH.sub.3                                               Cl H  CH.sub.2 CF.sub.3                                                                   0 C.sub.2 H.sub.5                                                                      H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.2 CF.sub.3                                                                   0 CH.sub.3                                                                             H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.2 CF.sub.3                                                                   0 CH.sub.3                                                                             H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.2 CF.sub.3                                                                   0 CH.sub.3                                                                             H H  CH.sub.3                                               Cl H  CH.sub.2 CF.sub.3                                                                   0 CH.sub.3                                                                             H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.2 CF.sub.3                                                                   1 C.sub.2 H.sub.5                                                                      H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.2 CF.sub.3                                                                   1 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.2 CF.sub.3                                                                   1 C.sub.2 H.sub.5                                                                      H H  CH.sub.3                                               Cl H  CH.sub.2 CF.sub.3                                                                   1 C.sub.2 H.sub.5                                                                      H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.2 CF.sub.3                                                                   1 CH.sub.3                                                                             H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.2 CF.sub.3                                                                   1 CH.sub.3                                                                             H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.2 CF.sub.3                                                                   1 CH.sub.3                                                                             H H  CH.sub.3                                               Cl H  CH.sub.2 CF.sub.3                                                                   1 CH.sub.3                                                                             H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.2 CF.sub.3                                                                   2 C.sub.2 H.sub.5                                                                      H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.2 CF.sub.3                                                                   2 C.sub.2 H.sub.5                                                                      H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.2 CF.sub.3                                                                   2 C.sub.2 H.sub.5                                                                      H H  CH.sub.3                                               Cl H  CH.sub.2 CF.sub.3                                                                   2 C.sub.2 H.sub.5                                                                      H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.2 CF.sub.3                                                                   2 CH.sub.3                                                                             H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.2 CF.sub.3                                                                   2 CH.sub.3                                                                             H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.2 CF.sub.3                                                                   2 CH.sub.3                                                                             H H  CH.sub.3                                               Cl H  CH.sub.2 CF.sub.3                                                                   2 CH.sub.3                                                                             H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H                                                                                  ##STR433##                                            Cl H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  COCH.sub.3                                             Cl H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  CO.sub.2 C.sub.2 H.sub.5                               Cl H  CH.sub.3                                                                            0 C.sub.2 H.sub.5                                                                      H H  CO.sub.2 CH.sub.3                                      Cl H  CH.sub.3                                                                            0 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            0 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            0 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            0 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            0 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            0 CH.sub.2 OCH.sub.3                                                                   H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            0 CH.sub.2 OCH.sub.3                                                                   H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            0 CH.sub.2 CCH.sub.3                                                                   H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            0 CH.sub.2 OCH.sub.3                                                                   H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            0 CH.sub.2 OCH.sub.3                                                                   H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            0 CH.sub.2 SCH.sub.3                                                                   H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            0 CH.sub.2 SCH.sub.3                                                                   H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            0 CH.sub.2 SCH.sub.3                                                                   H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            0 CH.sub.2 SCH.sub.3                                                                   H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            0 CH.sub.2 SCH.sub.3                                                                   H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H                                                                                  ##STR434##                                            Cl H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  COCH.sub.3                                             Cl H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  CO.sub.2 C.sub.2 H.sub.5                               Cl H  CH.sub.3                                                                            0 CH.sub.3                                                                             H H  CO.sub.2 CH.sub.3                                      Cl H  CH.sub.3                                                                            0 COC.sub.2 H.sub.5                                                                    H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            0 COC.sub.2 H.sub.5                                                                    H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            0 COC.sub.2 H.sub.5                                                                    H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            0 COC.sub.2 H.sub.5                                                                    H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            0 COC.sub.2 H.sub.5                                                                    H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            0 COC.sub.3 H.sub.7 -n                                                                 H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            0 COC.sub.3 H.sub.7 -n                                                                 H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            0 COC.sub.3 H.sub.7 -n                                                                 H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            0 COC.sub.3 H.sub.7 -n                                                                 H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            0 COC.sub.3 H.sub.7 -n                                                                 H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            0 CCC.sub.3 H.sub.7 -n                                                                 H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            0 COC.sub.6 H.sub.5                                                                    H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            0 COCH.sub.3                                                                           H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            0 COCH.sub.3                                                                           H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            0 COCH.sub.3                                                                           H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            0 COCH.sub.3                                                                           H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            0 COCH.sub.3                                                                           H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            0 H     H H  (CH.sub.2).sub.5 Br                                    Cl H  CH.sub.3                                                                            0 H     H H  CH.sub.2 CH.sub.2 CO.sub.2 H                           Cl H  CH.sub.3                                                                            0 H     H H  CH.sub.2 CH.sub.2 SCH.sub.3                            Cl H  CH.sub.3                                                                            0 H     H H  CH.sub.2 CO.sub.2 CH.sub.3                             Cl H  CH.sub.3                                                                            0 H     H H  CO.sub.2 C.sub.2 H.sub.5                               Cl H  CH.sub.3                                                                            0 H     H H  CO.sub.2 CH.sub.3                                      Cl H  CH.sub.3                                                                            0 H     H H  COCH.sub.3                                             Cl H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H                                                                                  ##STR435##                                            Cl H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H  COCH.sub.3                                             Cl H  CH.sub.3                                                                            0 iso-C.sub.3 H.sub.7                                                                  H H  CO.sub.2 CH.sub.3                                      Cl H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H                                                                                  ##STR436##                                            Cl H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H  COCH.sub.3                                             Cl H  CH.sub.3                                                                            0 n-C.sub.3 H.sub.7                                                                    H H  CO.sub.2 CH.sub.3                                      Cl H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H                                                                                  ##STR437##                                            Cl H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  COCH.sub.3                                             Cl H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  CO.sub.2 C.sub.2 H.sub.5                               Cl H  CH.sub.3                                                                            1 C.sub.2 H.sub.5                                                                      H H  CO.sub.2 CH.sub.3                                      Cl H  CH.sub.3                                                                            1 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            1 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            1 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            1 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            1 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            1 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            1 CH.sub.2 CH.sub.3                                                                    H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            1 CH.sub.2 CH.sub.3                                                                    H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            1 CH.sub.2 OCH.sub.3                                                                   H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            1 CH.sub.2 OCH.sub.3                                                                   H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            1 CH.sub.2 OCH.sub.3                                                                   H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            1 CH.sub.2 OCH.sub.3                                                                   H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            1 CH.sub.2 SCH.sub.3                                                                   H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            1 CH.sub.2 SCH.sub.3                                                                   H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            1 CH.sub.2 SCH.sub.3                                                                   H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            1 CH.sub.2 SCH.sub.3                                                                   H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            1 CH.sub.2 SCH.sub.3                                                                   H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            1 CH.sub.2 SCH.sub.3                                                                   H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H                                                                                  ##STR438##                                            Cl H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  COCH.sub.3                                             Cl H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  CO.sub.2 C.sub.2 H.sub.5                               Cl H  CH.sub.3                                                                            1 CH.sub.3                                                                             H H  CO.sub.2 CH.sub.3                                      Cl H  CH.sub.3                                                                            1 COC.sub.2 H.sub.5                                                                    H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            1 COC.sub.2 H.sub.5                                                                    H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            1 COC.sub.2 H.sub.5                                                                    H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            1 COC.sub.2 H.sub.5                                                                    H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            1 COC.sub.2 H.sub.5                                                                    H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            1 COC.sub.2 H.sub.5                                                                    H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            1 COC.sub.3 H.sub.7 -n                                                                 H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            1 COC.sub.3 H.sub.7 -n                                                                 H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            1 COC.sub.3 H.sub.7 -n                                                                 H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            1 COC.sub.3 H.sub.7 -n                                                                 H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            1 COC.sub.3 H.sub.7 -n                                                                 H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            1 COC.sub.3 H.sub.7 -n                                                                 H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            1 COCH.sub.3                                                                           H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            1 COCH.sub.3                                                                           H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            1 COCH.sub.3                                                                           H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            1 COCH.sub.3                                                                           H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            1 COCH.sub.3                                                                           H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            1 COCH.sub.3                                                                           H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            1 H     H H  (CH.sub.2).sub.5 Br                                    Cl H  CH.sub.3                                                                            1 H     H H  CH.sub.2 CH.sub.2 CO.sub.2 H                           Cl H  CH.sub.3                                                                            1 H     H H  CH.sub.2 CH.sub.2 SCH.sub.3                            Cl H  CH.sub.3                                                                            1 H     H H  CH.sub.2 CO.sub.2 CH.sub.3                             Cl H  CH.sub.3                                                                            1 H     H H  CO.sub.2 C.sub.2 H.sub.5                               Cl H  CH.sub.3                                                                            1 H     H H  CO.sub.2 CH.sub.3                                      Cl H  CH.sub.3                                                                            1 H     H H  COCH.sub.3                                             Cl H  CH.sub.3                                                                            1 H     H H                                                                                  ##STR439##                                            Cl H  CH.sub.3                                                                            1 H     H H                                                                                  ##STR440##                                            Cl H  CH.sub.3                                                                            1 H     H H  sec-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H                                                                                  ##STR441##                                            Cl H  CH.sub.3                                                                            1 iso-C.sub.2 H                                                                        H H  COCH.sub.3                                             Cl H  CH.sub.3                                                                            1 iso-C.sub.3 H.sub.7                                                                  H H  CO.sub.2 CH.sub.3                                      Cl H  CH.sub.3                                                                            1 n-C.sub.2 H                                                                          H H                                                                                  ##STR442##                                            Cl H  CH.sub.3                                                                            1 n-C.sub.3 H                                                                          H H  COCH.sub.3                                             Cl H  CH.sub.3                                                                            1 n-C.sub.3 H                                                                          H H  CO.sub.2 CH.sub.3                                      Cl H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H                                                                                  ##STR443##                                            Cl H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  COCH.sub.3                                             Cl H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  CO.sub.2 C.sub.2 H.sub.5                               Cl H  CH.sub.3                                                                            2 C.sub.2 H.sub.5                                                                      H H  CO.sub.2 CH.sub.3                                      Cl H  CH.sub.3                                                                            2 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            2 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            2 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            2 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            2 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            2 CH.sub.2 OC.sub.2 H.sub.5                                                            H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            2 CH.sub.2 OCH.sub.3                                                                   H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            2 CH.sub.2 OCH.sub.3                                                                   H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            2 CH.sub.2 OCH.sub.3                                                                   H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            2 CH.sub.2 OCH.sub.3                                                                   H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            2 CH.sub.2 OCH.sub.3                                                                   H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            2 CH.sub.2 OCH.sub.3                                                                   H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            2 CH.sub.2 SCH.sub.3                                                                   H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            2 CH.sub.2 SCH.sub.3                                                                   H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            2 CH.sub.2 SCH.sub.3                                                                   H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            2 CH.sub.2 SCH.sub.3                                                                   H H  n-C.sub.3 H                                            Cl H  CH.sub.3                                                                            2 CH.sub.2 SCH.sub.3                                                                   H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            2 CH.sub.2 SCH.sub.3                                                                   H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H                                                                                  ##STR444##                                            Cl H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  COCH.sub.3                                             Cl H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  CO.sub.2 C.sub.2 H.sub.5                               Cl H  CH.sub.3                                                                            2 CH.sub.3                                                                             H H  CO.sub.2 CH.sub.3                                      Cl H  CH.sub.3                                                                            2 COC.sub.2 H.sub.5                                                                    H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            2 COC.sub.2 H.sub.5                                                                    H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            2 COC.sub.2 H.sub.5                                                                    H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            2 COC.sub.2 H.sub.5                                                                    H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            2 COC.sub.2 H.sub.5                                                                    H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            2 COC.sub.2 H.sub.5                                                                    H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            2 COC.sub.3 H.sub.7 -n                                                                 H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            2 COC.sub.3 H.sub.7 -n                                                                 H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            2 COC.sub.3 H.sub.7 -n                                                                 H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            2 COC.sub.3 H.sub.7 -n                                                                 H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            2 COC.sub.3 H.sub.7 -n                                                                 H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            2 COC.sub.3 H.sub.7 -n                                                                 H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            2 COCH.sub.3                                                                           H H  C.sub.2 H.sub.5                                        Cl H  CH.sub.3                                                                            2 COCH.sub.3                                                                           H H  CH.sub.2 OCH.sub.3                                     Cl H  CH.sub.3                                                                            2 COCH.sub.3                                                                           H H  CH.sub.3                                               Cl H  CH.sub.3                                                                            2 COCH.sub.3                                                                           H H  n-C.sub.3 H.sub.7                                      Cl H  CH.sub.3                                                                            2 COCH.sub.3                                                                           H H  n-C.sub.4 H.sub.9                                      Cl H  CH.sub.3                                                                            2 COCH.sub.3                                                                           H H  tert-C.sub.4 H.sub.9                                   Cl H  CH.sub.3                                                                            2 H     H H  (CH.sub.2).sub.5 Br                                    Cl H  CH.sub.3                                                                            2 H     H H  CH.sub.2 CH.sub.2 CO.sub.2 H                           Cl H  CH.sub.3                                                                            2 H     H H  CH.sub.2 CH.sub.2 SCH.sub.3                            Cl H  CH.sub.3                                                                            2 H     H H  CH.sub.2 CO.sub.2 CH.sub.3                             Cl H  CH.sub.3                                                                            2 H     H H  CO.sub.2 C.sub.2 H.sub.5                               Cl H  CH.sub.3                                                                            2 H     H H  CO.sub.2 CH.sub.3                                      Cl H  CH.sub.3                                                                            2 H     H H  COCH.sub.3                                             Cl H  CH.sub.3                                                                            2 H     H H                                                                                  ##STR445##                                            Cl H  CH.sub.3                                                                            2 H     H H                                                                                  ##STR446##                                            Cl H  CH.sub.3                                                                            2 H     H H  sec-C.sub.4 H.sub.9                                    Cl H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H                                                                                  ##STR447##                                            Cl H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H  COCH.sub.3                                             Cl H  CH.sub.3                                                                            2 iso-C.sub.3 H.sub.7                                                                  H H  CO.sub.2 CH.sub.3                                      Cl H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H                                                                                  ##STR448##                                            Cl H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  COCH.sub.3                                             Cl H  CH.sub.3                                                                            2 n-C.sub.3 H.sub.7                                                                    H H  CO.sub.2 CH.sub.3                                      __________________________________________________________________________

                                      TABLE 3                                      __________________________________________________________________________      ##STR449##                                                                    R.sup.1                                                                           R.sup.2                                                                           R.sup.3                                                                             n  R.sup.4        R.sup.5                                                                           R.sup.6                                                                          R.sup.7                                      __________________________________________________________________________     Br H  C.sub.2 H.sub.5                                                                     0  H              H  H H                                            Br H  C.sub.2 H.sub.5                                                                     0  tert-C.sub.4 H.sub.9                                                                          H  H H                                            Br H  C.sub.2 H.sub.5                                                                     2  H              H  H H                                            Br H  C.sub.2 H.sub.5                                                                     1  H              H  H H                                            Br H  CH.sub.3                                                                            0  H              H  H H                                            Br H  CH.sub.3                                                                            0  tert-C.sub.4 H.sub.9                                                                          H  H H                                            Br H  CH.sub.3                                                                            2  H              H  H H                                            Br H  CH.sub.3                                                                            2  CH.sub.3       CH.sub.3                                                                          H H                                            Br H  CH.sub.3                                                                            2  CH.sub.3       H  H H                                            Br H  CH.sub.3                                                                            2  C.sub.6 H.sub.5                                                                               H  H H                                            Br H  CH.sub.3                                                                            2                                                                                  ##STR450##    H  H H                                            Br H  CH.sub.3                                                                            1  H              H  H H                                            Cl H  C.sub.2 H.sub.5                                                                     0  H              H  H H                                            Cl H  C.sub.2 H.sub.5                                                                     0  tert-C.sub.4 H.sub.9                                                                          H  H H                                            Cl H  C.sub.2 H.sub.5                                                                     2  H              H  H H                                            Cl H  C.sub.2 H.sub.5                                                                     2  CH.sub.3       CH.sub.3                                                                          H H                                            Cl H  C.sub.2 H.sub.5                                                                     2  CH.sub.3       H  H H                                            Cl H  C.sub.2 H.sub.5                                                                     2  C.sub.6 H.sub.5                                                                               H  H H                                            Cl H  C.sub.2 H.sub.5                                                                     2                                                                                  ##STR451##    H  H H                                            Cl H  C.sub.2 H.sub.5                                                                     2                                                                                  ##STR452##    H  H H                                            Cl H  C.sub.2 H.sub.5                                                                     1  H              H  H H                                            Cl H  CH.sub.3                                                                            0  H              H  H H                                            Cl H  CH.sub.3                                                                            0  tert-C.sub.4 H.sub.9                                                                          H  H H                                            Cl H  CH.sub.3                                                                            2  H              H  H H                                            Cl H  CH.sub.3                                                                            2  CH.sub.3       H  H H                                            Cl H  CH.sub.3                                                                            2  iso-C.sub.3 H.sub.7                                                                           H  H H                                            Cl H  CH.sub.3                                                                            2  CH.sub.2 CH═CH.sub.2                                                                      H  H H                                            Cl H  CH.sub.3                                                                            2  CH.sub.3       CH.sub.3                                                                          H H                                            Cl H  CH.sub.3                                                                            2  n-C.sub.4 H.sub.9                                                                             H  H H                                            Cl H  CH.sub.3                                                                            2  CH.sub.2 C.sub.6 H.sub.5                                                                      H  H H                                            Cl H  CH.sub.3                                                                            2  CH.sub.3       C.sub.6 H.sub.5                                                                   H H                                            Cl H  CH.sub.3                                                                            2  C.sub.6 H.sub.5                                                                               H  H H                                            Cl H  CH.sub.3                                                                            2                                                                                  ##STR453##    H  H H                                            Cl H  CH.sub.3                                                                            2                                                                                  ##STR454##    H  H H                                            Cl H  CH.sub.3                                                                            2                                                                                  ##STR455##    H  H H                                            Cl H  CH.sub.3                                                                            2                                                                                  ##STR456##    H  H H                                            Cl H  CH.sub.3                                                                            2                                                                                  ##STR457##    H  H H                                            Cl H  CH.sub.3                                                                            2                                                                                  ##STR458##    H  H H                                            Cl H  CH.sub.3                                                                            2                                                                                  ##STR459##    H  H H                                            Cl H  CH.sub.3                                                                            2                                                                                  ##STR460##    H  H H                                            Cl H  CH.sub.3                                                                            2                                                                                  ##STR461##    H  H H                                            Cl H  CH.sub.3                                                                            2                                                                                  ##STR462##    H  H H                                            Cl H  CH.sub.3                                                                            2                                                                                  ##STR463##    H  H H                                            Cl H  CH.sub.3                                                                            1  H              H  H H                                            Cl H  CHF.sub.2                                                                           0  H              H  H H                                            Cl H  CHF.sub.2                                                                           1  H              H  H H                                            Cl H  CF.sub.3                                                                            0  H              H  H H                                            Cl H  CH.sub.2 CF.sub.3                                                                   0  H              H  H H                                            Cl H  CH.sub.2 CH.sub.2 F                                                                 0  H              H  H H                                            Cl H  CH.sub.2 CHF.sub.2                                                                  0  H              H  H H                                            __________________________________________________________________________

                                      TABLE 4                                      __________________________________________________________________________      ##STR464##                                                                    R.sup.1                                                                          R.sup.2                                                                           R.sup.3                                                                             n R.sup.5                                                                           R.sup.6                                                                          R.sup.7                                                                          Z R.sup.10                                                                          R.sup.11                                               __________________________________________________________________________     Br                                                                               H  CH.sub.3                                                                            0 H  H H O H  C.sub.6 H.sub.5                                        Br                                                                               H  CH.sub.3                                                                            0 H  H H O H  H                                                      Br                                                                               H  CH.sub.3                                                                            0 H  H H S H  H                                                      Br                                                                               H  CH.sub.3                                                                            1 H  H H O H  H                                                      Cl                                                                               H  CH.sub.2 CF.sub.3                                                                   0 H  H H O H  H                                                      Cl                                                                               H  CH.sub.2 CF.sub.3                                                                   0 H  H H S H  H                                                      Cl                                                                               H  CH.sub.2 CH.sub.2 F                                                                 0 H  H H O H  H                                                      Cl                                                                               H  CH.sub.2 CH.sub.2 F                                                                 0 H  H H S H  H                                                      Cl                                                                               H  CH.sub.2 CHF.sub.2                                                                  0 H  H H O H  H                                                      Cl                                                                               H  CH.sub.2 CHF.sub.2                                                                  0 H  H H S H  H                                                      Cl                                                                               H  CH.sub.3                                                                            0 H  H H S CH.sub.3                                                                          CH.sub.3                                               Cl                                                                               H  CH.sub.3                                                                            0 H  H H O H  C.sub.2 H.sub.5                                        Cl                                                                               H  CH.sub.3                                                                            0 H  H H O H                                                                                  ##STR465##                                            Cl                                                                               H  CH.sub.3                                                                            0 H  H H O H                                                                                  ##STR466##                                            Cl                                                                               H  CH.sub.3                                                                            0 H  H H O H  C.sub.6 H.sub.5                                        Cl                                                                               H  CH.sub.3                                                                            0 H  H H S H  C.sub.6 H.sub.5                                        Cl                                                                               H  CH.sub.3                                                                            0 H  H H O H  CH.sub.2 CH.sub.2 Cl                                   Cl                                                                               H  CH.sub.3                                                                            0 H  H H O H  CH.sub.3                                               Cl                                                                               H  CH.sub.3                                                                            0 H  H H S H  CH.sub.3                                               Cl                                                                               H  CH.sub.3                                                                            0 H  H H O H  H                                                      Cl                                                                               H  CH.sub.3                                                                            0 H  H H S H  H                                                      Cl                                                                               H  CH.sub.3                                                                            2 H  H H O H  C.sub.2 H.sub.5                                        Cl                                                                               H  CH.sub.3                                                                            2 H  H H S H  H                                                      Cl                                                                               H  CH.sub.3                                                                            1 H  H H S H  H                                                      Cl                                                                               H  CH.sub.3                                                                            0 H  H H O H                                                                                  ##STR467##                                            Cl                                                                               H  CH.sub.3                                                                            0 H  H H O H                                                                                  ##STR468##                                            Cl                                                                               H  CH.sub.3                                                                            0 H  H H S H                                                                                  ##STR469##                                            __________________________________________________________________________

In process (a), if, for example, 4-chloro-4'-methylmercaptomethylbenzophenone and ethyl carbazate are used as the starting materials, the reaction is illustrated by the following equation: ##STR470##

In process (b), if, for example, 4-chloro-4'-methylmercaptomethylbenzophenone hydrazone and 4-trifluoro-methoxyphenyl isocyanate are used as the starting materials, the reaction is illustrated by the following equation: ##STR471##

In process (c), if, for example, 4-chloro-4'-methylmercaptomethylbenzophenone 10 hydrazone and isobutyl chiorocarbonate are used as the starting materials, the reaction is illustrated by the following equation: ##STR472##

In process (d), if, for example, 4-chloro-4'-methylmercaptomethylbenzophenone ethoxycarbonylhydrazone ane methyliodide are used as the starting materials, the reaction is illustrared by the following equation: ##STR473##

In the process (e), if, for example, 4-chloro-4'-methylmercaptomethylbenzophenone ethoxycarbonylhydrazone is oxidized by sodium periodate, the reaction is illustrated by the following equation: ##STR474##

In process (f), if, for example, 4-chloro-4'-methylmercaptomethylbenzophenone ethoxycarbonylhydrazone is oxidized by m-chloroperbenzoic acid, the reaction is illustrated by the following equation: ##STR475##

In process (a), the compounds of the formula (II) mean compounds based on the above definitions of R¹, R², R³, R⁶, R⁷ and n, preferably compounds based on the above preferred definitions.

The starting compounds of the formula (II) are novel, and can be obtained by the following processes:

(g) in the case where n is 0:

compounds of the formula (XI) ##STR476## wherein R¹, R², R⁶, R⁷ and hal have the same meaning mentioned above,

are reacted with compounds of the formula (XII) or salts thereof

    R.sup.3 --SH                                               (XII)

wherein R³ has the same meaning mentioned above,

in the presence of inert solvent, and if appropriate, in the presence of an acid binder, or

(h) in the case where n is 0:

compounds of the formula (XIII) or salts thereof ##STR477## wherein R¹, R², R⁶ and R⁷ have the same meaning mentioned above,

are reacted with compounds of the formula (XIV)

    R.sup.15 --R.sup.3                                         (XIV)

wherein R³ has the same meanings mentioned above, and R¹⁵ is chlorine, bromine or iodine;

in the presence of an inert solvent, and if appropriate, in the presence of an acid binder, or

(j) in the case where n is 0 and R¹ is fluorine or chlorine:

compounds of the formula (XV) ##STR478## wherein R², R³ and R⁷ have the same meaning mentioned above,

are reacted with compounds of the formula (XVI) ##STR479## wherein R⁶ has the same meaning mentioned above and R¹⁶ is fluorine or chlorine, and

R¹⁷ is lithium, magnesium bromide or magnesium iodide,

in the presence of an inert solvent, and if appropriate, in the presence of an acid binder, or

(k) in the case where n is 0:

compounds of the formula (XVII ##STR480## wherein R², R³, R⁷ and R¹⁶ have the same meanings as mentioned above,

are reacted with compounds of the formula (XVIII) ##STR481## wherein R¹ and R⁶ have the same meanings as mentioned above, in the presence of an inert solvent, or

(m) in the case where n is 0, R² is hydrogen and R³ is perfluoroalkyl, then R³ is replaced by R¹⁸ :

compounds of the formula (XIX) ##STR482## wherein R¹, R⁶ and R⁷ have same meaning as mentioned above, are reacted with compounds of the formula (XX)

    R.sup.18 --I                                               (XX)

wherein R¹⁸ is C₁₋₄ perfluoroalkyl,

in the presence of an inert solvent, an if appropriate, in the presence of an acid binder, or

(n) in the case where n is 0 and R² is C₁₋₄ alkyl, then R² is replaced by R¹⁹ :

compounds of the formula (XXI) ##STR483## wherein R¹, R³, R⁶ and R⁷ have same meaning as mentioned above,

are reacted with compounds of the formula

    hal --R.sup.19                                             (XXII)

wherein hal has the same meaning as mentioned above and R¹⁹ is C₁₋₄ alkyl,

in the presence of an inert solvent, and if appropriate in the presence of an acid binder, or

(p) in the case where n is 1:

compounds of the formula (XXIII) ##STR484## wherein R¹, R², R³, R⁶ and R⁷ have the same meaning mentioned above,

are oxidized, if appropriate, in the presence of an inert solvent, or

(q) in the case where n is 2:

compounds of the formula (XXIV) ##STR485## wherein R¹, R², R³, R⁶, R⁷ and q have the same meaning mentioned above,

are oxidized, if appropriate, in the presence of an inert solvent.

Examples of the compounds of the formula (II) are shown in Table 5.

                                      TABLE 5                                      __________________________________________________________________________      ##STR486##                                                                    R.sup.1                                                                          R.sup.6                                                                           R.sup.7                                                                            A          R.sup.1                                                                          R.sup.6                                                                           R.sup.7                                                                            A                                                 __________________________________________________________________________     Br                                                                               H  H   CH(CH.sub.3)SCH.sub.3                                                                     Cl                                                                               H  H   CH.sub.2 S(CH.sub.2).sub.3 F                      Br                                                                               H  H   CH(CH.sub.3)SO.sub.2 CH.sub.3                                                             Cl                                                                               H  H   CH.sub.2 SC.sub.2 H.sub.5                         Br                                                                               H  H   CH(CH.sub.3)SOCH.sub.3                                                                    Cl                                                                               H  H   CH.sub.2 SC.sub.3 H.sub.7 -iso                    Br                                                                               H  H   CH.sub.2 SC.sub.2 H.sub.5                                                                 Cl                                                                               H  H   CH.sub.2 SC.sub.3 H.sub.7 -n                      Br                                                                               H  H   CH.sub.2 SC.sub.3 H.sub.7 -n                                                              Cl                                                                               H  H   CH.sub.2 SC.sub.4 H.sub.9 -n                      Br                                                                               H  H   CH.sub.2 SCF.sub.3                                                                        Cl                                                                               H  H   CH.sub.2 SC.sub.4 H.sub.9 -sec                    Br                                                                               H  H   CH.sub.2 SCH.sub.2 CF.sub.3                                                               Cl                                                                               H  H   CH.sub.2 SCF.sub.2 CF.sub.2 CF.sub.3              Br                                                                               H  H   CH.sub.2 SCH.sub.2 CH═CH.sub.2                                                        Cl                                                                               H  H   CH.sub.2 SCF.sub.2 CF.sub.3                       Br                                                                               H  H   CH.sub.2 SCH.sub.2 CH.sub.2 F                                                             Cl                                                                               H  H   CH.sub.2 SCF.sub.2 CHF.sub.2                      Br                                                                               H  H   CH.sub.2 SCH.sub.2 CHF.sub.2                                                              Cl                                                                               H  H   CH.sub.2 SCF.sub.3                                Br                                                                               H  H   CH.sub.2 SCH.sub.2 F                                                                      Cl                                                                               H  H   CH.sub.2 SCH.sub.2 C.tbd.CH                       Br                                                                               H  H   CH.sub.2 SCH.sub.3                                                                        Cl                                                                               H  H   CH.sub.2 SCH.sub.2 CF.sub.2 CF.sub.2 H            Br                                                                               H  H   CH.sub.2 SCHF.sub.2                                                                       Cl                                                                               H  H   CH.sub.2 SCH.sub.2 CF.sub.2 CF.sub.3              Br                                                                               H  H   CH.sub.2 SO.sub.2 C.sub.2 H.sub.5                                                         Cl                                                                               H  H   CH.sub.2 SCH.sub.2 CF.sub.3                       Br                                                                               H  H   CH.sub.2 SO.sub.2 C.sub.3 H.sub.7 -n                                                      Cl                                                                               H  H   CH.sub.2 SCH═CH.sub.2                         Br                                                                               H  H   CH.sub.2 SO.sub.2 CH.sub.2 CF.sub.3                                                       Cl                                                                               H  H   CH.sub.2 SCH.sub.2 CH═CH.sub.2                Br                                                                               H  H   CH.sub.2 SO.sub.2 CH.sub.2 CH═CH.sub.2                                                Cl                                                                               H  H   CH.sub.2 SCH.sub.2 CH.sub.2 CH.sub.2 Cl           Br                                                                               H  H   CH.sub.2 SO.sub.2 CH.sub.2 CH.sub.2 F                                                     Cl                                                                               H  H   CH.sub.2 SCH.sub.2 CH.sub.2 Cl                    Br                                                                               H  H   CH.sub.2 SO.sub.2 CH.sub.2 CHF.sub.2                                                      Cl                                                                               H  H   CH.sub.2 SCH.sub.2 CH.sub.2 F                     Br                                                                               H  H   CH.sub.2 SO.sub.2 CH.sub.3                                                                Cl                                                                               H  H   CH.sub.2 SCH.sub.2 CHF.sub.2                      Br                                                                               H  H   CH.sub.2 SOC.sub.2 H.sub.5                                                                Cl                                                                               H  H   CH.sub.2 SCH.sub.2 CN                             Br                                                                               H  H   CH.sub.2 SOC3H.sub.7 -n                                                                   Cl                                                                               H  H   CH.sub.2 SCH.sub.2 F                              Br                                                                               H  H   CH.sub.2 SOCH.sub.2 CF.sub.3                                                              Cl                                                                               H  H   CH.sub.2 SCH.sub.2 Cl                             Br                                                                               H  H   CH.sub.2 SOCH.sub.2 CH═CH.sub.2                                                       Cl                                                                               H  H   CH.sub.2 SCH.sub.3                                Br                                                                               H  H   CH.sub.2 SOCH.sub.2 CH.sub.2 F                                                            Cl                                                                               H  2-Cl                                                                               CH.sub.2 SCH.sub.3                                Br                                                                               H  H   CH.sub.2 SOCH.sub.2 CHF.sub.2                                                             Cl                                                                               H  3-Cl                                                                               CH.sub.2 SCH.sub.3                                Br                                                                               H  H   CH.sub.2 SOCH.sub.2 F                                                                     Cl                                                                               H  2-F CH.sub.2 SCH.sub.3                                Br                                                                               H  H   CH.sub.2 SOCH.sub.3                                                                       Cl                                                                               H  3-F CH.sub.2 SCH.sub.3                                Br                                                                               H  H   CH.sub.2 SOCHF.sub.2                                                                      Cl                                                                               H  2-Br                                                                               CH.sub.2 SCH.sub.3                                Cl                                                                               H  H   CH(C.sub.2 H.sub.5)SCH.sub.3                                                              Cl                                                                               H  3-Br                                                                               CH.sub.2 SCH.sub.3                                Cl                                                                               H  H   CH(C.sub.2 H.sub.5)SO.sub.2 CH.sub.3                                                      Cl                                                                               H  3-CH.sub.3                                                                         CH.sub.2 SCH.sub.3                                Cl                                                                               H  H   CH(C.sub.2 H.sub.5)SOCH.sub.3                                                             Cl                                                                               H  2-CH.sub.3                                                                         CH.sub.2 SCH.sub.3                                Cl                                                                               H  H   CH(CH.sub.3)SCH.sub.3                                                                     Cl                                                                               H  H   CH.sub.2 SCHF.sub.2                               Cl                                                                               H  H   CH(CH.sub.3)SO.sub.2 CH.sub.3                                                             Cl                                                                               H  H   CH.sub.2 SO.sub.2 C.sub.2 H.sub.5                 Cl                                                                               H  H   CH(CH.sub.3)SOCH.sub.3                                                                    Cl                                                                               H  H   CH.sub.2 SO.sub.2 C.sub.3 H.sub.7 -n              Cl                                                                               H  H   CH(n-C.sub.3 H.sub.7)SCH.sub.3                                                            Cl                                                                               H  H   CH.sub.2 SO.sub.2 CH.sub.2 C.tbd.CH               Cl                                                                               H  H   CH.sub.2 SO.sub.2 CH.sub.2 CF.sub.3                                                       Cl                                                                               3-F                                                                               H   CH.sub.2 SCH.sub.3                                Cl                                                                               H  H   CH.sub.2 SO.sub.2 CH.sub.2 CH═CH.sub.2                                                Cl                                                                               2-Cl                                                                              H   CH.sub.2 SO.sub.2 C.sub.2 H.sub.5                 Cl                                                                               H  H   CH.sub.2 SO.sub.2 CH.sub.2 CH.sub.2 CH.sub.2 F                                            Cl                                                                               2-F                                                                               H   CH.sub.2 SO.sub.2 C.sub.2 H.sub.5                 Cl                                                                               H  H   CH.sub.2 SO.sub.2 CH.sub.2 CH.sub.2 CH.sub.2 Cl                                           Cl                                                                               3-F                                                                               H   CH.sub.2 SO.sub.2 C.sub.2 H.sub.5                 Cl                                                                               H  H   CH.sub.2 SO.sub.2 CH.sub.2 CH.sub.2 Cl                                                    Cl                                                                               2-Cl                                                                              H   CH.sub.2 SO.sub.2 CH.sub.3                        Cl                                                                               H  H   CH.sub.2 SO.sub.2 CH.sub.2 CH.sub.2 F                                                     Cl                                                                               2-F                                                                               H   CH.sub.2 SO.sub.2 CH.sub.3                        Cl                                                                               H  H   CH.sub.2 SO.sub.2 CH.sub.2 CHF.sub.2                                                      Cl                                                                               3-F                                                                               H   CH.sub.2 SO.sub.2 CH.sub.3                        Cl                                                                               H  H   CH.sub.2 SO.sub.2 CH.sub.3                                                                Cl                                                                               2-Cl                                                                              H   CH.sub.2 SOC.sub.2 H.sub.5                        Cl                                                                               H  2-Cl                                                                               CH.sub.2 SO.sub.2 CH.sub.3                                                                Cl                                                                               2-F                                                                               H   CH.sub.2 SOC.sub.2 H.sub.5                        Cl                                                                               H  3-Cl                                                                               CH.sub.2 SO.sub.2 CH.sub.3                                                                Cl                                                                               3-F                                                                               H   CH.sub.2 SOC.sub.2 H.sub.5                        Cl                                                                               H  2-F CH.sub.2 SO.sub.2 CH.sub.3                                                                Cl                                                                               2-Cl                                                                              H   CH.sub.2 SOCH.sub.3                               Cl                                                                               H  3-F CH.sub.2 SO.sub.2 CH.sub.3                                                                Cl                                                                               2-F                                                                               H   CH.sub.2 SOCH.sub.3                               Cl                                                                               H  2-Br                                                                               CH.sub.2 SO.sub.2 CH.sub.3                                                                Cl                                                                               3-F                                                                               H   CH.sub.2 SOCH.sub.3                               Cl                                                                               H  3-Br                                                                               CH.sub.2 SO.sub.2 CH.sub.3                                                                Cl                                                                               3-Cl                                                                              H   CH.sub.2 SC.sub.2 H.sub.5                         Cl                                                                               H  3-CH.sub.3                                                                         CH.sub.2 SO.sub.2 CH.sub.3                                                                Cl                                                                               3-Cl                                                                              H   CH.sub.2 SCH.sub.3                                Cl                                                                               H  2-CH.sub.3                                                                         CH.sub.2 SO.sub.2 CH.sub.3                                                                Cl                                                                               3-Cl                                                                              H   CH.sub.2 SO.sub.2 C.sub.2 H.sub.5                 Cl                                                                               H  H   CH.sub.2 SOC.sub.2 H.sub.5                                                                Cl                                                                               3-Cl                                                                              H   CH.sub.2 SO.sub.2 CH.sub.3                        Cl                                                                               H  H   CH.sub.2 SOC.sub.3 H.sub.7 -n                                                             Cl                                                                               3-Cl                                                                              H   CH.sub.2 SOC.sub.2 H.sub.5                        Cl                                                                               H  H   CH.sub.2 SOCH.sub.2 C.tbd.CH                                                              Cl                                                                               3-Cl                                                                              H   CH.sub.2 SOCH.sub.3                               Cl                                                                               H  H   CH.sub.2 SOCH.sub.2 CF.sub.3                                                              F H  H   CH.sub.2 SC.sub.2 H.sub.5                         Cl                                                                               H  H   CH.sub.2 SOCH.sub.2 CH═CH.sub.2                                                       F H  H   CH.sub.2 SCH.sub.3                                Cl                                                                               H  H   CH.sub.2 SOCH.sub.2 CH.sub.2 CH.sub.2 Cl                                                  F H  H   CH.sub.2 SO.sub.2 C.sub.2 H.sub.5                 Cl                                                                               H  H   CH.sub.2 SOCH.sub.2 CH.sub.2 Cl                                                           F H  H   CH.sub.2 SO.sub.2 CH.sub.3                        Cl                                                                               H  H   CH.sub.2 SOCH.sub.2 CH.sub.2 F                                                            F H  H   CH.sub.2 SOC.sub.2 H.sub.5                        Cl                                                                               H  H   CH.sub.2 SOCH.sub.2 CHF.sub.2                                                             F H  H   CH.sub.2 SOCH.sub.3                               Cl                                                                               H  H   CH.sub.2 SOCH.sub.2 F                                                                     F 3-F                                                                               H   CH.sub.2 SC.sub.2 H.sub.5                         Cl                                                                               H  H   CH.sub.2 SOCH.sub.3                                                                       F 3-F                                                                               H   CH.sub.2 SCH.sub.3                                Cl                                                                               H  2-Cl                                                                               CH.sub.2 SOCH.sub.3                                                                       F 3-F                                                                               H   CH.sub.2 SO.sub.2 C.sub.2 H.sub.5                 Cl                                                                               H  3-Cl                                                                               CH.sub.2 SOCH.sub.3                                                                       F 3-F                                                                               H   CH.sub.2 SO.sub.2 CH.sub.3                        Cl                                                                               H  2-F CH.sub.2 SOCH.sub.3                                                                       F 3-F                                                                               H   CH.sub.2 SOC.sub.2 H.sub.5                        Cl                                                                               H  3-F CH.sub.2 SOCH.sub.3                                                                       F 3-F                                                                               H   CH.sub.2 SOCH.sub.3                               Cl                                                                               H  2-Br                                                                               CH.sub.2 SOCH.sub.3                                                                       I H  H   CH.sub.2 SC.sub.2 H.sub.5                         Cl                                                                               H  3-Br                                                                               CH.sub.2 SOCH.sub.3                                                                       I H  H   CH.sub.2 SCF.sub.3                                Cl                                                                               H  3-CH.sub.3                                                                         CH.sub.2 SOCH.sub.3                                                                       I H  H   CH.sub.2 SCH.sub.2 CF.sub.3                       Cl                                                                               H  2-CH.sub.3                                                                         CH.sub.2 SOCH.sub.3                                                                       I H  H   CH.sub.2 SCH.sub.2 CH.sub.2 F                     Cl                                                                               H  H   CH.sub.2 SOCHF.sub.2                                                                      I H  H   CH.sub.2 SCH.sub.2 CHF.sub.2                      Cl                                                                               2-Cl                                                                              H   CH.sub.2 SC.sub.2 H.sub.5                                                                 I H  H   CH.sub.2 SCH.sub.3                                Cl                                                                               2-F                                                                               H   CH.sub.2 SC.sub.2 H.sub.5                                                                 I H  H   CH.sub.2 SCHF.sub.2                               Cl                                                                               3-F                                                                               H   CH.sub.2 SC.sub.2 H.sub.5                                                                 I H  H   CH.sub.2 SO.sub.2 C.sub.2 H.sub.5                 Cl                                                                               2-Cl                                                                              H   CH.sub.2 SCH.sub.3                                                                        I H  H   CH.sub.2 SO.sub.2 CH.sub.3                        Cl                                                                               2-F                                                                               H   CH.sub.2 SCH.sub.3                                                                        I H  H   CH.sub.2 SOC.sub.2 H.sub.5                        I H  H   CH.sub.2 SOCH.sub.3                                                   Cl                                                                               H  H   CH.sub.2 SOCH.sub.3                                                   Cl                                                                               H  H   CH.sub.2 SCN                                                          Cl                                                                               H  H   CH.sub.2 SCSOCH.sub.3                                                 Cl                                                                               H  H   CH.sub.2 CSOC.sub.2 H.sub.5                                           Cl                                                                               H  H   CH.sub.2 SCH.sub.2 Si(CH.sub.3).sub.3                                 Cl                                                                               H  H   CH.sub.2 SOCH.sub.2 Si(CH.sub.3).sub.3                                Cl                                                                               H  H   CH.sub.2 SO.sub.2 CH.sub.2 Si(CH.sub.3).sub.3                         Br                                                                               H  H   CH.sub.2 SCH.sub.2 Si(CH.sub.3).sub.3                                 Br                                                                               H  H   CH.sub.2 SOCH.sub.2 Si(CH.sub.3).sub.3                                Br                                                                               H  H   CH.sub.2 SO.sub.2 CH.sub.2 Si(CH.sub.3).sub.3                         __________________________________________________________________________

In the process (g), the starting materials of the formula (XI) are in part known, for example, 4-chloro-4'-chloromethylbenzophenone is described in Japanese Patent Kokoku Publication Sho 46-10164 together with production method thereof, or the staring materials of the formula (I) can be obtained by halogenating benzophenones of the formula (XXV) ##STR487## wherein, R¹, R², R⁶ and R⁷ have the same meanings as mentioned above, according to conventional methods, using, for example, N-bromosuccinimide or N-cheorosuccin imide as halogenating agent.

The compounds of the formula (XXV) can be obtained by a Friedel-Crafts reaction wherein substituted benzoyl halides and alkyl-substituted benzenes are used as starting materials, and aluminum chloride is used as a catalyst.

The compounds of the formula (XI) may be exemplified as follows:

4-chloro-4'-chloromethylbenzophenone,

4-chloromethyl-4'-fluorobenzophenone,

4-bromo-4'-chloromethylbenzophenone,

4-bromomethyl-4'-chlorobenzophenone,

4-bromomethyl-4'-fluorobenzophenone,

4-bromo-4'-bromomethylbenzophenone,

4-(1-bromoethyl)-4'-chlorobenzophenone,

4-(1-bromopropyl)-4'-chlorobenzophenone, and the like.

In the above process (g), the compounds of the formula (XII) are well known in the field of organic chemistry and, for example, there may be mentioned:

methylmercaptan and salts thereof,

ethylmercaptan and salts thereof, and the like.

In the above process (h), the compounds of the formula (XIII) are novel and such compounds can be synthesized by, for instance, reacting benzophenones of the above formula (XI) with thiourea. This reaction is well known per se in the field of organic chemistry and can be carried out by the method analogous to that described in "Jikken Kagaku Koza (Experimental Chemistry Course)" fourth edition, edited by Japanese Chemical Society, Vol. 25, page 336, 1992, published by Maruzen.

Examples of the compounds of the formula (XIII) are are shown in following Table 6.

                  TABLE 6                                                          ______________________________________                                          ##STR488##                                                                    R.sup.1                                                                               R.sup.6  R.sup.7  A                                                     ______________________________________                                         Br     H        H        CH.sub.2 SC(═NH)NH.sub.2.HBr                      Cl     H        H        CH(C.sub.2 H.sub.5)SC(═NH)NH.sub.2.HBr            Cl     H        H        CH(CH.sub.3)SC(═NH)NH.sub.2.HBr                   Cl     H        H        CH(n-C3H.sub.7)SC(═NH)NH.sub.2.HBr                Cl     H        H        CH.sub.2 SC(═NH)NH.sub.2.HBr                      Cl     H        2-CH.sub.3                                                                              CH.sub.2 SC(═NH)NH.sub.2.HBr                      Cl     H        3-CH.sub.3                                                                              CH.sub.2 SC(═NH)NH.sub.2.HBr                      Cl     H        2-F      CH.sub.2 SC(═NH)NH.sub.2.HBr                      Cl     H        3-F      CH.sub.2 SC(═NH)NH.sub.2.HBr                      Cl     H        2-Cl     CH.sub.2 SC(═NH)NH.sub.2.HBr                      Cl     H        3-Cl     CH.sub.2 SC(═NH)NH.sub.2.HBr                      Cl     H        2-Br     CH.sub.2 SC(═NH)NH.sub.2.HBr                      Cl     H        3-Br     CH.sub.2 SC(═NH)NH.sub.2.HBr                      Cl     2-Cl     H        CH.sub.2 SC(═NH)NH.sub.2.HBr                      Cl     2-F      H        CH.sub.2 SC(═NH)NH.sub.2.HBr                      Cl     3-F      H        CH.sub.2 SC(═NH)NH.sub.2.HBr                      Cl     3-Cl     H        CH.sub.2 SC(═NH)NH.sub.2.HBr                      F      H        H        CH.sub.2 SC(═NH)NH.sub.2.HBr                      F      3-F      H        CH.sub.2 SC(═NH)NH.sub.2.HBr                      I      H        H        CH.sub.2 SC(═NH)NH.sub.2.HBr                      ______________________________________                                    

In the process (h), the compounds of the formula (XIV) are known in the field of organic chemistry and, for example, there may be mentioned:

methyl iodide, ethyl iodide, methyl bromide, ethyl bromide, boromodifluoromethane, iodotrifluoromethane, 1-bromo-2-fluoroethane, 1-bromo-2-chloroethane, 2,2,2-trifluoro-1-iodoethane, 1-bromo-2,2-difluoroethane, and the like.

In the process (j), the compounds of the formula (XV) can be obtained when compounds of the formula (XXVI) ##STR489## wherein R² and R⁷ are defined as above, are reacted with the compound of the formula (XII),

in the presence of an acid binder, and, if appropriate, in the presence of an inert solvent, under the same reaction conditions as described for process (g).

The compounds of the formula (XXVI) are well known and include the following:

4-cyanobenzyl bromide, 4-cyanobenzyl chloride, and the like.

In the process (j), the compounds of the formula (XV) are well known and exemplified by the following compounds:

4-methylmercaptobenzonitril, and the like.

In the process (j), the compounds of the formula (XVI) are obtained by metalation of

compounds of the formula (XXVII) ##STR490## wherein R⁶ and R¹⁶ have same meaning as mentioned above, and R²⁰ is bromine or iodine,

with alkyllithium or magnesium,

in the presence of an inert solvent, and, if appropriate, in the presence of a catalyst.

The following compounds of the formula (XXVII) may be mentioned:

4-fluorobromobenzen, 4-fluoroiodobenzen, 4-chloroiodobenzen, 4-chlorobromobenzene, 2-fluoro-4-chlorobromobenzen, 3-fluoro-4-chlorobromobenzen, and the like.

In the process (k), the compounds of the formula (XVII) are obtained by metalation of compounds of the formula (XXVIII) ##STR491## wherein, R², R³, R⁷ and R²⁰ have same meaning mentined above,

with alkyllithium or magnesium,

in the presence of an inert solvent, and, if appropriate, in the presence of a catalyst.

The compounds of the formula (XXVIII) are well known and include the following:

4-methylthiomethylbromobenzene, 4-methylthiomethyliodobenzene, 4-ethylthiomethylbromobenzene, 4-ethylthiomethyliodobenzene, and the like.

In the process (m), the compounds of the formula (XIX) are well known compounds in the field of organic chemistry, and include the following:

4-(4-chlorobenzoyl)benzylthiocyanate, and the like.

In the process (m), the compounds of the formula (XX) are well known compounds in the field of organic chemistry, and include the following:

iodotrifluoromethane, iodopentafluoroethane, and the like.

The reaction in the process (m) can be conducted by a method analogous to that described in Journal of Fluorine Chemistry Vol.43, 27-24 (1989).

In the process (n), the compounds of the formula (XXI) are synthesized by the above processes (g) to (m) and include the following:

4-fluoro-4'-methylmercaptomethylbenzophenone,

4-chloro-4'-methylmercaptomethylbenzophenone,

4-bromo-4'-methylmercaptomethylbenzophenone,

4-iodo-4'-methylmercaptomethylbenzophenone,

4-fluoro-4'-ethylmercaptomethylbenzophenone,

4-chloro-4'-ethylmercaptomethylbenzophenone,

4-bromo-4'-ethylmercaptomethylbenzophenone, and the like.

In the process (n), the compounds of the formula (XXII) are known in the field of organic chemistry and include the following:

methyl iodide, ethyl iodide, methyl bromide, ethyl bromide, and the like.

The process (n) is well known per se in the field of organic chemistry and can be carried out by, for example, the method similar to that described in "Jikken Kagaku Koza (Experimental Chemistry Course)" fourth edition, edited by Japanese Chemical Society, Vol. 25, page 329, 1992, published by Maruzen.

In the process (n), the compounds of the formula (XXII) are synthesized by the above processes (g) to (n). As examples thereof, the following compounds in addition to those exemplified as the compounds of the above formula (XXI) may be mentioned:

4-bromo-4'-(1-methylmercaptoethyl)benzophenone,

4-chloro-4'-(1-methylmercaptoethyl)benzophenone,

4-chloro-4'-(1-methylmercaptopropyl)benzophenone,

4-chloro-4'-(1-methylmercaptobutyl)benzophenone, and the like.

As the oxidizing agents used in the above process (p), there may be mentioned, for example, aqueous hydrogen peroxide, peracetic acid, m-chloroperbenzoic acid, OXONE™, sodium periodate, t-butylhydroperoxide and N-bromosuccinimide.

The oxidation reaction in the above production methods (p) and (q) can be carried out by, for example, the method similar to that described in "Jikken Kagaku Koza (Experimental Chemistry Course)" fourth edition, edited by Japanese Chemical Society, Vol. 24, page 350 or 365, 1992, published by Maruzen.

In the above process (q), the compounds of the formula (XXIV) are synthesized by the above production methods (g) to (p). As examples thereof, the following compounds in addition to those exemplified as the compounds of the above formulae (XXI) and (XXIII) may be mentioned:

4-fluoro-4'-methylsulfinylmethylbenzophenone,

4-chloro-4'-methylsulfinylmethylbenzophenone,

4-chloro-4'-difluoromethylsulfinylmethylbenzophenone,

4-bromo-4'-methylsulfinylmethylbenzophenone,

4-iodo-4'-methylsulfinylmethylbenzophenone,

4-ethylsulfinylmethyl-4'-fluorobenzophenone,

4-chloro-4'-ethylsulfinylmethylbenzophenone,

4-bromo-4'-ethylsulfinylmethylbenzophenone,

4-bromo-4'-(1-methylsulfinylethyl)benzophenone,

4-chloro-4'-(1-methylsulfinylethyl)benzophenone,

4-chloro-4'-(1-methylsulfinylpropyl)benzophenone,

4-chloro-4'-(1-methylsulfinylbutyl)benzophenone, and the like.

As the oxidizing agents which can be used in the above production method (q), there may be mentioned, for example, potassium permanganate, sodium perborate in addition to the oxidizing agents described in connection with the above production method (p).

In the process (a), starting compounds of the formula (III) mean compounds based on the above definition of R⁴, preferably compounds based on the above preferred definition.

In the process (a), the compounds of the formula (III) are well known in the field of organic chemistry, and include the following:

hydrazine hydrate, methyl carbazate, ethyl carbazate, n-propyl carbazate, isopropyl carbazate, n-butyl carbazate, isobutyl carbazate, tert-butylhydrazine, acetohydrazide, benzohydrazide, semicarbazide, thiosemicarbazide, formic hydrazide, and the like.

In the processes (b) and (c), starting compounds of the formula (IV) mean compounds based on the above definition of R¹, R², R³, R⁶, R⁷ and n, preferably compounds based on the above preferred definitions.

The compounds of the formula (IV) are synthesized by the above processes (a), (d), (e) and (f). Specific examples of the compounds of the formula (IV) include the following compounds:

4-fluoro-4'-methylmercaptomethylbenzophenone hydrazone,

4-chloro-4'-methylmercaptomethylbenzophenone hydrazone,

4-chloro-4'-difluoromethylmercaptomethylbenzophenone hydrazone,

4-chloro-4'-trifluoromethylmercaptomethylbenzophenone hydrazone,

4-bromo-4'-methylmercaptomethylbenzophenone hydrazone,

4-ethylmercaptomethyl-4'-fluorobenzophenone hydrazone,

4-chloro-4'-methylsulfinylmethylbenzophenone hydrazone,

4-ethylsulfinylmethyl-4'-bromobenzophenone hydrazone,

4-bromo-4'-methylsulfonylmethylbenzophenone hydrazone,

4-chloro-4'-methylsulfonylmethylbenzophenone hydrazone, and the like.

In the process (b), the compounds of the formula (V), as the starting material, are well known in the field of organic chemistry. Examples thereof which may be mentioned are as follows:

4-trifluoromethoxyphenylisocyanate, phenylisocyanate, and the like.

In the process (c), the compounds of the formula (VI) as the starting material are well known in the field of organic chemistry. Examples thereof which may be mentioned are as follows:

methyl chlorocarbonate, ethyl chlorocarbonate, propyl chlorocarbonate, isopropyl chlorocarbonate, butyl chlorocarbonate, isobutyl chlorocarbonate, tert-butyl chlorocarbonate, methyl bromocarbonate, ethyl bromocarbonate, propyl bromocarbonate, isopropyl bromocarbonate, butyl bromocarbonate, isobutyl bromocarbonate, tert-butyl bromocarbonate, allyl bromocarbonate, acetyl chloride, acetyl bromide, propionyl chloride, butyryl chloride, isobutyryl chloride, valeryl chloride, isovaleryl chloride, pivaloyl chloride, and the like.

In the processes (d), the compounds of the formula (VII) are synthesized by the above processes (a), (b), (c) and (f). Examples thereof include the following compounds:

4-fluoro-4'-methylmercaptomethylbenzophenone hydrazone,

4-bromo-4'-methylmercaptomethylbenzophenone hydrazone,

4-iodo-4'-methylmercaptomethylbenzophenone hydrazone,

4-chloro-4'-ethylmercaptomethylbenzophenone hydrazone,

4-bromo-4'-methylmercaptomethylbenzophenone ethoxycarbonylhydrazone,

4-chloro-4'-methylmercaptomethylbenzophenone ethoxycarbonylhydrazone,

4-chloro-4'-ethylmercaptomethylbenzophenone ethoxycarbonylhydrazone,

4-chloro-4'-(1-methylmercaptoethyl)benzophenone ethoxycarbonylhydrazone, and the like.

In the process (d), the compounds of the formula (VIII) as the starting material are those which are well known in the field of organic chemistry. Examples thereof which may be mentioned are as follows:

methyl iodide, ethyl iodide, propyl iodide, chloromethyl methyl ether, chloromethyl ethyl ether, chloromethyl methyl sulfide, acetyl chloride, benzoyl chloride, cinnamoyl chloride, methylchloroformate, methyl chlorocarbonate, ethyl chlorocarbonate, propyl chlorocarbonate, isopropyl chlorocarbonate, butyl chlorocarbonate, isobutyl chlorocarbonate, tert-butyl chlorocarbonate, methyl bromocarbonate, ethyl bromocarbonate, propyl bromocarbonate, isopropyl bromocarbonate, butyl bromocarbonate, isobutyl bromocarbonate, tert-butyl bromocarbonate, allyl bromocarbonate, and the like.

In the process (e), the compounds of the formula (IX) are obtained by the processes (a) to (d). Examples thereof include the following compounds, in addition to those exemplified as the compounds of formulae (IV) and (VII).

As the oxidizing agents which are used in the above processes (e) and (f), there may be mentioned the oxidizing agents described in connection with the process (n).

In the process (f), the compounds of the formula (X) are the compounds according to the invention, which are synthesized by the above processes (a) to (e). As example thereof, the following compounds in addition to those exemplified as the compounds of the above formulae (IV) and (VII) may be mentioned:

4-fluoro-4'-methylsulfinylmethylbenzophenone hydrazone,

4-bromo-4'-methylsulfinylmethylbenzophenone hydrazone,

4-iodo-4'-methylsulfinylmethylbenzophenone hydrazone,

4-chloro-4'-ethylsulfinylmethylbenzophenone hydrazone,

4-chloro-4'-methylsulfinylmethylbenzophenone ethoxycarbonylhydrazone, and

4-bromo-4'-ethylsulfinylmethylbenzophenone ethoxycarbonylhydrazone.

As are mentioned hereinabove, the compounds of the formulae (II), (XIII), (XIX), (XXI), (XXIII), and (XXIV) which are employed as starting materials or intermediates in the preparation of the compounds of the formula (I) are novel, and then those compounds can be represented by the following formula (XXIX): ##STR492## wherein R¹ is halogen,

R² is hydrogen or C₁₋₄ alky,

R⁶ is hydrogen or halogen,

R⁷ is hydrogen, halogen or C₁₋₂ alkyl,

n is 0, 1 or 2,

X is cyano, optionally substituted C₁₋₄ alky, C₂₋₄ alkenyl, C₃₋₄ alkynyl, C₁₋₄ alkyl-carbonyl, C₁₋₄ alkoxy-thiocarbonyl or carboxamidine and their salts, provided that when X is cyano, C₁₋₄ alkyl-carbonyl C₁₋₄ alkoxy-thiocarbonyl or carboxamidine and their salts then n is 0.

The reaction of the above production method (a) can be carried out in an appropriate diluent. As such diluents, there may be mentioned optional inert organic solvents, for example, aliphatic, alicyclic or aromatic hydrocarbons (which may be optionally chlorinated), such as pentane, hexane, cyclohexane, petroleum ether, ligroin, benzene, toluene, xylene, dichloromethane, chloroform, carbon tetrachloride, 1,2-dichloroethane, chlorobenzene and dichlorobenzene; ethers such as ethyl ether, methyl ethyl ether, isopropyl ether, butyl ether, dioxane, dimethoxyethane (DME), tetrahydrofuran (THF) and diethylene glycol dimethyl ether (DGM); nitrites such as acetonitrile, propionitrile and acrylonitrile; alcohols, with the proviso that R³ is not monohalogenomethyl, such as methanol, ethanol, isopropanol, butanol and ethylene glycol; esters such as ethyl acetate and amyl acetate; acid amides such as dimethylformamide (DMF), dimethylacetamide (DMA), N-methylpyrrolidone, 1,3-dimethyl-2-imidazolidinone and hexamethylphosphoric triamide (HMPA); and sulfones and sulfoxides such as dimethyl sulfoxide (DMSO) and sulfolan.

The reaction in the above production method (a), can be carried out in the presence of an acid cataylst. Examples of usable acid catalysts may be mentioned: mineral acids such as hydrochloric acid, sulfuric acid, phosphoric acid, hydrobromic acid, organic acids such as formic acid, acetic acid, trifluoroacetic acid, and propionic acid, methanesulfonic acid, benzenesulfonyl acid and p-toluenesulfonic acid: and organic amine hydrochlorides auch as pyridine hydrochloride and triethylamine hydrochloride and the like.

The reaction of the production method (a) can be conducted at a temperature within a substantially broad range, but it is generally possible to employ a reaction temperature of about -20 to about 200° C., preferably about 20 to about 150° C. Further, the reaction should preferably be conducted under normal pressure but it may optionally be operated under an elevated or reduced pressure.

For carrying out the production method (a), for instance, 1 mole of the compound of the formula (II) can be reacted with 1 to 10 moles of the compound of the formula (III) in a diluent such as ethanol and in the presence of an acid catalyst such as acetic acid to thereby obtain the object compound of the formula (I).

In carrying out the process (b) mentioned above, use may be made, as suitable diluent, of any inert solvent.

Examples of such diluents are aliphatic, cycloaliphatic and aromatic, optionally chlorinated, hydrocarbons such as pentane, hexane, cyclohexane, petroleum ether, ligroin, benzene, toluene, xylene, dichloromethane, chloroform, carbon tetrachloride, 1,2-dichloroethane, chlorobenzene, dichlorobenzene and the like; ethers such as diethyl ether, methyl ethyl ether, diisopropyl ether, dibutyl ether, dioxane, dimethoxyethane(DME), tetrahydrofurane (THF), dimethylene glycol dimethyl ether and the like; ketones such as acetone, methylethyl ketone (MEK), methyl-isopropyl ketone, methyl-isobutyl ketone (MIBK) and the like; nitriles such as acetonitrile, propionitrile and the like; esters such as ethyl acetate, amyl acetate and the like, acid amides such as dimethyl formamide (DMF), dimethyl acetamide (DMA), N-methylpyrrolidone, 1,3-dimethyl-2-imidazolidinone, hexamethylphosphoric traimide (HWA) and the like; sulfones and sulfoxides such as dimethyl sulfoxide (DMSO), sulfolane and the like; and base such as pyridine.

In the above mentioned process (b), the reaction temperature can be varied within a substantially wide range. In general, the reaction is carried out at a temperature of from about -120° C. to about 200° C., preferably from 20° C. to about 100° C.

Further, the reaction is carried out under normal pressure, although it is also possible to employ a higher or reduced pressure.

When the above mentioned process (b) according to the present invention is carried out, use is made, for example, of about 1 to 3 moles of the compound of the formula (V) in a diluent such as acetonitrile per 1 mole of the compounds represented by the general formula (IV) to obtain the desired compounds.

The reaction of the above production method (c) can be carried out in an appropriate diluent, for example, an optional inert organic solvent. Examples of such organic solvents are: aliphatic, alicyclic or aromatic hydrocarbons (which may be optionally chlorinated), such as pentane, hexane, cyclohexane, petroleum ether, ligroin, benzene, toluene, xylene, dichloromethane, chloroform, carbon tetrachloride, 1,2-dichloroethane, chlorobenzene and dichlorobenzene; ethers such as ethyl ether, methyl ethyl ether, isopropyl ether, butyl ether, dioxane, dimethoxyethane (DME), tetrahydrofuran (THF) and diethylene glycol dimethyl ether (DGM); ketones such as acetone, methyl ethyl ketone (MEK), methyl-isopropyl ketone and methyl isobutyl ketone (MIBK); nitriles such as acetonitrile, propionitrile and acrylonitrile; esters such as ethyl acetate and amyl acetate; acid amides such as dimethylformamide (DMF), dimethylacetamide (DMA), N-methylpyrrolidone, 1,3-dimethyl-2-imidazolidinone and hexamethylphosphoric triamide (HMPA); and sulfones and sulfoxides such as dimethyl sulfoxide (DMSO) and sulfolan.

The production method (c) can also be carried out in the presence of an acid binding agent. Examples of usable acid binding agents are as follows: inorganic bases, for example, hydroxides, carbonates and bicarbonates of alkali metals or alkaline earth metals, such as sodium hydrogencarbonate, potassium hydrogencarbonate, sodium carbonate, potassium carbonate, lithium hydroxide, sodium hydroxide, potassium hydroxide and calcium hydroxide; organic bases, for example, tertiary amines, N,N-dialkylanilines and pyridines, such as triethylamine, 1,1,4,4-tetramethylethylenediamine (TMEDA), N,N-dimethylaniline, N,N-diethylaniline, pyridine, 4-dimethylaminopyridine (DMAP), 1,4-diazabicyclo[2,2,2]octane (DABCO) and 1,8-diazabicyclo[5,4,0]undec-6-ene (DBU).

The reaction of the production method (c) can be conducted at a temperature within a substantially broad range, but it is generally possible to employ a reaction temperature of about -70 to about 150° C., preferably about -10 to about 80° C. Further, the reaction should preferably be conducted under normal pressure but it may optionally be operated under an elevated or reduced pressure.

For carrying out the production method (c), for instance, 1 mole of the compound of the formula (IV) can be reacted with 1 to 3 moles of the compound of the formula (VI) in a diluent such as dichloromethane and in the presence of a base such as 4-(N,N-dimethylamino)pyridine to thereby obtain the object compound of the formula (I).

In carrying out the process (d) mentioned above, use may be made, as suitable diluent, of any inert solvent.

Examples of such diluents are aliphatic, cycloaliphatic and aromatic, optionally chlorinated, hydrocarbons such as pentane, hexane, cyclohexane, petroleum ether, ligroin, benzene, toluene, xylene, dichloromethane, chloroform, carbon tetrachloride, 1,2-dichloroethane, chlorobenzene, dichlorobenzene and the like; ethers such as diethyl ether, methyl ethyl ether, diisopropyl ether, dibutyl ether, dioxane, dimethoxyethane(DME), tetrahydrofurane (THF) dimethylene glycol dimethyl ether and the like; ketones such as acetone, methylethyl ketone (MEK), methyl-isopropyl ketone, methyl-isobutyl ketone (MIBK) and the like; nitriles such as acetonitrile, propionitrile and the like; esters such as ethyl acetate, amyl acetate and the like, acid amides such as dimethyl formamide (DMF), dimethyl acetamide (DMA), N-methylpyrrolidone, 1,3-dimethyl-2-imidazolidinone, hexamethylphosphoric traimide (HMPA) and the like; sulfones and sulfoxides such as dimethyl sulfoxide (DMSO), sulfolane and the like; and base such as pyridine.

The process (d) according to the invention is carried out preferably in the presence of an acid binder. As example of such acid binder may be mentioned: inorganic bases including hydroxide, carbonate, bicarbonate of alkali metals and alkali earth metals such as, for example, sodium hydrogencarbonate, potassium hydrogencarbonate, sodium carbonate, potassium carbonate, and the like, inorganic alkali metal amide including lithium amide, sodium amide, potassium amide, and the like, organic bases including alkorate, tertiary amines, N,N-dialkylanilines, and pyridines such as, for example, triethylamine, tributylamine, 1,1,4,4-tetramethylenediamine (TMEDA), N,N-dimethylaniline, N,N-diethlaniline, pyridine, 4-dimethylaminopyridine (DMAP), 1,4-diaza-bicyclo-[2,2,2]octane (DABCO), 1,8-diazabicyclo[5,4,0]-undec-7-ene (DBU) and the like.

In the above mentioned process (d), the reaction temperature can be varied within a substantially wide range. In general, the reaction is carried out at a temperature of from about -70° C. about 150° C., preferably from -10° C. to about 100° C. Further, the reaction is carried out under normal pressure, although it is also possible to employ a higher or reduced pressure.

When the above mentioned process (d) according to the present invention is carried out, use is made, for example, about 1 to 5 moles of the compound of the formula (VIII), in diluent such as tetrahydrofurane and in the presence of an acid binder, such as sodium hydrogencarbonate, per 1 mole of the compounds represented by the general formula (VII) to obtain the desired compounds.

The reaction of the above production methods (e) and (f) can be carried out in an appropriate diluent. As such diluents, there may be mentioned water and optional inert organic solvents, for example, aliphatic, alicyclic or aromatic hydrocarbons (which may be optionally chlorinated) such as pentane, hexane, cyclohexane, petroleum ether, ligroin, benzene, toluene, xylene, dichloromethane, chloroform, carbon tetrachloride, 1,2-dichloroethane, chlorobenzene and dichlorobenzene; ethers such as ethyl ether, methyl ethyl ether, isopropyl ether, butyl ether, dioxane, dimethoxyethane (DME), tetrahydrofuran (THF) and diethylene glycol dimethyl ether (DGM); nitriles such as acetonitrile, propionitrile and acrylonitrile; and alcohols such as methanol, ethanol, isopropanol, butanol and ethylene glycol.

The reaction of the production method (e) can be conducted at a temperature within a substantially broad range, but it is generally possible to employ a reaction temperature of about -30° C. to about 150° C., preferably about -20° C. to about 100° C. Furthermore, the reaction should preferably be conducted under normal pressure but it may optionally be operated under an elevated or reduced pressure.

For carrying out the production method (e), for instance, 1 mole of the compound of the formula (IX) can be reacted with 1 to 10 moles of an oxidizing agent in a diluent such as methanol to thereby obtain the object compound of the formula (I).

The production method (f) can be conducted at a temperature within a substantially broad range, but it is generally possible to employ a reaction temperature of about -70° C. to about 150° C., preferably about -10° C. to about 100° C. Further, the reaction should preferably be conducted under normal pressure but it may optionally be operated under an elevated or reduced pressure.

For carrying out the production method (f), for instance, 1 mole of the compound of the formula (X) can be reacted with 1 to 3 moles of an oxidizing agent in a diluent such as dichloromethane to thereby obtain the object compound of the formula (I).

Further, the compounds of the formula (I), according to the invention can be used for combating a broad range of various pests, particularly injurious sucking insects, biting insects and other plantparasitic pests as well as pests of stored cereals and hygiene pests, and can be used as insecticides for combating them.

Examples of such pests are as follows:

As insects, there may be mentioned pests from the order of the Coleoptera, for example, Callosobruchus chinensis, Sitophilus zeamais, Tribolium castaneum, Epilachna vigintioctomaculata, Agriotes fuscicollis, Anomala rufocuprea, Leptinotrarsa decemlineata, Diabrotica spp., Monochamus alternatus, Lissorhoptrus oryzophilus and Lyctus bruneus;

pests from the order of the Lepidoptera, for example, Lymantria dispar, Malacosoma neustria, Pieris rapae, Spodoptera litura, Mamestra brassicae, Chilo suppressalis, Pyrausta nubilalis, Ephestia cautella, Adoxophyes orana, Carpocapsa pomonella, Agrotis fucosa, Galleria mellonella, Plutella xylostella, Heliothis virescens and Phyllocnistis citrella;

pests from the order of the Hemiptera, for example, Nephotettix cincticeps, Nilaparvata lugens, Pseudococcus comstocki, Unaspis yanonensis, Myzus persicase, Aphis pomi, Aphis gossypii, Lipaphis erysimi, Stephanitis nashi, Nezara spp., Cimex lectularius, Trialeurodes vaporariorum and Psylla spp.;

pests from the order of the Orthoptera, for example, Blattela germanica, Periplaneta americana, Gryllotralpa africana and Locusta migratoria migratoriodes;

pests from the order of the Isoptera, for example, Deucotermes speratus and Coptotermes formosanus; and

pests from the order of the Diptera, for example, Musca domestica, Aedes aegypti, Hylemia platura, Culex pipiens, Anopheles sinensis and Culex tritaeniorhynchus.

As mites, there may be mentioned, for example, Tetranychus kanzawai, Tetranychus urticae, panonychus citri, Aculops pelekassi and Tarsonemus spp.

As nematodes, there may be mentioned, for example, Meloidogyne incognita, Bursaphelenchus xylophilus, Aphelenchoides besseyi, Heterodera glycines and Pratylenchus spp.

Further, in the pharmaceutical field of veterinary medicine, the novel compounds according to the invention are effective against various injurious animal parasites (endoparasites and ectoparasites), such as insects and helminths. Examples of such animal parasites include the following pests:

As insects, there may be mentioned, for example, Gastrophilus spp., Stomoxys spp., Trichodectes spp., Rhodnius spp. and Ctenocephalides spp.

As mites, there may be mentioned, for example, Ornithodoros spp., Ixodes spp. and Boophilus spp.

In this specification, the "insecticide(s)" is a generic term for substances having combating action against all the pests as mentioned above.

In the case of the use as insecticides, the active compounds of the formula (I) can be converted into customary formulations, such as solutions, wettable powders, suspensions, powders, foams, pastes, tablets, granules, aerosols, natural and synthetic materials impregnated with active compounds, very fine capsules in polymeric substances and in coating compositions for seed, furthermore in formulations used with buring equipment, such as fumigating cartridges, fumigating cans and fumigating coils and the like, as well as ULV cold- and warm-mist formulations.

These formulations are produced in the manner known per se, for example, by mixing the active compounds with extenders, that is liquid solvents, liquefied gases under pressure and/or solid carriers, optionally with the use of surface-active agents, that is emulsifying agents and/or dispersing agents and/or foam-forming agents. Use of a surface-active agent is preferred.

As liquid solvents or carriers, there are suitable in the main: aromatic hydrocarbons, such as xylene, toluene or alkyl naphthalenes; chlorinated aromatic hydrocarbons and chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride; aliphatic hydrocarbons, such as cyclohexane or paraffins, for example mineral oil fractions, alcohols, such as butanol or glycol as well as their ethers and esters, ketones, such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone; strongly polar solvents, such as dimethyl-formamide and dimethylsulfoxide; as well as water. In the case of the use of water as an liquid solvent or carrier, organic solvents can be used as auxiliary solvents.

By liquefied gaseous diluents or carriers there are meant liquids which are gaseous at normal temperature and under atmospheric pressure, for example aerosol propellants, such as butane, propane, nitrogen, carbon dioxide and halogenohydrocarbons.

As solid diluents or carriers there are suitable: for example, ground natural minerals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground synthetic minerals, such as highly-dispersed silicic acid, alumina and silicates.

As solid carriers for granules there are suitable: for example, crushed and fractionated natural rocks such as calcite, marble, pumice, sepiolite and dolomite, as well as synthetic granules of inorganic and organic meals, and granules of organic material such as sawdust, coconut shells, maize cobs and tobacco stalks.

As emulsifying and/or foam-forming agents there are suitable: for example non-ionic and anionic emulsifiers, such as polyoxy-ethylene-fatty acid esters, polyoxyethylene-fatty alcohol ethers, for example alkylaryl polyglycol ethers, alkylsulfonates, alkyl-sulfates, arylsulfonates as well as albumin hydrolysation products.

As dispersing agents there are suitable: for example lignin-sulphite waste liquors and methylcellulose.

Adhesives may also be used in formulations such as powders, granules and emulsions, and the followings are to be mentioned as examples of usable adhesives: for example carboxymethylcellulose and natural and synthetic polymers such as gum arabic, polyvinyl alcohol and polyvinyl acetate.

It is possible to use colorants such as inorganic pigments, for example iron oxide, titanium oxide and Prussian Blue, and organic dyestuffs, such as alizarin dyestuffs, azo dyestuffs and metal phthalocyanine dyestuffs, and trace nutrients such as salts of metals, for example iron, manganese, boron, copper, cobalt, molybdenum and zinc.

The formulations in general can contain between 0.1 and 95 per cent by weight, preferably between 0.5 and 90% by weight of the above active compound.

The active compounds of the formula (I), according to the invention, can be present in their commercially available formulations and the use forms prepared with these formulations as a mixture with other active compounds, such as insecticides, attractants, sterilants, miticides, nematocides, fungicides, growth-regulating substances or herbicides. The above insecticides include, for example, organic phosphate, carbamates, carboxylates, chlorinated hydrocarbons and insecticidal substances produced by microorganisms.

The active compounds of the formula (I), according to the invention, can further be present as a mixture with synergistic agents. Synergistic agents are compounds which increase the action of the active compounds, without it being necessary for the synergistiec agent added to be active itself.

The content of the active compounds of the formula (I), according to the invention, in their use form can be varied within wide limits. The concentration of the active compounds of the formula (I) according to the invention in their use form can generally be from 0.0000001 to 100 per cent by weight, preferably between 0.00001 and 1 per cent by weight.

The compounds of the formula (I), according to the invention, can be employed in a customary manner appropriate for the use forms, for example, by spraying and by scattering. The ompounds of formula (I) can be applied for the treatment of soil and of leaves. They also show activity after systemic translocation. Further, the active compounds according to the invention have a good stability to alkali on limed substances and excellent residual action on wood and soil. Thus, they are extremely effective for combating hygiene pests and pests of stored cereals.

Then, the following Examples illustrates the invention, but they should not be regarded as limiting the scope of the invention.

SYNTHESIS EXAMPLE 1 ##STR493##

An ethanol solution (50 ml) of 4-chloro-4'-methylmercaptomethylbenzophenone (9.3 g), hydrazine hydrate (6 ml) and acetic acid (3 ml) was heated for 20 hours with refluxing. The solvent was distilled off under reduced pressure, and then the obtained oily substance was diluted with dichloromethane and washed successively with an aqueous 5% sodium hydroxide solution, water and an aqueous saturated a sodium chloride solution, followed by drying over anhydrous magnesium sulfate. The solvent was then distilled off to obtain 4-chloro-4'-methylmercaptomethylbenzophenone hydrazone (7.1 g) as an isomer mixture (syn form/anti form=about 1:1).

n_(D) ²⁰ 1.6350

SYNTHESIS EXAMPLE 2 ##STR494##

An ethanol solution (100 ml) of 4-fluoro-4'-methylmercaptomethylbenzophenone (7.8 g), ethyl carbazate (9.4 g) and acetic acid (9 ml) was heated for 20 hours with refluxing. The solvent was distilled off under reduced pressure, and then the obtained oily substance was diluted with dichloromethane, and washed successively with an aqueous 5% sodium hydroxide solution, water and an aqueous saturated sodium chloride solution, followed by drying over anhydrous magnesium sulfate. The solvent was then distilled off to obtain 4-fluoro-4'-methylmercaptomethylbenzophenone ethoxycarbonylhydrazone (6.4 g) as an isomer mixture.

n_(D) ²⁰ 1.6040

SYNTHESIS EXAMPLE 3 ##STR495##

An ethanol solution (100 ml) of 4-chloro-4'-methylsulfinylmethyl benzophenone (5.8 g), ethyl carbazate (6.3 g) and pyridinium p-toluenesulfonate (0.1 g) was heated for 6 hours with refluxing. After cooling to a room temperature, the reaction mixture was poured into ice-water, and the precipitated crystals were collected by filtration, and washed successively with an aqueous sodium bicarbonate solution and water. After air-drying, 4-chloro-4'-methylsulfinylmethylbenzophenone ethoxycarbonylhydrazone (6.4 g) was obtained as an isomer mixture.

melting point: 65-70° C.

A reaction was conducted in the same manner as in Synthesis Example 3 except that 4-chloro-4'-methylsulfonylmethylbenzophenone (6.2 g) was used instead of 4-chloro-4'-methylsulfinylmethylbenzophenone to thereby obtain 4-chloro-4'-methylsulfonylmethylbenzophenone ethoxycarbonylhydrazone (6.7 g) as an isomer mixture.

melting point: 166-169° C.

SYNTHESIS EXAMPLE 4 ##STR496##

An ethanol solution (100 ml) of 4-chloro-4'-methylmercaptomethylbenzophenone (8.3 g), ethyl carbazate (10 g) and pyridinium p-toluenesulfonate (0.1 g) was heated for 16 hours with refluxing. After cooling to a room temperature, the reaction mixture was poured into ice water, and then the precipitated crystals were collected by filtration, and washed with water. After air-drying, 4-chloro-4'-methylmercaptomethylbenzophenone ethoxycarbonylhydrazone (9.4 g) was obtained as an isomer mixture.

melting point: 105-109° C.

This mixture (1.0 g) was purified by silica gel column chromatography (developing solvent: n-hexane:ethyl acetate=9:1) to obtain 0.24 g of Isomer A having a melting point of 106-107° C. from the first eluate portion and 0.56 g of Isomer B having a melting point of 117-120° C. from the second eluate portion.

SYNTHESIS EXAMPLE 5 ##STR497##

To a dichloromethane solution (30 ml) of 4-chloro-4'-methylmercaptomethylbenzophenone hydrazone (1.5 g) and 4-(N,N-dimethylamino)pyridine (1.2 g), isobutyl chlorocarbonate (0.8 g) was dropwise added under cooling with ice and subsequently stirred at a room temperature for 20 hours. The reaction mixture was then successively washed with 2N hydrochloric acid, water and an aqueous saturated sodium chloride solution, and dried over anhydrous magnesium sulfate. After distilling off the solvent, the crude product was purified by silica gel column chromatography (developing solvent: ethyl acetate:n-hexane=1:4) to obtain 4-chloro-4'-methylmercaptomethylbenzophenone isobutoxycarbonyl hydrazone (0.5 g) as an isomer mixture.

n_(D) ²⁰ 1.6103

SYNTHESIS EXAMPLE 6 ##STR498##

To a acetonitrile solution (10 ml) of 4-chloro-4'-methylmercaptomethylbenzophenone (0.5 g), 4-trifluoromethoxyphenyl isocyanate (0.3 g) was added and stirred at a room temperature for 10 hours. After the soluvent was distilled off under reduced pressure, the resdue was recrystallized from ethanol to obtain 4-chloro-4'-methylmercaptomethylbenzophenone4-(4-trifluoromethoxyphenyl)-semicarbazone (0.5 g).

melting point: 179-183° C.

SYNTHESIS EXAMPLE 7 ##STR499##

To a dimethylformamide solution (10 ml) of 4-chloro-4'-methylmercaptomethylbenzophenone ethoxycarbonylhydrazone (3.6 g), sodiumuhydride-60% oil suspension (0.4 g) was added under an argon atmosphere and stirred at a room temperature untill the evolution of hydrogen gas ceased.

And then methyl iodide (3 g) was added and stirred at room temperature for 16 hours. After the reaction mixture was poured into ice-water, ethyl acetate was added thereto. Then the organic layer was separated, and washed successively with an aqueous 2 N hydrochloric acid solution, water and aqueous saturated sodium chloride solution, followed by drying over anhydrous sodium sulfate. After distilling off the solvent, the obtained crude product was purified by silca gel colum chromatography (developing solvent n-hexane:ethyl acetate=5:1) to obtain 4-chloro-4'-methylmercaptomethylbenzophenone N'-ethoxycarbonyl-N'-methylhydrazone (1.5 g).

n_(D) ²⁰ 1.6039

The following Table 7 shows the compounds synthesized in the above Synthesis Examples 1 to 7 together with the compounds synthesized in the same manner as those in the Synthesis Examples 1 to 7. Compounds of Nos. 1 to 30, and 33 to 216 are isomer mixtures (anti form/syn form). Compound Nos. 31 and 32 are pure isomers.

    TABLE 7        -       ##STR500##      Compound         melting point or        No. R.sup.1 R.sup.2 R.sup.3 n R.sup.4 R.sup.5 R.sup.6 R.sup.7 refractiv       e index        1 Br H CH.sub.3 0 H H H H n.sub.D.sup.20 =       1.6890                       2 Cl H CH.sub.3 0 H H H H n.sub.D.sup.20 =        1.6350        3 Cl H CH.sub.3 1 H H H H 45-51°       C.                              4 Cl H CH.sub.3 2 H H H H 124-130.degree       .       C.      5 Br H CH.sub.3 0 CO.sub.2 C.sub.2 H.sub.5 CH.sub.2 OCH.sub.3 H H      n.sub.D.sup.20 =       1.5972                                                   6 Br H      CH.sub.3 0 CO.sub.2 C.sub.2 H.sub.5 CH.sub.2       SCH.sub.3 H H n.sub.D.sup.20 =       1.6032                                    7 Br H CH.sub.3 0 CO.sub.2      C.sub.2 H.sub.5 CH.sub.3 H H n.sub.D.sup.20 =       1.6186                      8 Br H CH.sub.3 0 CO.sub.2 C.sub.2 H.sub.5      H H H 98-103°       C.                                                   9 Br H CH.sub.3 0      CO.sub.2 CH.sub.3 CH.sub.2 OCH.sub.3 H H n.sub.D.sup.20 = 1.5984               10 Br H CH.sub.3 0 CO.sub.2 CH.sub.3 H H H 125-135° C.         11 Br H C.sub.2 H.sub.5 0 CO.sub.2 CH.sub.3 H H H n.sub.D.sup.20 =      1.6267        12 Br H CH.sub.2 CF.sub.3 0 CO.sub.2 C.sub.2       H.sub.5 H H H n.sub.D.sup.20 =       1.5824                                    13 Br H CH.sub.2 CHF.sub.2 0      CO.sub.2 C.sub.2 H.sub.5 H H H n.sub.D.sup.20 =       1.5941                    14 Br H CH.sub.3 1 CO.sub.2 CH.sub.3 H H H      58-63°       C.                                                          15 Br H      CH.sub.3 2 CO.sub.2 CH.sub.3 H H H 179-183°       C.                     16 Cl H CH.sub.3 0 CO.sub.2 C.sub.2 H.sub.5      CH.sub.2 CO.sub.2 C.sub.2 H.sub.5 H H n.sub.D.sup.20 =       1.5763             17 Cl H CH.sub.3 0 CO.sub.2 C.sub.2 H.sub.5 CH.sub.2        OC.sub.2 H.sub.5 H H n.sub.D.sup.20 =       1.5773                            18 Cl H CH.sub.3 0 CO.sub.2 C.sub.2      H.sub.5 CH.sub.2 OCH.sub.3 H H n.sub.D.sup.20 =       1.5903                    19 Cl H CH.sub.3 0 CO.sub.2 C.sub.2 H.sub.5      CH.sub.2 SCH.sub.3 H H n.sub.D.sup.20 =       1.6088                            20 Cl H CH.sub.3 0 CO.sub.2 C.sub.2      H.sub.5 CH.sub.3 H H n.sub.D.sup.20 =       1.6039                              21 Cl H CH.sub.3 0 CO.sub.2 C.sub.2        H.sub.5 CHF.sub.2 H H n.sub.D.sup.20 =       1.5824                                              22 Cl H CH.sub.3 0 CO.sub.2      C.sub.2       H.sub.5      ##STR501##       H H n.sub.D.sup.20 =       1.5872                           23 Cl H CH.sub.3 0 CO.sub.2 C.sub.2 H.sub.5      COC.sub.3 H.sub.7 -iso H H n.sub.D.sup.20 =       1.5740                        24 Cl H CH.sub.3 0 CO.sub.2 C.sub.2      H.sub.5 COC.sub.3 H.sub.7 -n H H n.sub.D.sup.20 =       1.5830                                                       25 Cl H CH.sub.3 0      CO.sub.2 C.sub.2       H.sub.5      ##STR502##       H H n.sub.D.sup.20 =       1.5996                           26 Cl H CH.sub.3 0 CO.sub.2 C.sub.2 H.sub.5       ##STR503##       H H n.sub.D.sup.20 =       1.6036                           27 Cl H CH.sub.3 0 CO.sub.2 C.sub.2 H.sub.5      COC.sub.6 H.sub.5 H H n.sub.D.sup.20 =       1.6175                             28 Cl H CH.sub.3 0 CO.sub.2 C.sub.2      H.sub.5 COCH═CHC.sub.6 H.sub.5 H H n.sub.D.sup.20 =       1.6318            29 Cl H CH.sub.3 0 CO.sub.2 C.sub.2       H.sub.5 COCH.sub.3 H H n.sub.D.sup.20 =       1.6015                           30 Cl H CH.sub.3 0 CO.sub.2 C.sub.2      H.sub.5 H H H 105-109°       C.                                          31 Cl H CH.sub.3 0 CO.sub.2        C.sub.2 H.sub.5 H H H 106-107°       C.                                32 Cl H CH.sub.3 0 CO.sub.2 C.sub.2      H.sub.5 H H H 117-120°       C.                                          33 Cl H CH.sub.2 CN 0      CO.sub.2 C.sub.2 H.sub.5 H H H 105-106.5°       C.                       34 Cl H CH.sub.3 0 CO.sub.2 C.sub.2 H.sub.5      n-C.sub.3 H.sub.7 H H n.sub.D.sup.20 =       1.5872                             35 Cl H CH.sub.3 0 CO.sub.2 CH.sub.2        CF.sub.3 H H H n.sub.D.sup.20 =       1.5954                                  36 Cl H CH.sub.3 0 CO.sub.2      CH.sub.2 CH═CH.sub.2 H H H n.sub.D.sup.20 =       1.6229                    37 Cl H CH.sub.3 0 CO.sub.2 CH.sub.2 CH.sub.2        Cl H H H 98-101°       C.                                              38 Cl H CH.sub.3 0      CO.sub.2 CH.sub.3 CH.sub.2 OCH.sub.3 H H n.sub.D.sup.20 = 1.6029               39 Cl H CH.sub.3 0 CO.sub.2 CH.sub.3 H H H 136-140° C.         40 Cl H CH.sub.2 CN 0 CO.sub.2 9H.sub.3 H H H 38.5-147.5° C.         41 Cl H CH.sub.3 0 CO.sub.2 C.sub.3 H.sub.7       -iso H H H 115-119°       C.                                            42 Cl H CH.sub.3 0      CO.sub.2 C.sub.4 H.sub.9 -iso H H H n.sub.D.sup.20 =       1.6103               43 Cl H CH.sub.3 0 CO.sub.2 C.sub.3 H.sub.7 -n H H        H 94-98°       C.                                                      44 Cl H      CH.sub.3 0 CO.sub.2 C.sub.4 H.sub.9 -n H H H 79-83°       C.             45 Cl H CH.sub.3 0 CO.sub.2 C.sub.5 H.sub.11 -n H H H      86-89°       C.                                                          46 Cl H      CH.sub.3 0 CO.sub.2 C.sub.6 H.sub.13 -n H H H 63.5-66.5° C.             47 Cl H CH.sub.3 0 CO.sub.2 C.sub.4 H.sub.9       -tert H H H 52-55°       C.                                             48 Cl H CH.sub.3 0      CO.sub.2 C.sub.2 H.sub.5 H H 3-Br 124-125°       C.                      49 Cl H CH.sub.3 0 CO.sub.2 C.sub.2 H.sub.5 H H        3-CH.sub.3 n.sub.D.sup.20 =       1.6147                                      50 Cl H C.sub.2 H.sub.5 0      CO.sub.2 C.sub.2 H.sub.5 H H H 77-78.5°       C.                         51 Cl H C.sub.2 H.sub.5 0 CO.sub.2 CH.sub.2      CF.sub.3 H H H n.sub.D.sup.20 =       1.5732                                    52 Cl H C.sub.2 H.sub.5 0      CO.sub.2 CH.sub.3 H H H 87-92°       C.                                  53 Cl H C.sub.3 H.sub.7 -iso 0      CO.sub.2 C.sub.2 H.sub.5 H H H 125-127°       C.                         54 Cl H C.sub.3 H.sub.7 -iso 0 CO.sub.2      CH.sub.3 H H H n.sub.D.sup.20 =       1.6267                                    55 Cl H C.sub.3 H.sub.7 -n 0      CO.sub.2 C.sub.2 H.sub.5 H H H 70-71°       C.                           56 Cl H C.sub.3 H.sub.7 -n 0 CO.sub.2      CH.sub.3 H H H 98-101°       C.                                          57 Cl H C.sub.4 H.sub.9 -n      0 CO.sub.2 C.sub.2 H.sub.5 H H H n.sub.D.sup.20 =       1.5908                  58 Cl H CF.sub.3 0 CO.sub.2 C.sub.2 H.sub.5 H H        H n.sub.D.sup.20 =       1.5772                                               59 Cl H CH.sub.2      C.tbd.CH 0 CO.sub.2 C.sub.2 H.sub.5 H H H 118-124°       C.              60 Cl H CH.sub.2 C.tbd.CH 0 CO.sub.2 CH.sub.3 H H H      127-137°       C.                                                        61 Cl H      CH.sub.2 CF.sub.3 0 CO.sub.2 C.sub.2 H.sub.5 H H H n.sub.D.sup.20 =      1.5838        62 Cl H CH.sub.2 CF.sub.3 0 CO.sub.2 CH.sub.3 H H H n.sub.D.sup.20 =      1.5603        63 Cl H CH.sub.2 CH.sub.2 CH.sub.2 Cl 0 CO.sub.2 C.sub.2 H.sub.5 H H H        77-79°       C.                                                        64 Cl H      CH.sub.2 CH.sub.2 F 0 CO.sub.2 C.sub.2 H.sub.5 H H H 75.5-77.5°      C.        65 Cl H CH.sub.2 CH.sub.2 F 0 CO.sub.2 CH.sub.3 H H H 78-82° C.        66 Cl H CH.sub.2 CH═CH.sub.2 0 CO.sub.2 C.sub.2 H.sub.5 H H H      67-81°       C.                                                          67 Cl H      CH.sub.2 CHF.sub.2 0 CO.sub.2 C.sub.2 H.sub.5 H H H n.sub.D.sup.20 =      1.5762        68 Cl H CH.sub.2 CHF.sub.2 0 CO.sub.2 CH.sub.3 H H H n.sub.D.sup.20 =      1.5838        69 Cl H CHF.sub.2 0 CO.sub.2 C.sub.2 H.sub.5 H H H 85-88.5° C.        70 Cl H CHF.sub.2 0 CO.sub.2 CH.sub.3 H H H 85-88°       C.            71 Cl H CH.sub.3 1 CO.sub.2 C.sub.2 H.sub.5 H H H      65-70°       C.                                                          72 Cl H      CH.sub.3 1 CO.sub.2 CH.sub.3 H H H 60-75°       C.                       73 Cl H C.sub.2 H.sub.5 1 CO.sub.2 C.sub.2      H.sub.5 H H H n.sub.D.sup.20 =       1.5835                                     74 Cl H C.sub.3 H.sub.7 -n 1        CO.sub.2 CH.sub.3 H H H 69.5-72°       C.                              75 Cl H CH.sub.2 CF.sub.3 1 CO.sub.2      C.sub.2 H.sub.5 H H H 64.5-72°       C.                                  76 Cl H CHF.sub.2 1 CO.sub.2      C.sub.2 H.sub.5 H H H 57-69°       C.                                    77 Cl H CHF.sub.2 1 CO.sub.2      CH.sub.3 H H H amorphous        78 Cl H CH.sub.3 2 CO.sub.2 C.sub.2 H.sub.5 H H H 166-169° C.         79 Cl H CH.sub.3 2 CO.sub.2 CH.sub.3 H H H 205-208° C.               80 Cl H CH.sub.3 2 CO.sub.2 C.sub.4 H.sub.9 -tert H H H      190-193°       C.                                                        81 Cl H      C.sub.2 H.sub.5 2 CO.sub.2 CH.sub.5 H H H 93-95°       C.                82 Cl H C.sub.2 H.sub.5 2 CO.sub.2 CH.sub.3 H H H      70-78°       C.                                                          83 Cl H      C.sub.3 H.sub.7 -iso 2 CO.sub.2 CH.sub.3 H H H n.sub.D.sup.20 = 1.5930         84 Cl H C.sub.3 H.sub.7 -n 2 CO.sub.2 CH.sub.3 H H H 131-138°      C.        85 Cl H CH.sub.2 CHF.sub.2 2 CO.sub.2 C.sub.2       H.sub.5 H H H 147-149°       C.                                         86 Cl CH.sub.3 CH.sub.3 0      CO.sub.2 C.sub.2 H.sub.5 H H H n.sub.D.sup.20 =       1.6205                    87 Cl CH.sub.3 CH.sub.3 0 CO.sub.2 CH.sub.3 H        H H n.sub.D.sup.20 =       1.6032                                             88 Cl CH.sub.3      CH.sub.3 1 CO.sub.2 C.sub.2 H.sub.5 H H H 48-53°       C.                89 Cl CH.sub.3 CH.sub.3 2 CO.sub.2 C.sub.2 H.sub.5 H      H H 115-117°       C.                                                    90 Cl C.sub.2      H.sub.5 CH.sub.3 0 CO.sub.2 C.sub.2 H.sub.5 H H H n.sub.D.sup.20 =      1.6052        91 Cl n-C.sub.3 H.sub.7 CH.sub.3 0 CO.sub.2 C.sub.2 H.sub.5 H H H      n.sub.D.sup.20 =       1.5995                                                   92 Cl H      CH.sub.3 0 CO.sub.2 C.sub.2 H.sub.5 H 2-Cl H 52-55°       C.             93 Cl H CH.sub.3 0 CO.sub.2       CH.sub.3 H 2-Cl H 61-64°       C.                                       94 Cl H CH.sub.3 0 CO.sub.2      C.sub.2 H.sub.5 H 3-Cl H 135-143°       C.                               95 F H CH.sub.3 0 CO.sub.2 C.sub.2      H.sub.5 H H H n.sub.D.sup.20 =       1.6040                                     96 F H CH.sub.3 0 CO.sub.2      C.sub.2 H.sub.5 H 3-F H n.sub.D.sup.20 =       1.5803                           97 I H CH.sub.3 0 CO.sub.2 C.sub.2      H.sub.5 H H H 128-130°       C.                                          98 Cl H CH.sub.3 0 COCH.sub.       3 H H H 124-128°       C.                                               99 Cl H CH.sub.3 0      COC.sub.2 H.sub.5 H H H 103-113°       C.                                100 Cl H CH.sub.3 0 COC.sub.3 H.sub.7        -n H H H 100-104°       C.                                             101 Cl H CH.sub.3 0      COC.sub.4 H.sub.9 -n H H H 50-55°       C.                               102 Cl H CH.sub.3 0 COC.sub.4 H.sub.9      -tert H H H 88-94°       C.                               103 Cl H CH.sub.3 0       ##STR504##       H H H 122-124°       C.                            104 Cl H CH.sub.3 0       ##STR505##       H H H 114-116°       C.                            105 Cl H CH.sub.3 0       ##STR506##       H H H 144-145°       C.                            106 Cl H CH.sub.3 0 COC.sub.6 H.sub.5 H H H      126-130°       C.                                                        107 Cl H      CH.sub.3 0 COCH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2       Cl H H H 100-103°       C.                                              108 Cl H CH.sub.3 0      COCH.sub.2 CH.sub.2 CH.sub.2 Cl H H H 83-88°       C.                    109 Cl H CH.sub.3 0 COCH.sub.2 CH.sub.2 Cl H H H      98-101°       C.                                                         110 Cl H      CH.sub.3 1 COC.sub.3 H.sub.7 -n H H H 140-145°       C.                  111 Cl H CH.sub.3 2 COC.sub.3 H.sub.7 -n H H H      121-131°       C.                     112 Cl H CH.sub.3 0       ##STR507##       H H H 145-148°       C.                            113 Cl H CH.sub.3 0 CONH.sub.2 H H H 167-176.degree       .       C.      114 Cl H CH.sub.3 0 CONHC.sub.2 H.sub.5 H H H n.sub.D.sup.20 = 1.6080      115 Cl H CH.sub.3 0       ##STR508##       H H H 179-183°       C.                            116 Cl H CH.sub.3 0 CONHCH.sub.2 CH.sub.2 Cl H H H        126-135°       C.                                                      117 Cl H      CH.sub.3 0 CSNH.sub.2 H H H 169-172°       C.                                                 118 Cl H CH.sub.3 0       ##STR509##       H H H n.sub.D.sup.20 =       1.6824                             119 Cl H CH.sub.3 2 CONHC.sub.2 H.sub.5 H H H      186-189°       C.                                                        120 Cl H      sec-C.sub.4 H.sub.9 0 CO.sub.2 C.sub.2 H.sub.5 H H H mixture of crystal                 and oily substance      121 Cl H CH.sub.3 0       ##STR510##       H H H 121-122.5°       C.                              122 Cl H CH.sub.3 0       ##STR511##       H H H n.sub.D.sup.20 =       1.6543                             123 Cl H CH.sub.3 0 COCH.sub.2 CO.sub.2 C.sub.2      H.sub.5 H H H n.sub.D.sup.20 =       1.6148                                     124 Cl H CH.sub.3 0 CO.sub.2        C.sub.2 H.sub.5 iso-C.sub.3 H.sub.7 H H n.sub.D.sup.20 = 1.5799                                                                        125 Cl        H CH.sub.3 0       ##STR512##       H H H n.sub.D.sup.20 =       1.6081                             126 Cl H CH.sub.3 0 CO.sub.2 C.sub.5 H.sub.11      -neo H H H 144-146°       C.                                             127 Cl H CH.sub.3 0      CO.sub.2 CH.sub.2 CH(CH.sub.3)C.sub.2 H.sub.5 H H H n.sub.D.sup.20 =      1.6061        128 Cl H CH.sub.3 0 CO.sub.2 CH.sub.2 C(CH.sub.3)═CH.sub.2 H H H      n.sub.D.sup.20 =       1.6195                                                   129 Cl H      CH.sub.3 0 CO.sub.2 C.sub.2 H.sub.5 H 3-F H n.sub.D.sup.20 = 1.6084            130 Cl H CH.sub.3 0 CO.sub.2 C.sub.2 H.sub.5 H 2-F H 73-76°        C.        131 Cl H CH.sub.3 0 CO.sub.2 C.sub.2 H.sub.5 CH.sub.2 C.sub.6 H.sub.5      H H n.sub.D.sup.20 =       1.6250                                               132 Cl H CH.sub.3      0 CO.sub.2 C.sub.2 H.sub.5 H H H n.sub.D.sup.20 =       1.5939                  133 Cl H CH.sub.3 0 COC.sub.3 H.sub.7 -n      CH.sub.3 H H n.sub.D.sup.20 =       1.6139                                      134 Cl H (CH.sub.2).sub.3 F        0 CO.sub.2 C.sub.2 H.sub.5 H H H 69.5-77.5°       C.                   135 Cl H CH.sub.2 CF.sub.3 2 CO.sub.2 C.sub.2      H.sub.5 H H H 147.5-154.5°       C.                                      136 Cl H CH═CH.sub.2 0      CO.sub.2 C.sub.2 H.sub.5 H H H n.sub.D.sup.20 =       1.6233                    137 Cl H CH.sub.2 Cl 0 CO.sub.2 C.sub.2      H.sub.5 H H H 102-103°       C.                                          138 Cl H CH.sub.3 0      tert-C.sub.4 H.sub.9 H H H n.sub.D.sup.20 =       1.5935                        139 Cl H CH.sub.3 0 CO.sub.2 CH.sub.3      COC.sub.3 H.sub.7 -n H H n.sub.D.sup.20 =       1.5773                          140 Cl H C.sub.2 H.sub.5 0 CO.sub.2      C.sub.3 H.sub.7 -n H H H n.sub.D.sup.20 =       1.5927                          141 Cl H C.sub.2 H.sub.5 0 CO.sub.2      C.sub.3 H.sub.7 -iso H H H 93.5-101°       C.                            142 Cl H CH.sub.3 0 COCH.sub.2 CN H H H      118-125.5°       C.                                                      143 Br H      CH.sub.3 2 CO.sub.2 C.sub.2 H.sub.5 H H H 159-161°       C.              144 Cl H CH.sub.3 2 CH.sub.3 H H H amorphous        145 Cl H CH.sub.3 2 CH.sub.3 CH.sub.3 H H 133.5-136° C.               146 Cl H CH.sub.3 2 C.sub.6 H.sub.5 H H H 172.5-180.5°      C.        147 Br H C.sub.2 H.sub.5 0 CO.sub.2 C.sub.3 H.sub.7       -n H H H n.sub.D.sup.20 =       1.6162                                         148 Cl H C.sub.2 H.sub.5        0 CO.sub.2 C.sub.4 H.sub.9 -sec H H H n.sub.D.sup.20 =       1.5944           149 Cl H C.sub.2 H.sub.5 0 COCH.sub.2 OCH.sub.3 H H H      86-95°       C.                                                          150 Cl H      CH═CH.sub.2 0 CO.sub.2 CH.sub.3 H H H n.sub.D.sup.20 = 1.6282              151 Cl H C.sub.2 H.sub.5 0 CO.sub.2 C.sub.4 H.sub.9 -iso H H H      n.sub.D.sup.20 =       1.5914                      152 Cl H C.sub.2       H.sub.5 0      ##STR513##       H H H n.sub.D.sup.20 =       1.5878                             153 Cl H CH.sub.3 2 C.sub.6 H.sub.5 CH.sub.3 H H      63-66.5°       C.                     154 Cl H C.sub.2       H.sub.5 0      ##STR514##       H H H n.sub.D.sup.20 =       1.5843                             155 Cl H CH.sub.3 0 CO.sub.2 C.sub.2 H.sub.5      COC.sub.2 H.sub.5 H H n.sub.D.sup.20 =       1.5756                             156 Cl H C.sub.2 H.sub.5 0 CO.sub.2      C.sub.3 H.sub.7 -n COC.sub.3 H.sub.7 -n H H n.sub.D.sup.20 = 1.5681            157 Cl H CH.sub.2 F 0 CO.sub.2 C.sub.2       H.sub.5 H H H n.sub.D.sup.20 =       1.6051                                    158 Cl H CH.sub.3 0 CO.sub.2      C.sub.2 H.sub.5 C.sub.2 H.sub.5 H H n.sub.D.sup.20 =       1.5931               159 Cl H C.sub.2 H.sub.5 0 CO.sub.2 C.sub.2      H.sub.5 C.sub.3 H.sub.5 -iso H H n.sub.D.sup.20 =       1.5694                  160 Br H CH.sub.3 0 CO.sub.2 C.sub.2 H.sub.5      C.sub.3 H.sub.5 -iso H H n.sub.D.sup.20 =       1.5956                          161 Cl H CH.sub.3 0 COCH.sub.2       OCH.sub.3 CO.sub.2 C.sub.2 H.sub.5 H H n.sub.D.sup.20 =       1.5850                                                              162 Cl H      CH.sub.3 0       ##STR515##       H H H 109-114.5°       C.                              163 Cl H CH.sub.3 0 CO.sub.2 C.sub.4 H.sub.9      -sec H H H n.sub.D.sup.20 =       1.5901                                        164 Br H C.sub.2 H.sub.5      0 CO.sub.2 C.sub.2 H.sub.5 H H H n.sub.D.sup.20 =       1.6231                  165 Cl H C.sub.2 H.sub.5 0 CO.sub.2 CH.sub.2      Si(CH.sub.3).sub.3 H H H n.sub.D.sup.20 =       1.5811                          166 Cl H CH.sub.2 OC.sub.2 H.sub.5 0      CO.sub.2 C.sub.2 H.sub.5 H H H 70-72°       C.                           167 Cl H CH.sub.2 OCH.sub.3 0 CO.sub.2      CH.sub.3 H H H n.sub.D.sup.20 =       1.6141                                    168 Cl H CH.sub.2       Si(CH.sub.3).sub.3 0 CO.sub.2 C.sub.2 H.sub.5 H H H 74-75° C.          169 Cl H CH.sub.3 0 CO.sub.2 CH.sub.2 CH.sub.2 OCH.sub.3 H H H      n.sub.D.sup.20 =       1.6336                                                   170 Cl H      CH.sub.3 0 H CO.sub.2 CH.sub.2 Si(CH.sub.3).sub.3 H H n.sub.D.sup.20 =      1.5702      171 Cl H CH.sub.3 0 H       ##STR516##       H H n.sub.D.sup.20 =       1.6133                           172 Cl H n-C.sub.3 H.sub.7 0 H --CO.sub.2 C.sub.3      H.sub.7 -n H H n.sub.D.sup.20 =       1.6018                                    173 Cl H C.sub.2 H.sub.5 1 H      CO.sub.2 CH.sub.3 H H 156.5-169°       C.                                174 Cl H C.sub.2 H.sub.5 1 H CO.sub.2        CH.sub.2 CF.sub.3 H H 101.5-107°       C.                              175 Cl H n-C.sub.3 H.sub.7 1 H CO.sub.2        C.sub.3 H.sub.7 -n H H n.sub.D.sup.20 =       1.5681                          176 Br H C.sub.2 H.sub.5 1 H CO.sub.2      CH.sub.3 H H 163-168.5°       C.                                         177 Br H C.sub.2 H.sub.5 1 H        CO.sub.2 C.sub.2 H.sub.5 H H 131-135°       C.                         178 Cl H CH.sub.3 0 H CO(CH.sub.2)5Br H H      n.sub.D.sup.20 =       1.6021                      179 Cl H CH.sub.3 0 H       ##STR517##       H H 117-120.5°       C.                            180 Cl H CH.sub.3 0 n-C.sub.4 H.sub.9 CO.sub.2      C.sub.2 H.sub.5 H H n.sub.D.sup.20 =       1.5528                               181 Cl H CH.sub.3 0 COC.sub.4      H.sub.9 -n CO.sub.2 C.sub.2 H.sub.5 H H n.sub.D.sup.20 =       1.5770           182 Cl H C.sub.2 H.sub.5 0 C.sub.2 H.sub.5 CO.sub.2      C.sub.2 H.sub.5 H H n.sub.D.sup.20 =       1.5822                               183 Br H C.sub.2 H.sub.5 0 C.sub.2        H.sub.5 CO.sub.2 C.sub.3 H.sub.7 -n H H n.sub.D.sup.20 = 1.5870              184 Cl H CH.sub.3 1 C.sub.2 H.sub.5 CO.sub.2 C.sub.2 H.sub.5 H H        n.sub.D.sup.20 =       1.5834                                                 185 Cl H      CH.sub.3 0 H COCO.sub.2 C.sub.2 H.sub.5 H H 118-123°       C.            186 Cl H CH.sub.3 0 CO.sub.2 C.sub.2 H.sub.5 CH.sub.2      CH═CH.sub.2 H H n.sub.D.sup.20 =       1.5962                               187 Cl H CH.sub.3 0 CO.sub.2      C.sub.2 H.sub.5 CH.sub.2 C.tbd.CH H H n.sub.D.sup.20 =       1.5944             188 Cl H CH.sub.3 0 CO.sub.2 C.sub.2 H.sub.5      CH.sub.2 CH.sub.2 F H H n.sub.D.sup.20 =       1.5837                           189 Cl H CH.sub.3 0 CO.sub.2 C.sub.2      H.sub.5 C.sub.2 H.sub.5 H H 30-38°       C.                              190 Cl H C.sub.2 H.sub.5 0 CO.sub.2      C.sub.2 H.sub.5 CH.sub.3 H H n.sub.D.sup.20 =       1.6021                      191 Cl H C.sub.2 H.sub.5 0 CO.sub.2 C.sub.2        H.sub.5 C.sub.2 H.sub.5 H H n.sub.D.sup.20 =       1.5922                     192 Cl H C.sub.2 H.sub.5 1 CO.sub.2 C.sub.2      H.sub.5 CH.sub.3 H H n.sub.D.sup.20 =       1.5930                              193 Cl H C.sub.2 H.sub.5 2 CO.sub.2        C.sub.2 H.sub.5 CH.sub.3 H H n.sub.D.sup.20 =       1.5622                    194 Cl H C.sub.2 H.sub.5 1 CO.sub.2 C.sub.2      H.sub.5 C.sub.2 H.sub.5 H H n.sub.D.sup.20 =       1.5852                       195 Cl H C.sub.2 H.sub.5 2 CO.sub.2      C.sub.2 H.sub.5 C.sub.2 H.sub.5 H H n.sub.D.sup.20 =       1.5854               196 Cl H C.sub.2 H.sub.5 1 CO.sub.2 CH.sub.3      CH.sub.3 H H n.sub.D.sup.20 =       1.6182                                      197 Cl H C.sub.2 H.sub.5 2      CO.sub.2 CH.sub.3 CH.sub.3 H H 58-62°       C.                           198 Br H CH.sub.3 0 CO.sub.2 C.sub.2      H.sub.5 C.sub.2 H.sub.5 H H n.sub.D.sup.20 =       1.6020                       199 Br H CH.sub.3 1 CO.sub.2 C.sub.2      H.sub.5 C.sub.2 H.sub.5 H H n.sub.D.sup.20 =       1.5950                       200 Br H CH.sub.3 2 C.sub.2 H.sub.5      CO.sub.2 C.sub.2 H.sub.5 H H n.sub.D.sup.20 =       1.5880                      201 Cl H CH.sub.3 0 CO.sub.2 C.sub.2      H.sub.5 CO.sub.2 CH.sub.3 H H n.sub.D.sup.20 =       1.5852                     202 Cl H CH.sub.3 1 CO.sub.2 CH.sub.3      CO.sub.2 C.sub.2 H.sub.5 H H n.sub.D.sup.20 =       1.5858                      203 Cl H CH.sub.3 0 CO.sub.2 C.sub.2      H.sub.5 CO.sub.2 C.sub.2 H.sub.5 H H n.sub.D.sup.20 =       1.5728              204 Cl H CH.sub.3 0 CO.sub.2 C.sub.4 H.sub.9 -iso      C.sub.2 H.sub.5 H H n.sub.D.sup.20 =       1.5783                               205 Cl H CH.sub.3 0 CO.sub.2      C.sub.2 H.sub.5 (CH.sub.2)5CH.sub.3 H H n.sub.D.sup.20 =       1.5749           206 Cl H CH.sub.3 0 CO.sub.2 CH.sub.2 CF.sub.3 C.sub.2        H.sub.5 H H amorphous        207 Cl H CH.sub.3 0 COC.sub.3 H.sub.7 -iso H H H n.sub.D.sup.20 =      1.6528        208 Cl H CH.sub.3 1 CO.sub.2 C.sub.4 H.sub.9 -n H H H n.sub.D.sup.20 =        1.5944        209 Cl H C.sub.2 H.sub.5 1 CO.sub.2 C.sub.4 H.sub.9 -iso H H H      n.sub.D.sup.20 =       1.5763                                                   210 Cl H      CH.sub.3 0 CO.sub.2 C.sub.2 H.sub.5 CH.sub.2 CN H H n.sub.D.sup.20 =      1.5977        211 Cl H C.sub.2 H.sub.5 0 CO.sub.2 C.sub.2 H.sub.5 COC.sub.6 H.sub.5      H H n.sub.D.sup.20 =       1.5990                                               212 Cl H C.sub.2      H.sub.5 1 CO.sub.2 C.sub.2 H.sub.5 COC.sub.6 H.sub.5 H H n.sub.D.sup.20      =       1.5890        213 Cl H C.sub.2 H.sub.5 2 CO.sub.2 C.sub.2 H.sub.5 COC.sub.6 H.sub.5      H H n.sub.D.sup.20 =       1.5980                                               214 Cl H CH.sub.3      0 COCH.sub.3 C.sub.2 H.sub.5 H H n.sub.D.sup.20 =       1.6140                  215 Cl H C.sub.2 H.sub.5 2 COC.sub.3 H.sub.7 -n        C.sub.2 H.sub.5 H H n.sub.D.sup.20 =       1.5808                             216 Cl H CH.sub.3 0 COC.sub.6      H.sub.5 COCH.sub.3 H H n.sub.D.sup.20 =       1.6308

SYNTHESIS OF INTERMEDIATES SYNTHESIS EXAMPLE 8 ##STR518##

To an acetonitrile solution (200 ml) of 4-bromomethyl-4'-fluorobenzophenone (20 g), an aqueous 15% sodium methylmercaptan solution (60 ml) was added and the mixture was heated for 6 hours with refluxing. After the reaction mixture was restored to room temperature, water (500 ml) and toluene (300 ml) were added. The organic layer was separated, which was then successively washed with an aqueous 2N sodium hydroxide solution and water, and dried over anhydrous magnesium sulfate. After distilling off the solvent, the crude product was purified by silica gel column chromatography (developing solvent n-hexane:ethyl acetate=9:1) to obtain 4-fluoro-4'-methylmercaptomethylbenzophenone (17 g).

n_(D) ²⁰ 1.6375

SYNTHESIS EXAMPLE 9 ##STR519##

To an ether solution (30 ml) of 4-bromoflurorobenzene (1.75 g), 1.6 M n-butyllithium hexane solution (6.3 ml) was added at -78° C., and the mixture was stirred for an hour at the same temperature. An ether solution (10 ml) of 4-methylmercaptomethylbenzonitrile (1.63 g) was dropwise added thereto at -78 ° C., and the mixture was stirred for 16 hours while restoring the mixture gradually to room temperature. To the reaction mixture, an aqueous 6 N hydrochloric acid was added and stirred for an hour at room temperature, and ether (20 ml) was added. Then the organic layer was separated, and washed with water, followed by drying over anhydrous magnesium sulfate. After distilling off the solvent, the obtained crude product was purified by silica gel column chromatography (developing solvent, n-hexane:ethyl acetate 9:1) to obtain 4-fluoro-4'-methylmercaptomethylbenzophenone (1.12 g).

n_(D) ²⁰ 1.6375

SYNTHESIS EXAMPLE 10 ##STR520##

S-(4-(4-chlorobenzoyl)benzyl)thiouronium bromide (3.3 g) and potassium carbonate (1.5 g) were dissolved in dimethylformnamide (20 ml). A methanol solution (10 ml) of potassium hydroxide (1.0 g) was added and stirred at room temperature for 30 minutes. To the reaction mixture, water (100 ml) and toluene (100 ml) were added. The organic layer was separated, and washed with water and an aqueous saturated sodium chloride solution, followed by drying over anhydrous magnesium sulfate. After distilling off the solvent, the crude product was purified by silica gel column chromatography (developing solvent: ethyl acetaten:hexane=1:9) to obtain 4-chloro-4'-ethylmercaptomethylbenzophenone (1.3 g).

melting point: 34-35° C.

4-chloro-4'-difluoromethylmercaptomethylbenzophenone (0.8 g) was obtained in the same manner as in Synthesis Example 10 by using bromodifluoromethane (3.9 g) instead of ethyl iodide.

melting point: 60-62° C.

4-chloro-4'-rifluoromethylmercaptomethylbenzophenone (0.4 g) was obtained in the same manner as in Synthesis Example 10 by using trifluoromethyl iodide (5.9 g) instead of ethyl iodide.

melting point: 78-79° C.

SYNTHESIS EXAMPLE 11 (Synthesis of starting material for Synthesis Example 10) ##STR521##

An acetone solution (500 ml) of 4-bromomethyl-4'-chlorobenzophenone (31 g) and thiourea (10 g) was heated for 30 minutes with refluxing. The precipitated crystals were then collected by filtration and washed with acetone to obtain S-(4-(4-chlorobenzoyl)benzyl)thiouronium bromide (33 g).

melting point: 76-78° C.

SYNTHESIS EXAMPLE 12 ##STR522##

To a tetrahydrofuran solution (30 ml) of lithium diisopropylamide which was prepared from a 1.6 M n-butyllithium hexane solution (12.5 ml) and diisopropylamine (2.1 g), a tetrahydrofuran solution (10 ml) of 4-chloro-4'-methylmercaptomethylbenzophenone (2.8 g) was added at -78° C., and the mixture was stirred for 30 minutes at the same temperature. Ethyl iodide (3.0 g) was subsequently added thereto at -78° C., and the mixture was stirred for 6 hours while restoring the mixture gradually to room temperature. After completing the reaction, the reaction mixture was washed with aqueous 5% ammonium chloride solution and aqueous saturated sodium chloride solution, and dried over anhydrous magnesium sulfate. After distilling off the solvent, the obtained crude product was purified by silica gel column chromatography (developing solvent: n-hexane:ethyl acetate=4:1) to obtain 4-chloro-4'-(1-methylmercaptopropyl)benzophenone (0.3 g) as oily substance.

¹ H-NMR (90 MHz, CDCl₃) (0.93 3H t) (1.88 3H s) (1.96 2H m); (3.63 1H t) (7.27-7.80 8H m)

SYNTHESIS EXAMPLE 13 ##STR523##

To a pyridine solution (30 ml) of 4-(4-chlorobenzolyl)benzylthiocyanate (1.5 g) and benzylthiocyanate (1.5 g), zinc powder (0.4 g) was added and stirred at room temperature for 24 hours under trifluoromethyl iodide atmosphere. Then toluene (50 ml) was added and zink powder was filtered off. The filtrate was washed with 2N HCl aq. (30 ml tree times) and dried over anhydrous magnesium sulfate. After the solvent was evaporated the residue was purified by means of column chromatography (n-hexane:ethylacetate=6:1). Then 4-chloro-4'-trifluoromethylmercaptobenzophenone (0.5 g) was obtained.

melting point: 78-79° C.

SYNTHESIS EXAMPLE 14 ##STR524##

A mixture of 4-chloro-4'-(2-chloroethylmercaptomethyl)benzophenone (4.9 g) and 1,8-diaza-bicyclo[5.4.0]undec-7-ene (4.3 g) in 100 ml of toluene was stirred for 3 hours at 80° C. After that, the mixture was washed with aqueous 2N hydrochloric acid solution and water, followed by drying over anhydrous sodium sulfate. The solvent was distilled off under reduced pressure to obtain 4-chloro-4'-vinylmercaptomethylbenzophenone (4.3 g).

n_(D) ²⁰ 1.6363

SYNTHESIS EXAMPLE 15 ##STR525##

To an acetic acid solution (30 ml) of 4-chloro-4'-methylmercaptomethylbenzophenone (8.3 g), aqueous 30% hydrogen peroxide solution (3.5 ml) was added, and the mixture was stirred for 2 hours while keeping at 10° C. To the reaction solution, water (200 ml) and toluene (200 ml) were added, and then the organic layer was separated, and washed successively with water, an aqueous sodium bicarbonate solution and an aqueous saturated sodium chloride solution, followed by drying over anhydrous magnesium sulfate. After distilling off the solvent, the crude product was purified by silicagel column chromatography (developing solvent: acetone:n-hexane=50:50) to obtain 4-chloro-4'-methylsulfinylmethylbenzophenone (5.3 g).

melting point: 125-128° C.

SYNTHESIS EXAMPLE 16 ##STR526##

4-Chloro-4'-methylsulfinylmethylbenzophenone (2.9 g) and m-chloroperbenzoic acid (2.5 g) were dissolved in dichloromethane, and the mixture was stirred for 12 hours at 0° C. After the precipitated crystals were filtered off, the filtrate was successively washed with aquous sodium bicarbonate solution, aqueous 5% sodium thiosulfate solution and water, and dried over anhydrous magnesium sulfate. After distilling off the solvent, the crude product was purified by silica gel column chromatography (developing solvent: ethyl acetate:n-hexane=1:5) to obtain 4-chloro-4'-methylsulfonylmethylbenzophenone (1.8 g).

melting point: 173-174° C.

SYNTHESIS EXAMPLE 17 ##STR527##

To an acetic acid solution (70 ml) of 4-chloro-4'-methylmercaptomethylbenzophenone (8.3 g), aqueous 30% hydrogen peroxide solution (7 ml) was added at room temperature, and the mixture was stirred for 6 hours at 70° C. The reaction mixture was poured into ice-water, and the precipitated crystals was collected by filtration, and washed with an aqueous sodium bicarbonate solution and water. The crystals was then air-dried to obtain 4-chloro-4'-methylsulfonylmethylbenzophenone (4.3 g).

melting point: 173-174° C.

REFERENCE EXAMPLE 1 (Synthesis of starting materials for Synthesis Example 8) ##STR528##

A carbon tetrachloride solution (200 ml) of 4-fluoro-4'-methylbenzophenone (16 g), N-bromosuccinimide (14.2 g) and 2,2'-azodi-isobutyronitrile (0.1 g) was heated for 16 hours with refluxing. After the mixture was cooled to a room temperature, the precipitates were collected by filtration, and the solvent was distilled off to obtain 4-bromomethyl-4'-fluorobenzophenone (20 g).

melting point: 73-75° C.

REFERENCE EXAMPLE 2 (Synthesis of starting material for Reference Example 1) ##STR529##

Into a toluene suspension (200 ml) of aluminum chloride (26 g), a toluene solution (50 ml) of p-fluorobenzoyl chloride (16 g) was dropwise added at a room temperature. Subsequently, the mixture was stirred for 20 hours at a room temperature, and then carefully poured into ice-water. Toluene (200 ml) was added thereto, and then the organic layer was separated, and washed successively with aqueous 2N hydrochloric acid solution, water and aqueous saturated sodium chloride solution, followed by drying over anhydrous sodium sulfate. The solvent was distilled off under reduced pressure to obtain 4-fluoro-4'-methylbenzophenone (16 g).

melting point: 97-98° C.

REFERENCE EXAMPLE 3 (Synthesis of starting material for Synthesis Example 9) ##STR530##

To an acetonitrile solution (500 ml) of 4-cyanobenzyl bromide (50 g), 15% methyl mercaptan sodium salt (120 ml) was added at a room temperature and heated for 6 hours with refluxing. After cooling to a room temperature, water (1 l) and toluene (1 l) was added thereto. The organic layer was separated and washed successively with an aqueous 2N sodium hydroxide solution sulfate. After distilling off the solvent, 4-methylmercaptomethylbenzonitrile (38 g) was obtained.

n_(D) ²⁰ 1.5821

The following Table 8 shows the compounds synthesized in the above Synthesis Examples 8 to 17 together with compounds synthesized in the same manner as those in the Synthesis Examples 8 to 17.

                  TABLE 8                                                          ______________________________________                                           #STR531##                                                                      -                                  Melting Point or                                                                R.sup.1 R.sup.6 R.sup.7 A Refrective                                           Index                                    ______________________________________                                         Br  H      H       CH.sub.2 SC(═NH)NH.sub.2.HBr                                                               225-231° C.                            Cl H H CH(CH.sub.3)SC(═NH)NH.sub.2.HBr 158-159° C.                  Cl H H CH.sub.2 SC(═NH)NH.sub.2.HBr 76-78° C.                       Cl H 2-Cl CH.sub.2 SC(═NH)NH.sub.2.HBr 110-114° C.                  Cl H 3-Cl CH.sub.2 SC(═NH)NH.sub.2.HBr 198-201° C.                  I H H CH.sub.2 SC(═NH)NH.sub.2.HBr 196-210° C.                      Cl H H CH.sub.2 SCN 149-150° C.                                         Cl H H CH.sub.2 S(CS)OC.sub.2 H.sub.5 62-68° C.                         Cl H H CH.sub.2 S(CO)CH.sub.3 98-99° C.                                 Br H H CH.sub.2 SC.sub.2 H.sub.5 46-48° C.                              Cl H H CH(CH.sub.3)SCH.sub.3 n.sub.D.sup.20 1.6198                             Cl H H CH.sub.2 SC.sub.2 H.sub.5 34-35° C.                              Cl H H CH.sub.2 SC.sub.3 H.sub.7 -iso n.sub.D.sup.20 1.6320                    Cl H H CH.sub.2 SC.sub.3 H.sub.7 -n n.sub.D.sup.20 1.6211                      Cl H H CH.sub.2 SCF.sub.3 78-79° C.                                     Cl H H CH.sub.2 SCH.sub.2 C.tbd.CH 80-81° C.                            Cl H H CH.sub.2 SCH.sub.2 CF.sub.3 77-78° C.                            Cl H H CH2SCH═CH2 n.sub.D.sup.20 1.6363                                    Cl H H CH.sub.2 SCH.sub.2 CH═CH.sub.2 n.sub.D.sup.20 1.6368                                                  Cl H H CH.sub.2 SCH.sub.2 CH.sub.2 Cl                                         65-67° C.                              Cl H H CH.sub.2 SCH.sub.2 CH.sub.2 F 44-45° C.                          Cl H 3-Br CH.sub.2 SCH.sub.3 n.sub.D.sup.20 1.6502                             Cl H 3-CH.sub.3 CH.sub.2 SCH.sub.3 n.sub.D.sup.20 1.6345                       Cl H 2-CH.sub.3 CH.sub.2 SCH.sub.3 n.sub.D.sup.20 = 1.6324                     Cl H H CH.sub.2 SCHF n.sub.D.sup.20 1.6237                                     Cl H H CH.sub.2 SCHF.sub.2 60-62° C.                                    Cl H H CH.sub.2 (SO.sub.2)CH.sub.3 173-174° C.                          Cl H H CH.sub.2 (SO)CH.sub.3 125-128° C.                                Cl 2-Cl H CH.sub.2 SCH.sub.3 n.sub.D.sup.20 1.6369                             Cl 3-Cl H CH.sub.2 SCH.sub.3 66-67° C.                                  F H H CH.sub.2 SCH.sub.3 n.sub.D.sup.20 1.6375                                 F 3-F H CH.sub.2 SCH.sub.3 n.sub.D.sup.20 1.6306                               I H H CH.sub.2 SCH.sub.3 89-91° C.                                      Cl H H CH.sub.2 SCH.sub.2 CN 87.5-88° C.                                Cl H H CH.sub.2 SCH.sub.2 CHF.sub.2 59-60.5° C.                         Cl H H CH.sub.2 SCH.sub.2 CH.sub.2 CH.sub.2 Cl n.sub.D.sup.20 1.6113                                             Br H H CH.sub.2 SCH.sub.2 CF.sub.3                                            79.5-81.5° C.                          Br H H CH.sub.2 SCH.sub.2 CHF.sub.2 62-64° C.                           Cl H H CH.sub.2 SCH.sub.2 CH.sub.2 CH.sub.2 F 39-40.5° C.                                                 Cl H H CH.sub.2 SCH.sub.2 Si(CH.sub.3)                                        .sub.3 95-100° C.                    ______________________________________                                    

BIOLOGICAL TEST EXAMPLES Preparation of Test Solutions

Solvent: 3 parts by weight of xylol

Emulsifier: 1 part by weight of polyoxyethylene alkyl phenyl ether

To produce a suitable preparation of active compound, 1 part by weight of active compound was mixed with the stated amount of solvent containing the stated amount of emulsifier, and the mixture was diluted with water to the prescribed concentration to prepare test solutions.

Test Example 1 (Test against Spodoptera litura larvae)

Testing Procedure

Leaves of cabbage (Brassica oleracea) were dipped into the solution of the active compound at the prescribed concentration. After air-drying the solution, the treated leaves were placed in a petridish, and ten third-instar larvae of common cutworm (Spodoptera litura) were released. The dish was then placed at an incubation chamber of 25° C. After 7 days, the number of dead larvae was examined to calculate mortality in %. The test was conducted with 2 replications, and the mortality in % is shown in their average.

Results

Compound Nos. 8, 12, 16, 34, 37, 43, 48, 50, 54, 57, 60, 63, 74, 83, 92, 106, 171, 121, 125, 132, 139, 140, 141, 142, 147, 148, 149, 151, 152, 155, 157, 158, 159, 160, 161, 162, 163, 164, 165, 168, 170, 171, 172, 173, 174, 175 and 176 exhibited 100% of mortality at the concentration of 200 ppm, and compound Nos. 1, 5, 22, 29, 33, 40, 47, 49, 68, 75, 79, 87, 100, 111, 113, 116, 123, 130, 133, 135, 136, 137, 143, 144, 145, 150, 154, 156 and 169 exhibited 100% of mortality at the concentration of 100 ppm.

Test Example 2 (Test against Aulacophora femoralis)

Testing Procedure

Leaves of cucumber (Cucumis sativus) were dipped into the solution of the active compound at the prescribed concentration. After air-drying the solution, the treated leaves were placed in a Petridish, and ten second-instar larvae of cucurbit leaf beetle (Aulacophora femoralis) were released. The dish was then placed at an incubation chamber of 25° C. After 7 days, the number of dead larvae was examined to calculate mortality in %. The test was conducted with 2 replications, and the mortality in % is shown in their average.

Results

Compound Nos. 3, 7, 15, 18, 23, 25, 31, 36, 39, 44, 51, 58, 59, 61, 65, 73, 77, 78, 84, 85, 91, 93, 96, 98, 101, 103, 109, 114, 115, 119, 120, 126, 129, 131, 133, 135, 136, 140, 145, 148, 150, 152, 154, 156, 163, 167, 169, 170 and 172 exhibited 100% of mortality at the concentration of 200 ppm.

Test Example 3 (Test against Plutella xylostella larvae resistant to benzoylureas)

Testing Procedure

Leaves of cabbage (Brassica oleracea) were dipped into the solution of the active compound at the prescribed concentration. After air-drying the solution, the treated leaves were placed in a petridish, and ten second-instar larvae of diamondback moth (Plutella xylostella) resistant to benzoylureas were released. The dish was then placed at an incubation chamber of 25° C. After 7 days, the number of dead larvae was examined to calculate mortality in %. The test was conducted with 2 replications, and the mortality in % is shown in their average.

Results

Compound Nos. 2, 11, 15, 17, 20, 26, 28, 30, 35, 41, 45, 53, 56, 62, 69, 71, 81, 86, 88, 90, 97, 99, 102, 104, 107, 127, 134, 139, 142, 147, 149, 152, 154, 156, 159, 167 and 168 exhibited 100% of mortality at the concentration of 200 ppm.

Test Example 4 (Test against Cnaphalocrocis medinalis)

Testing Procedure

The solution of the active compound at the prescribed concentration were spread on 3.5-leaf stage of rice. After air-drying the solution, the treated leaves were cut and were placed in a Petridish, and ten third-instar larvae of rice leafroller (Cnaphalocrocis medinalis) were released. The dish was then placed at an incubation chamber of 25° C. After 7 days, the number of dead larvae was examined to calculate mortality in %. The test was conducted with 2 replications, and the mortality in % is shown in their average.

Results

Compound Nos. 4, 9, 10, 13, 24, 27, 32, 42, 46, 52, 55, 64, 67, 70, 72, 76, 82, 89, 94, 95, 105, 108, 110, 112, 124, 128, 140, 148, 151, 160, 163 and 165 exhibited 100% of mortality at the concentration of 50 ppm.

Test Example 5 (Test against Diabrotica balteata)

Preparation of Test Formulation

carrier: 7 parts by weight of Kaolin

emulsifier: 1 part by weight of detergent

For the seed treatment a certain amount of active ingredient is solved acetone and mixed into a the stated amount of carrier containing the stated amount of emulsifier.

For seed coating 200 mg of the formulation are dispersed with 0.2 ml of water within a plastic pot. 10 g of maize are added to the dispersion and mixed thoroughly on rotary shaker for 2 minutes.

Testing Procedure

After drying of the seed coating five treated/untreated seedcernels were added into 300 ml of standardized wet soil and kept at a temperature of 20° C. Two replications are prepared for each preparation.

After two days each pot is infested with 20 second-instar-larvae of Diabrotica balteata, seven days after infestation the number of emerged plants per pot is counted.

The efficacy is calculated to 100% Abbot, if all plants emerged and to 0% Abbot, if no plant emerged.

Results Compound Nos. 8, 39, 70 and 95 exhibited 100% of mortality at the 0.1 g of the active ingredient per 10 g seedcernels. 

We claim:
 1. A compound of the formula: ##STR532##
 2. A method of treating seeds to prevent pesticidal infestation which comprises applying an effective amount of a compound whereinR¹ is Br or Cl, R² is H, R³ is Ch₃ or C₂ H₅,n is 1 or 2, R⁴ is CO₂ H₅, R⁵ is H, R⁶ is H and R⁷ is H. according to claim 1 to said seeds.
 3. A composition for treating seeds to prevent pesticidal infestation which comprises an effective amount of a compound according to claim 1 and an inert carrier. 